通过熔融-快冷-可控结晶技术,制备了不同Pb含量的PbO-Na2O-Nb2O5-SiO2系的玻璃陶瓷,并对其结晶行为和介电性能进行了研究.XRD分析结果表明,在750℃下热处理的样品,随Pb含量增加,相结构由立方钙钛矿演变至焦绿石相;而850℃下热处理样品,随Pb含量增加,相结构由方钙钛矿演变为钨青铜/钙钛矿两相共存;介电性能测试结果表明,750℃热处理样品介电常数随Pb含量增加而降低;850℃热处理样品趋势相反,且高Pb含量样品的介电常数温度依赖性显著.采用EDS对玻璃相内和陶瓷颗粒内部元素分布进行了分析,并采用三元系相图对结晶反应过程进行了解释,表明,不同组分和热处理条件下,析晶反应路径的不同是造成相变演化和介电性能显著不同的主要原因.
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