以TiC,Ti,Al,C粉末为反应物原料,采用自蔓延高温反应按照质量分数为15% TiC,50% Ti,28% Al,7% C的配比合成了纯度为96.76%、气孔率为9.45%的高纯Ti3AlC2块体材料。研究添加TiC对合成产物Ti3AlC2材料纯度的影响,并对其摩擦磨损性能进行分析。结果表明:当添加 TiC 的质量分数小于15%,Ti3AlC2含量随 TiC 含量的增加而增加;当添加TiC质量分数大于15%,Ti3AlC2含量随TiC含量的增加而降低。当载荷较小,Ti3AlC2材料以磨粒磨损为主;而载荷较大,其以磨粒磨损为主并伴随有轻微黏着磨损。
High purity Ti3AlC2 was synthesized by self?propagating high?temperature synthesis method using TiC,Ti,Al and C powders as raw materials. Ti3AlC2 material with high density was successfully fabricated when the mass fraction of TiC/Ti/Al/C is equal to 15%/50%/28%/7%. The content of Ti3AlC2 in the material reaches as high as 96.76%,and the porosity is only 9.45%. The effects of TiC on the purity of sintered Ti3AlC2 were studied. When the addition content of TiC is less than 15%,Ti3AlC2 percentage content firstly increases with the increase of TiC content,but when the addition content of TiC is greater than 15%,it will decrease with continuously increasing amount of TiC. When the load is low,the main wear mechanism is abrasive wear. Under a higher load,the wear mechanism transforms to abrasive wear and light adhesive wear.
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