以过硫酸胺(APS)为引发剂,N,N-亚甲基双丙烯酰胺(MBA)为交联剂,采用插层聚合法制备了蒙脱土/海藻酸钠接枝丙烯酸(MMT/SA—g—PAA)高吸水性复合物。通过红外光谱(FT—IR)、扫描电镜(SEM)、热重分析(TGA)对MMT/SA—g—PAA的结构和性能进行了表征。研究了MMT/SA-g—PAA对重金属离子的吸附性能,结果表明室温下MMT/SA—g-PAA对Pb2+、Cu2+、Ni2+的最大吸附量分别为968.9、231.0及236.Omg/g,其中对Pb2+和Cu计的吸附符合Langmuir吸附模型,而对Ni2+的吸附符合Freundlich吸附模型。
Montmorillonite/sodium alginate gratt poly (acryhc acid) superabsorbent composxte was prepared by intercalation polymerization of sodium alginate (SA), acrylic (AA) and montmorillonite (MMT) using ammo- nium persulfate (APS) as an initiator and N,N'-methylenebisacrylamide (MBA) as a cross linker. The super- absorbent composite was characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). Sorption behavior of heavy metal ions on MMT/ SA-g-PAA was investigated. Maximal amount Of adsorption for Pb2+ , Cu2+ and Ni2+ was 968.9,231.0 and 236.0mg/g, respectively, and the adsorption of Pb2+ and Cu2+ was in accordance with Langmuir model, while that of Ni2+ was in accordance with Freundlich model.
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