The stability of NiO and oxidized nickel-niobium surface alloy electrode under various molten carbonate fuel cell(MCFC) cathode conditions were investigated by determination of equilibrium solubility of nickel ions in the carbonate melt of the two electrode materials.It is found that under MCFC cathode conditions the stability of NiO electrode is improved significantly by the deposition of niobium.As far as stability is concerned,oxidized nickel-niobium alloy electrode can be considered as a candidate for cathode material of MCFC.
参考文献
[1] | Blomen L;Mugerwa M.Fuel Cell System[M].New York:Plenum Press,1993 |
[2] | Appleby J;Folkes F.Fuel Cell Handbook[M].Van Nostrand Reinhold,New York,1990 |
[3] | Selman J R;Claar T D.Molten Carbonate Fuel Cell Technology[M].Pennington,NJ,1982 |
[4] | Fuel Cell,a handbook(DOE/METC-88/6096)[S].,1988. |
[5] | Ota K I;Kim B T;Take H Y.[A].昆明,1994:42. |
[6] | Selman J R;Maru H C;Braustein J.Advances in Molten Salt Chemistry[M].New York:Plenum Press,1983:308. |
[7] | Selman J R;Marianowski L G;Lovering D G.Molten Salt Technology[M].New York:Plenum Press,1982:323. |
[8] | Vogel W;Bregoli L;Kunz H.Proc.Symp.Molten Carbonate Fuel Cell Technology.Montreal,Canada[M].The Electrochemical Society,Pennington,NJ,USA,1988:443. |
[9] | Baumgartner C .[J].Journal of the Ceramic Society of Japan,1986,69:162. |
[10] | Shores D;Selman J R;Israni S.Proc.2nd Symp.Molten Carbonate Fucl Cell technology[M].Washington,DC,USA,1990:290. |
[11] | Iacovangelo C .[J].Journal of the Electrochemical Society,1986,133:1359. |
[12] | Kucera G;Myles K;Brown A.Proc.4th Annual Fuel Cells Contractors Review Meet[C].Morgantown,WV,USA,1992 |
[13] | Myles K;Krumpelt M;Kucera G.Proc.Joint Contractors Meet:Advanced Turbine Systems[A].Morgantown,WV,USA,1993:386. |
[14] | Plomp L;Veldhuis J;Sitters E.Proc.International Fuel Cell Conf[C].Makuhari,Japan,1992:Ⅲ-B-1. |
[15] | Smith J;Kucera G;Brown A.Proc.2nd Symp.Molten Carbonate Fuel Cell Technology,Seattle,WA,USA[A].Pennington,NJ,USA,1990:225. |
[16] | Plomp L;Veldhuis B J;Sitters E F et al.[J].Journal of Power Sources,1992,39:369. |
[17] | Giorgi L;Carewska M;Patriaca M et al.[J].Journal of Power Sources,1994,49:227. |
[18] | Nobuyuki Kamiya;Yasuhiro Takeishi;Soichi Shibata.[A].昆明,1994:58. |
[19] | Yabe H;Ito Y;Ema K et al.[J].Journal of Power Sources,1988,24:207. |
[20] | Fujii T;Baba H .[J].Boshoku Gijutsu,1980,29:457. |
[21] | Mellors G W;Senderoff S .[J].Journal of the Electrochemical Society,1965,112:266. |
[22] | Orfield M L;Shores D A .[J].This Journal,1989,136:2862. |
[23] | Yabe H;Ito Y;Ema K et al.[J].Journal of the Electrochemical Society,1992,139:667. |
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