合成了侧链携带金刚烷的温敏性聚合物(Pnipam-Ad)及环糊精二聚体(trans-Azoβ-CD Dimer),利用Pnipam-Ad侧链的金刚烷与trans-Azoβ-CD Dimer的主客体识别作用构筑了超分子体系.以二维核磁共振谱(2D NMR)、粘度法等手段对Pnipam-Ad与trans-Azoβ-CD Dimer之间的主客体包结作用进行了研究,两者之间的缔合受Pnipam-Ad和trans-Azoβ-CD Dimer浓度及trans-Azoβ-CD Dimer光异构的影响.此外,trans-Azoβ-CD Dimer对Pnipam-Ad聚合物链的物理交联作用使两者混合溶液的最低临界溶解温度(LCST)低于纯P(NIPAM)的LCST.
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