Degradation of Residual Formaldehyde in Fabric by Photo-catalysis

武汉理工大学学报-材料科学版(英文版), 2008, 23(2): 147-150.

^1, , ^2, , ^3, , ^4, , ^5, , ^6, , ^7,

1.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

2.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

3.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

4.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

5.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

6.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

7.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

基金项目: Sichuan Province,the Research of Photo Purification to Environment with Nano TiO2(05YJ029-010)

Degradation of Residual Formaldehyde in Fabric by Photo-catalysis

YAO Yadong ^1, , GUO Xiangli ^2, , KANG Yunqing ^3, , LI Xieji ^4, , CHEN Aizheng ^5, , YANG Weizhong ^6, , YIN Guangfu ^7,

1.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

2.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

3.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

4.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

5.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

6.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

7.College of Materials Science & Engineering, Siehuan University, Chengdu 610064, China

Keywords： photo-catalytic degradation

The residual formaldehyde (HCHO) in fabric was degraded using photo-catalysis assisted by the compound catalyst of nano-TiO2 and nano-ZnO. The effects of several factors on the degradation,such as the composing of catalyst, irradiation time, pH value and the H2CHO concentration of the immersed solution were investigated. Results showed that H2CHO of the immersed solution had degraded 93% after 5 h irradiation, and the degradation ratio of formaldehyde could be improved and the aging of the fabric can be avoided with the addition of ZnO nanoparticles and pH value of the immersed-fibric solution. The fabric with residual formaldehyde about 1 800 μg/g can be efficiently treated to satisfy the China National Standard(GB/2912.1-1998) with the photo-catalytic degradation.

参考文献

[1]	K Shi.Produce,Hazard,Detection and Removal of Formaldehyde in Fabric[J].Test Technology,2002(09):18-21.
[2]	J Ji;X Lu.The Control of Free Formaldehyde During the Process of Fabric Treating[J].Printing Dyeing,2003(07):28-30.
[3]	D Xie.Formaldehyde and Pollution-free Textile[J].Chemical Education,2000(7-8):4-5.
[4]	Y Wang;H He.The Study on Photo-catalytic Degradation of Waste Water Contained Formaldehyde[J].Environmental Protection of Chemical Industry,2003(12):311-313.
[5]	J Ju;L Shi .Preparation of Nano-TiO2-WO3 and Formaldehyde Photo-catalytic Degradation[J].J Fine Chem,2004,21(03):181-184.
[6]	G Ye;S Jiang .Degradation of Butaldehyde in Effluent by Photocatalysis[J].J Qingdao Institute of Chem Technol,2000,21(03):206-208.
[7]	C S Deng;R F James;Wright P V .Poly(Tetrathleneglycol Malonate)-titanium Oxide Hybrid Material by Sol-gel Methods[J].Journal of Materials Chemistry,1998,8(01):153-159.
[8]	P Arnal;R J P Con'in;D Leclercq et al.Preparation of Anatase,Brookite and Rutile at Low Temperature by Nonhydrilytic Solgel Methods[J].Journal of Materials Chemistry,1996,6(12):1925-1932.
[9]	J Xu;Q Pan;Y Shun et al.Emulsion Synthesis,Microstructure and Gas Sensing Properties of Nanoeter ZnO Ceramics[J].Chinese Journal of Inorganic Chemistry,1998,14(03):355-359.
[10]	R Zhang;H Liu;F Li .Synthetic Industrialized Method of Nanometer TiO2 and Application of Environmental Protection Respect[J].Environmental Chemistry,1999,18(06):579-583.
[11]	GB 2912.1-1998.GB 2912.1-1998.The Testing of Formaldehyde in Textile[S].,1998.
[12]	K Okamoto;Y Yamamoto;H Tanaka et al.Kinetics of Heterogeneous Photocatalytic Decompostion of Phenol Over Anatase TiO2 Power[J].Bulletin of the Chemical Society of Japan,1985,58(07):2023-2028.
[13]	F Robert;A Sharrock .European Approach to UV Protection with a Novel Pigment[J].Journal of Coatings Technology,1990,125(62):789-794.
[14]	GB 18401-2003.GB 18401-2003.China National Standard of the Safety of Fabric Products[S].
[15]	廖东亮,肖新颜,邓沁,张会平,万彩霞.二氧化钛光催化降解甲醛反应动力学研究[J].化工环保,2003(04):191-194.

上一张下一张

计量

下载量()
访问量()

作者相关

在本站搜索
在百度学术搜索
在万方数据库搜索
在CNKI搜索

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Degradation of Residual Formaldehyde in Fabric by Photo-catalysis

参考文献