环糊精具有良好的生物相容性和环境友好性,并且来源丰富、价格低廉,其在高分子合成领域中的应用越来越受到关注.研究表明,难溶于水的有机单体与环糊精形成的复合物可以直接在水相中通过自由基成功地引发聚合.这一方面使反应过程更加绿色化,减轻污染;另一方面,通过调整配方和工艺,可以进一步简化流程,控制产物结构,提高产物质量.本文从环糊精及环糊精/单体复合物分子结构出发,较为系统的综述了近些年来环糊精在聚合反应中的应用成果.
参考文献
| [1] | Helmut Ritter;Monir Tabatabai .Cyclodextrin in polymer synthesis: a green way to polymers[J].Progress in Polymer Science,2002(9):1713-1720. |
| [2] | Debunne A;Vervaet C;Remon JP .Development and in vitro evaluation of an enteric-coated multiparticulate drug delivery system for the administration of piroxicam to dogs.[J].European journal of pharmaceutics and biopharmaceutics: official journal of Arbeitsgemeinschaft fuer Pharmazeutische Verfahrenstechnik e.V,2002(3):343-348. |
| [3] | Flosbach C.;Herm M.;Ritter H.;Glockner P. .Cyclodextrin-assisted polymerization - a new way to synthesize powder coat resins[J].Progress in Organic Coatings: An International Review Journal,2003(2/4):177-182. |
| [4] | Cao YJ.;Xiao XH.;Ji SF.;Lu RH.;Guo QX. .Study of the inclusion processes of styrene and alpha-methyl-styrene in beta-cyclodextrin[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2004(4):815-820. |
| [5] | Choi SW;Ritter H .Towards green routes for polymer synthesis: Polymerization of cyclodextrin host-guest complexed diethyl fumarate and copolymerization with complexed styrene in homogenous aqueous solution[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2004(6):716-719. |
| [6] | Reihmann MH.;Ritter H. .Oxidative oligomerization of cyclodextrin-complexed bifunctional phenols catalyzed by horseradish peroxidase in water[J].Macromolecular chemistry and physics,2000(7):798-804. |
| [7] | Sarvothaman MK;Ritter H .Discriminating influence of alpha- and methylated beta-cyclodextrins on complexation and polymerization of diacrylate and dimethacrylate monomers[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2004(23):1948-1952. |
| [8] | Storsberg J.;van Aert H.;van Roost C.;Ritter H. .Cyclodextrins in polymer synthesis: A simple and surfactant free way to polymer particles having narrow particle size distribution[J].Macromolecules,2003(1):50-53. |
| [9] | Saito R.;Kobayashi H. .Synthesis of polymers by template polymerization. 2. Effects of solvent and polymerization temperature[J].Macromolecules,2002(19):7207-7213. |
| [10] | Alupei IC.;Alupei V.;Ritter H. .Cyclodextrins in polymer synthesis: Crosslinking water-soluble unsaturated polyester resins using a cyclodextrin/styrene complex in aqueous medium[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2003(8):527-531. |
| [11] | Theis A.;Ritter H. .Cyclodextrins in polymer synthesis: Free radical polymerization of beta-cyclodextrin complexes of photosensitive mesoionic 6-oxo-1,6-dihydropyrimidin-3-ium-4-olates in aqueous medium[J].Macromolecular chemistry and physics,2003(10):1297-1304. |
| [12] | Storsberg J.;Ritter H. .Cyclodextrins in polymer synthesis: free radical polymerization of cyclodextrin host-guest complexes of methyl methacrylate or styrene from homogenous aqueous solution[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2000(5):236-241. |
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