以TiO_2为载体,采用双注法合成了AgBr/TiO_2复合光催化剂.利用X射线衍射仪(XRD)、紫外可见分光光度计(UV-Vis)和扫描电子显微镜(SEM)对AgBr/TiO_2的结构、光吸收、形貌进行了表征.研究了AgBr/TiO_2在可见光下对甲基橙和丁基罗丹明B的光催化活性.结果表明,与TiO_2相比,AgBr/TiO_2的光吸收范围拓展到400-600 nm波段,并且随着AgBr负载量的增加,AgBr/TiO_2的可见光吸收强度增强;当AgBr与TiO_2的摩尔比为0.25时,AgBr/TiO_2具有最大催化活性;在相同条件下,AgBr/TiO_2对丁基罗丹明B的降解效果优于甲基橙.
AgBr/TiO_2 composite photocatalyst was prepared by double-jet method using TiO_2 as sub-strate. The structure, light absorption and microscopy of AgBr/TiO_2 were respectively measured by X-ray diffraction (XRD), ultraviolet visible spectroscopy (UV-Vis) and scanning electron mi-croscopy (SEM). The photocatalytic activity of AgBr/TiO_2 for degradation of methyl orange (MO) and butyl rhodamine B (b-RhB) was studied under visible light irradiation. The results showed that the light absorption of AgBr/TiO_2 was broadened to 400-600 nm compared to TiO_2. With increas-ing the content of AgBr in AgBr/TiO_2, the light absorption intensity increased. AgBr/TiO_2 showed maximal photocatalytic activity when the molar ratio of AgBr to TiO_2 was 0.25. In addition, degra-dation efficiency of b-RhB with AgBr/TiO_2was higher than that of MO under the same condition.
参考文献
[1] | Yu JC;Ho WK;Yu JG;Yip H;Wong PK;Zhao JC .Efficient visible-light-induced photocatalytic disinfection on sulfur-doped nanocrystalline titania[J].Environmental Science & Technology: ES&T,2005(4):1175-1179. |
[2] | C.Hu;Jimmy C.Yu;Z.Hao;P.K.Wong .Effects of acidity and inorganic ions on the photocatalytic degradation of different azo dyes[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(1):35-47. |
[3] | Xu JH;Li JX;Dai WL;Cao Y;Li HX;Fan KN .Simple fabrication of twist-like helix N,S-codoped titania photocatalyst with visible-light response[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2008(1):72-80. |
[4] | Yoichi Ishibai;Junya Sato;Takashi Nishikawa .Synthesis of visible-light active TiO2 photocatalyst with Pt-modification: Role of TiO2 substrate for high photocatalytic activity[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2008(2):117-121. |
[5] | Zhao J C;Chen C C;Ma W H .Photocatalytic degradation of organic pollutants under Visible light irradiation[J].Topics in Catalysis,2005,35(3-4):269-278. |
[6] | Yao W F;Wang H;Xu X H .Photocatalytic property of bismuth titanate Bi_(12)Ti_2O_(20) crystals[J].Applied Catalysis A:General,2003,243(01):l85-190. |
[7] | Liu S W;Song C F;Lü M K .A novel TiO_2/Zr_xTi_(1-x)O_2 composite photocatalytic films[J].Catalysis Communications,2003,4(07):343-346. |
[8] | Yao WF.;Wang H.;Xu XH.;Zhou JT.;Yang XN.;Zhang Y.;Shang SX. .Photocatalytic property of bismuth titanate Bi2Ti2O7[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2004(1):29-33. |
[9] | Hyun Gyu Kim;Dong Won Hwang;Jae Sung Lee .An Undoped,Single-Phase Oxide Photocatalyst Working under Visible Light[J].Journal of the American Chemical Society,2004(29):8912-8913. |
[10] | Tang J;Zou Z;Ye J .Efficient photocatalytic decomposition of organic contaminants over CaBi_2O_4 under visible-light irradiation[J].Angewandte Chemie,2004,116:4563-4566. |
[11] | 张庆庆,汤斌.胶体氯化银抗菌膜的制备及其光催化抗菌特性[J].南京理工大学学报(自然科学版),2004(05):547-551. |
[12] | 李国平,李杰,罗运军.AgBr纳米簇:PAMAM树形分子模板法制备及光催化性能研究[J].无机化学学报,2007(02):253-257. |
[13] | Kakuta N;Goto N;Ohkita H et al.Silver bromide as a photocatalyst for hydrogen generation from CH_3OH/H_2O solution[J].Journal of Physical Chemistry B,1999,103(29):517-519. |
[14] | Rodrigues S;Uma S;Martyanov IN;Klabunde KJ .AgBr/Al-MCM-41 visible-light photocatalyst for gas-phase decomposition of CH3CHO[J].Journal of Catalysis,2005(2):405-410. |
[15] | Chun Hu;Yongqing Lan;Jiuhui Qu;Xuexiang Hu;Aimin Wang .Ag/AgBr/TiO_2 Visible Light Photocatalyst for Destruction of Azodyes and Bacteria[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(9):4066-4072. |
[16] | Hu C;Hu XX;Wang LS;Qu JH;Wang AM .Visible-light-induced photocatalytic degradation of azodyes in aqueous AgI/TiO2 dispersion[J].Environmental Science & Technology: ES&T,2006(24):7903-7907. |
[17] | Lan YQ;Hu C;Hu XX;Qu JH .Efficient destruction of pathogenic bacteria with AgBr/TiO2 under visible light irradiation[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2007(3/4):354-360. |
[18] | Mohammad R. Elahifard;Sara Rahimnejad;Saeed Haghighi .Apatite-Coated Ag/AgBr/TiO2 Visible-Light Photocatalyst for Destruction of Bacteria[J].Journal of the American Chemical Society,2007(31):9552-9553. |
[19] | Yujing Zang;Ramin Farnood .Photocatalytic activity of AgBr/TiO2 in water under simulated sunlight irradiation[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2008(4):334-340. |
[20] | Tani T.Photographic Sensitivity:Theory and Mechanisms[M].New York:Oxford Univeristy Press,1995 |
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