以稀土硝酸盐和硼酸作为原料,采用溶胶-凝胶法在硅底片上通过浸涂合成了YBO3∶Eu3+薄膜.应用X-射线衍射(XRD)、能量色散X射线衍射(EDX)、原子力显微镜(AFM)和荧光分光光谱仪分别研究了其晶体结构、形貌、化学成份和光致发光(PL)性能.结果表明,成功合成了YBO3∶Eu3薄膜,由平均粒径为100 nm、均方根(RMS)粗糙度为10 nm的YBO3∶Eu3+纳米晶组成,在PL光谱中于588 nm和616 nm处分别呈现出橙色发光峰和红色发光峰,归因于Eu3+掺杂的(5 D0→7F1)和(5D0→7F2)能级跃迁.
参考文献
[1] | 巴学巍,李东锋,米晓云.La2Zr2O7:Eu发光材料的共沉淀法制备与表征[J].人工晶体学报,2010(05):1319-1324. |
[2] | 司伟.水热改性纳米荧光粉Eu0.12Y1.78Ca0.10O3-δ及其光致发光性能[J].人工晶体学报,2011(03):689-693,699. |
[3] | 张鹏,张晓凡,朱建锋.柠檬酸燃烧法制备Sr3Y2(BO3)4∶Eu3+荧光粉及特性研究[J].人工晶体学报,2011(05):1141-1144,1149. |
[4] | Alivisatos AP .SEMICONDUCTOR CLUSTERS, NANOCRYSTALS, AND QUANTUM DOTS[J].Science,1996(5251):933-937. |
[5] | Hongwei Song;HongQuan Yu;Guohui Pan .Electrospinning Preparation, Structure, and Photoluminescence Properties of YBO3:Eu~(3+) Nanotubes and Nanowires[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(14):4762-4767. |
[6] | Qin, C.;Qin, L.;Chen, G.;Xu, H.;Lin, T. .Preparation and luminescence properties of SiO_2@LaBO _3:Eu~(3+) nanoparticles[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,2013(8):1827-1-1827-10. |
[7] | Kang YC.;Bin Park S.;Roh HS. .Preparation of Y2O3 : Eu phosphor particles of filled morphology at high precursor concentrations by spray pyrolysis[J].Advanced Materials,2000(6):451-453. |
[8] | Arai Y;Kominami H;Nakanishi Y;Hatanaka Y .Luminescent properties of SrGa2S4 : Eu thin film phosphors deposited by two electron beam evaporation[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2005(1/4):473-476. |
[9] | Kida T;Rahman MM;Nagano M .Preparation of CaMgSi2O6 : Eu2+ phosphor films by a layer-by-layer deposition method[J].Journal of the Electrochemical Society,2006(4):H82-H85. |
[10] | Kyung Nam Kim;Ha-Kyun Jung;Hee Dong Park .Synthesis and characterization of red phosphor (Y,Gd)BO_3:Eu by the coprecipitation method[J].Journal of Materials Research,2002(4):907-910. |
[11] | K N Shinde,S J Dhoble,Animesh Kumar.Combustion synthesis of Ce3+, Eu3+ and Dy3+ activated NaCaPO4 phosphors[J].稀土学报(英文版),2011(06):527-535. |
[12] | Vikas Dubey;Jagjeet Kaur;Sadhana Agrawal;N.S. Suryanarayana;K.V.R. Murthy.Effect of Eu~(3+) concentration on photoluminescence and thermoluminescence behavior of YBO_3:Eu~(3+) phosphor[J].Superlattices and microstructures,2014:156-171. |
[13] | C.K. Lin;M.L. Pang;M. Yu;J. Lin .Photoluminescence of wet chemical process-derived (Y, Gd) BO_3: Eu~(3+) /Tb~(3+) thin film phosphors[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2005(3/4):299-306. |
[14] | Junxi Wan;Zhenghua Wang;Xiangying Chen;Li Mu;Yitai Qian .Shape-tailored photoluminescent intensity of red phosphor Y_2O_3:Eu~(3+)[J].Journal of Crystal Growth,2005(3/4):538-543. |
[15] | Zhu HL;Yang DR;Zhu LM;Li DS;Chen PH;Yuz GX .Hydrothermal synthesis and photoluminescence properties of La2-xEuxSn2O7 (x=0-2.0) nanocrystals[J].Journal of the American Ceramic Society,2007(10):3095-3098. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%