欢迎登录材料期刊网

材料期刊网

高级检索

采用高温固相法和溶胶-凝胶法制备LiCoXMn2-XO4(x=0,0.05,0.1,0.2),研究了掺杂Co后,材料的相结构和充放电性能,并与LiMn2O4相对比.结果表明:掺杂Co后材料的充放电性能相对LiMn2O4均有所提高;两种方法制备的LiCoXMn2-XO4循环40次后,容量保持率、放电比容量均优于LiMn2O4;且当x =0.05时,两种方法制备的LiCoXMn2-XO4的充放电性能均明显优于x=0.1和x=0.2时.

参考文献

[1] Naoto Kitamura;Hidenobu Iwatsuki;Yasushi Idemoto .Improvement of cathode performance of LiMn_2O_4 as a cathode active material for Li ion battery by step-by-step supersonic-wave treatments[J].Journal of Power Sources,2009(1):114-120.
[2] Liu W.;Chaput F.;Dunn B.;Farrington GC. .SYNTHESIS AND ELECTROCHEMICAL STUDIES OF SPINEL PHASE LIMN2O4 CATHODE MATERIALS PREPARED BY THE PECHINI PROCESS[J].Journal of the Electrochemical Society,1996(3):879-884.
[3] Gao Y.;Dahn JR. .THE HIGH TEMPERATURE PHASE DIAGRAM OF LI1+XMN2-XO4 AND ITS IMPLICATIONS[J].Journal of the Electrochemical Society,1996(6):1783-1788.
[4] Bruno Scrosati .Recent advances in lithium ion battery materials[J].Electrochimica Acta,2000(15/16):2461-2466.
[5] Sun-Ho Kang;John B. Goodenough .Li[Li_yMn_(2-y)]O_4 Spinel Cathode Material Prepared by a Solution Method[J].Electrochemical and solid-state letters,2000(12):536-539.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%