通过控制提拉速率,采用液面漩涡法制备了高度有序的微米级聚苯乙烯(PS)二雏胶体晶体.利用扫描电子显微镜(SEM)和紫外可见分光光度计(UV-vis)考察了提拉速率对胶体晶体微观结构的影响.发现波面漩涡法制备二雏胶体晶体的过程中存在最佳提拉速率,且其随着PS微球粒径的增大而减小.理论研究表明:提拉速率对毛细管作用力和流体静压力有显著影响.提拉速率达到最佳时,毛细管作用力达到与流体静压力和静电斥力的平衡,此时组装的PS二雏胶体晶体质量最高.
参考文献
| [1] | Frey W.;Chilkoti A.;Woods CK. .Ultraflat nanosphere lithography: A new method to fabricate flat nanostructures[J].Advanced Materials,2000(20):1515-1519. |
| [2] | Hinz P;Dislich H .[J].Journal of Non-Crystalline Solids,1986,82(1-3):411-416. |
| [3] | Micheletto R;Fukuda H;Ohtsu M .[J].Langmuir,1995,11(09):3333-3336. |
| [4] | Yue Li;Guotao Duan;Weiping Cai .Controllable superhydrophobic and lipophobic properties of ordered pore indium oxide array films[J].Journal of Colloid and Interface Science,2007(2):615-620. |
| [5] | Pan Feng;Zhang Junying;Zhang Weiwei et al.[J].Applied Physics Letters,2007,90:122114-1-122114-3. |
| [6] | Johnson BJS.;Zhu CC.;Stein A.;Schroden RC. .Synthesis and characterization of 2D and 3D structures from organic derivatives of polyoxometalate clusters: Role of organic moiety, counterion, and solvent[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2001(23):5972-5978. |
| [7] | Miguez H.;Lopez C.;Blanco A.;Moya JS.;Requena J.;Mifsud A.;Fornes V.;Meseguer F. .Control of the photonic crystal properties of fcc-packed submicrometer SiO2 spheres by sintering[J].Advanced Materials,1998(6):480-483. |
| [8] | Reculusa S.;Ravaine S. .Synthesis of colloidal crystals of controllable thickness through the Langmuir-Blodgett technique[J].Chemistry of Materials,2003(2):598-605. |
| [9] | Nagayama K .[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1996,109:363-374. |
| [10] | Goldenberg L M;Wagner J;Stumpe J .[J].Langmuir,2002,18(14):5627-5629. |
| [11] | Pan F;Zhang JY;Cai C;Wang TM .Rapid fabrication of large-area colloidal crystal monolayers by a vortical surface method[J].Langmuir: The ACS Journal of Surfaces and Colloids,2006(17):7101-7104. |
| [12] | 张凯,雷毅,王宇光,江璐霞.单分散聚苯乙烯微球的制备及影响因素研究[J].功能高分子学报,2002(02):189-193. |
| [13] | Im SH.;Park OO. .Effect of evaporation temperature on the quality of colloidal crystals at the water-air interface[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(25):9642-9646. |
| [14] | Dimitrov A S;Dushkin C D;Yoshimura H et al.[J].LANGMUIR,1994,10(02):432-440. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%