以苯乙烯、丙烯酸丁IR,N-羟甲基丙烯酰胺、丙烯酰胺为原料,用聚乙烯醇(PVA)作为胶体保护剂,采用无皂乳液聚合方式,制备苯乙烯-丙烯酸酯树脂乳液.同时以HDI三聚体与聚乙二醇单甲醚500(MPEG 500)为主要原料制备水分散聚异氛酸酯交联剂.用苯乙烯一丙烯酸酯树脂乳液与亲水改性聚异氛酸酯复合,制备纸张表面施胶增强剂.应用试验表明,制备的增强剂对提高纸张表面性能较有效果:表面施胶增强剂用童为1%时,纸张的环压强度提高23.4%,拉伸强度提高34.O%,撕裂度提高38.6%,拉毛强度提高30.4%.施胶度可达57s.
参考文献
[1] | Zhang, SW;Liu, R;Jiang, JQ;Bai, HY .Film formation and mechanical properties of the alkoxysilane-functionalized poly (styrene-co-butyl acrylate) latex prepared by miniemulsion copolymerization[J].Progress in Organic Coatings: An International Review Journal,2009(1):56-61. |
[2] | Kong, XZ;Zhu, XL;Jiang, XB;Li, XF .Preparation and full characterization of cationic latex of styrene-butyl acrylate[J].Polymer: The International Journal for the Science and Technology of Polymers,2009(17):4220-4227. |
[3] | Andersson C;Backfolk K .Interdiffusion in carboxylated styrene/butyl acrylate latex films studied by topographic and thermal analysis[J].Progress in Organic Coatings: An International Review Journal,2008(1):63-71. |
[4] | 马好;沈一丁 .[J].中国造纸学报,2008,23(03):60-62. |
[5] | Suganuma;Hajime;Watanabe et al.Water-dispersible Polyisocyanate Composition,Production Thereof,and Water-based Curable Composition and Application Thereof[P].USP:7417090,2008-08-26. |
[6] | Tien;Hegedus C F;Santosusso C R et al.Two Component Waterborne Crosslinkable Polyurethane/AcrylateHybrid Systems[P].USP:5594065,1997-01-14. |
[7] | Krefeld C 1;KOIn H J I;Kerken W K et al.Binder Compositions and Their Use in Aqueous Coating and Adhesive Compositions[P].USP:6,420,478 B1,2002-07-16. |
[8] | Bergisch Gladbach H J L;Odenthal M B;Odenthal R H .Highly FunctionalPolyisocyanate Mixtures Which are Dispersible in Water[P].USP:6777523 BI,2004-08-17. |
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