稀土化合物作为PVC热稳定剂具有优异的热稳定性和良好的耐候性,无毒环保,且和其他热稳定剂有协同作用.本文介绍了聚氯乙烯(PVC)稀土热稳定剂的合成现状,作用机理,及应用进展,并指出其今后的发展前景.
参考文献
[1] | 郭玉军.浅析聚氯乙烯稀土热稳定剂的稳定机理[J].聚氯乙烯,2006(10):25-26. |
[2] | Gonzalez-Ortiz LJ;Arellano M;Sanchez-Pena MJ;Mendizabal E;Jasso-Gastinel CF .Effect of stearate preheating on the thermal stability of plasticized PVC compounds[J].Polymer Degradation and Stability,2006(11):2715-2722. |
[3] | 杨占红,舒万艮.稀土热稳定剂在聚氯乙烯塑料中的应用前景[J].稀土,1995(05):46. |
[4] | Ponce-Ibarra VH;Benavides R;Cadenas-Pliego G;Palos-Pizarro I;Huerta BM .Thermal degradation of poly(vinyl chloride) synthesized with a titanocene catalyst[J].Polymer Degradation and Stability,2006(3):499-503. |
[5] | 李晶,吴晓东,翁端.聚氯乙烯塑料稀土稳定剂的研究开发现状和发展趋势[J].稀土,2004(02):54-58. |
[6] | Radka Kalouskova;Miroslava Novotna;Zdenek Vymazal .Investigation of thermal stabilization of poly(vinyl chloride) by lead stearate and its combination with synthetic hydrotalcite[J].Polymer Degradation and Stability,2004(2):903-909. |
[7] | Yan-Bin Liu;Wei-Qu Liu;Meng-Hua Hou .Metal dicarboxylates as thermal stabilizers for PVC[J].Polymer Degradation and Stability,2007(8):1565-1571. |
[8] | 王月欣,王志岭,张倩,王辰伟,李艳星.含稀土的N-环己基马来酰亚胺耐热改性剂在PVC中的应用[J].高分子材料科学与工程,2008(11):149-152. |
[9] | Li, S.;Yao, Y. .Effect of thermal stabilizers composed of zinc barbiturate and calcium stearate for rigid poly(vinyl chloride)[J].Polymer Degradation and Stability,2011(4):637-641. |
[10] | 严海彪,刘庆丰,陈艳林.PVC新型无毒热稳定剂研究进展[J].聚氯乙烯,2005(06):7-9,29. |
[11] | Theresa Obuajulu Egbuchunam;Devrim Balkoese;Felix Ebhodaghe Okieimen .Effect of zinc soaps of rubber seed oil (RSO) and/or epoxidised rubber seed oil (ERSO) on the thermal stability of PVC plastigels[J].Polymer Degradation and Stability,2007(8):1572-1582. |
[12] | 徐竞,陈闻中.新型β-二酮辅助热稳定剂DBM-S和SBM-S的应用[J].塑料助剂,2009(05):28-32. |
[13] | Wang M;Xu JY;Wu H;Guo SY .Effect of pentaerythritol and organic tin with calcium/zinc stearates on the stabilization of poly(vinyl chloride)[J].Polymer Degradation and Stability,2006(9):2101-2109. |
[14] | 彭振博,胡斌,苏庆德,曲锦忠.稀土PVC稳定剂的作用机制研究[J].中国稀土学报,2003(03):255-258. |
[15] | 李玉芳.PVC稀土热稳定剂研究应用进展[J].国外塑料,2008(11):34-38. |
[16] | 赵劲松,付志敏,王栋.稀土复合稳定剂在PVC加工中的应用及稳定机理探讨[J].聚氯乙烯,2002(03):30-34. |
[17] | 稀土锡新型热稳定剂在浙江问世·硅氧烷制备新法获国家专利·吉化集团公司开工兴建4500t/a特戊酸生产项目·粉煤灰阻燃剂·PVC抗冲改性剂聚烯烃弹性体·纳米粒子成核剂·能砂磨的粘接剂·大湖公司阻燃剂和成核剂等新品·克莱恩新增一批磷系阻燃剂[J].塑料助剂,2005(01):41-42. |
[18] | 吴茂英.硬脂酸稀土对PVC塑料的热稳定作用及其递变规律和机理[J].稀土,2007(03):9-12. |
[19] | 吴茂英.脂肪酸稀土用作PVC热稳定剂的热稳定性和透明性递变规律[J].稀土,1999(05):41-44. |
[20] | 刘建平,宋霞,方廉,杨锦宗.马来酸单酯稀土作为PVC热稳定剂的应用实验[J].中国塑料,2002(01):67-69. |
[21] | 曾冬铭,许志惠,舒万艮,刘又年.PVC塑料稀土复合热稳定剂的研制[J].稀土,2001(01):20-21. |
[22] | 李侃社,丁贺,闫兰英,汪晓芹,李锦,章结兵.N-苯基马来酰胺酸根合镧(Ⅲ)的合成及对PVC的热稳定作用[J].中国稀土学报,2009(04):460-463. |
[23] | 佘晓燕.马来酸单双酚A酯稀土的合成及热稳定性的研究[J].广州化工,2008(05):61-64. |
[24] | 李良波,郭连波,孟平蕊,刘来涛.稀土稳定剂的制备与应用[J].塑料科技,2007(07):86-90. |
[25] | 丁贺 .PVC新型稀土热稳定剂的合成与应用研究[D].西安科技大学,2008. |
[26] | 刘二烈,李响,徐晓楠,徐文国.一种新型稀土热稳定剂的合成与应用研究[J].塑料,2006(03):56-58. |
[27] | 刘乃亮,齐暑华,吴波,杨贵忠,杨辉,卢文书,李梦韬,许灯顺.硬脂酸稀土稳定剂的制备与复配应用[J].化学与黏合,2010(04):68-71. |
[28] | GUO Yong,ZHENG Yuying,QIU Shangchang,ZENG Anran,LI Baoming.Metal lanolin fatty acid as novel thermal stabilizers for rigid poly(vinyl chloride)[J].稀土学报(英文版),2011(05):401-406. |
[29] | 刘佳,蒋平平,刘小林,徐会志,汪佳二.稀土类PVC热稳定剂--镧、铈、镨盐的性能研究[J].塑料科技,2009(04):78-82. |
[30] | 田美珠,秦梅,王振华.巯基乙酸稀土的合成及其应用研究[J].化学工程师,2006(03):6-8. |
[31] | Fang, L;Song, YH;Zhu, XN;Zheng, Q .Influence of lanthanum stearate as a co-stabilizer on stabilization efficiency of calcium/zinc stabilizers to polyvinyl chloride[J].Polymer Degradation and Stability,2009(5):845-850. |
[32] | 谌伟庆,刘珊,陈义旺,石秋杰.水杨酸镧热稳定剂对PVC塑料热稳定性的影响及其机理研究[J].稀土,2009(01):49-52. |
[33] | 宫耀华,吴建军,罗筑,鲁圣军,于杰,王丽娥,徐明.钙锌/稀土复合稳定剂对PVC热稳定性能的影响[J].聚氯乙烯,2009(05):33-34,44. |
[34] | 张伟,郭文龙,魏忠,贾鑫,马彦青.纳米巯基乙酸镧热稳定剂的合成、表征及热、力学性能研究[J].石河子大学学报(自然科学版),2012(02):235-238. |
[35] | 周喜,韩晓英.我国稀土产业现状及发展趋势(上)[J].稀土,2010(05):96-101. |
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