材料期刊网

Y2O3: Eu nanocrystals were synthesized by EDTA complexing sol-gel process at a relatively low temperature, in which ethylen-diamine-tetraacetic acid (EDTA) and polyethylene glycol (PEG) were used as the chelating agent and polymerization agent respectively. Formation process of Y2O3:Eu and structure characterization were carried out by TG-DTA, XRD, SEM/EDX. The results show that pure cubic phase Y2O3: Eu nanocrystalsere is produced after the precursor calcinated at 600 ℃ for 2 h, and the crystallinity increases with increasing calcination temperature. The nanoparticles of the Y2O3: Eu are basically spherical in shape. The mean particle size increases from about 30 to 70 nm when the calcination temperature increases from 600 to 1000 ℃. The luminescent properties of phosphor were analyzed by measuring the excitation and emission spectra. The main emission peak of the sample is around 612 nm, resulting in a red emission. The emission intensity increases with the calcination temperature. Compared with microsized Y2O3: Eu phosphors prepared by a conventional method, nanosized Y2O3: Eu synthesized by the present work, gives and a clear red shift in the emission spectrum. Moreover, the quenching concentration of Eu is raised.