用共沉淀法制备了发绿光的SrAl2O4:Eu2+,Dy3+纳米长余辉发光粉体.用TG-DSC,XRD,SEM和荧光分光光度计等对发光粉体特性进行了表征.结果表明,在1150℃煅烧温度下合成了单相的SrAl2O4发光粉体,发光粉体的形貌为粒状,平均粒径为100 nm.在可见光(波长400 nm)激发下,SrAl2O4:Eu2+,Dy3+纳米发光粉体的发射光谱为峰值位于512 nm的绿色宽带谱.与固相法合成的发光材料相比,发光粉体的激发光谱和发射光谱均发生了蓝移.并探讨了合成温度对发光粉体发光性能的影响.
参考文献
[1] | Palilla F C;Levine A K;Tomkus M R .[J].Journal of Electrochem Soe,1968,115(06):642. |
[2] | Matusuazawa T;Aoki Y;Takeuchi N et al.[J].Journal of the Electrochemical Society,1996,143(08):2670. |
[3] | Jia WY.;Lu LZ.;Liu HM.;Yen WM.;Yuan HB. .Phosphorescent dynamics in SrAl2O4 : Eu2+, Dy3+ single crystal fibers[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1998(0):424-428. |
[4] | Katsumata T;Nabae T;Sasajima K .[J].Journal of the Electrochemical Society,1997,144(09):243. |
[5] | 张平,徐明霞,沈毅,秦宇星.添加剂对SrAl2O4:Eu,Dy纳米晶形貌和发光性能的影响[J].稀有金属材料与工程,2005(z1):89-92. |
[6] | Takahashi H;Tanabe S;Hanada T .[J].Journal of the Ceramic Society of Japan,1996,104(04):322. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%