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针对柴油中含量较高的加氢以及分子筛吸附难以脱除的多环噻吩类硫化物,活性炭展现了极好的吸附脱硫性能.就构效关系、活性炭表面改性及机理等方面综述了活性炭对多环噻吩硫吸附的研究进展.对于柴油中分子尺寸较大的多环噻吩硫,活性炭中孔部分起着重要的吸附作用;活性炭表面酸性含氧基团能促进其对噻吩硫的吸附,通过表面负载金属离子和表面氧化改性,能提高其吸附容量及选择性.因此,为了早日实现活性炭吸附脱硫的工业化应用,应进一步加强中孔活性炭的制备、表面改性以及孔和化学性质的协同作用等方面的研究.

参考文献

[1] Chunshan Song;Xiaoliang Ma .New design approaches to ultra-clean diesel fuels by deep desulfurization and deep dearomatization[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(1/2):207-238.
[2] Babich I V;Moulijin J A .Science and technology of novel process for deep desulfurization of oil refinery streams:a review[J].Fuel,2003,82:607-631.
[3] 孙志娟,余谟鑫,张心亚,陈焕钦.油品中噻吩类硫化物脱除技术研究进展[J].化工进展,2005(09):1002-1005,1010.
[4] Yang RT.;Hernandez-Maldonado AJ.;Yang FH. .Desulfurization of transportation fuels with zeolites under ambient conditions[J].Science,2003(5629):79-81.
[5] Hernandez-Maldonado A J;Yang F H;Qi G S et al.Desulfurization of transportation fuels by orbents:Cu (Ⅰ)-,Ni(Ⅱ)-,and Zn(Ⅱ)-zeolites[J].Appl Catal B:Enviro,2005,56:111-126.
[6] Xiaoling Ma;Lu Sun .A new approach to deep desulfurization of gasoline, diesel fuel and jet fuel by selective adsorption for ultra-clean fuels and for fuel cell applications[J].Catalysis Today,2002(1/2):107-116.
[7] Velu S;Ma X L;Song C S et al.Desulfuriation of JP-8 Jet fuel by selective adsorption over a Ni-based adsorbent for micro solid oxide fuel cells[J].Energy and Fuels,2005,19:1116-1125.
[8] Zhou A N;Ma X L;Song C S .Liquid-phase adsorption of multi-ring thiophenic sulfur compounds on carbon materials with different surface properties[J].Journal of Physical Chemistry B,2006,110:4699-4707.
[9] 余谟鑫,姬乔娜,方媛,宋国胜,李忠.活性炭催化氧化脱除汽油和柴油中噻吩类硫化物的选择性[J].化工学报,2009(04):1007-1016.
[10] Shaker Haji;Can Erkey .Removal of dibenzothiophene from Model Diesel by Adsorption on Carbon Aerogels for Fuel Cell Applications[J].Industrial & Engineering Chemistry Research,2003(26):6933-6937.
[11] Jae Hyung Kim;Xiaoliang Ma;Anning Zhou;Chunshan Song .Ultra-deep desulfurization and denitrogenation of diesel fuel by selective adsorption over three different adsorbents:A study on adsorptive selectivity and mechanism[J].Catalysis Today,2006(1/2):74-83.
[12] Xue M;Chitrakar R;Sakane K;Hirotsu T;Ooi K;Yoshimura Y;Toba M;Feng Q .Preparation of cerium-loaded Y-zeolites for removal of organic sulfur compounds from hydrodesulfurizated gasoline and diesel oil[J].Journal of Colloid and Interface Science,2006(2):535-542.
[13] Shalaby C;Ma X L;Song C S.Adsorptive desulfurization of diesel fuels by surface modified activated carbons[J].Prepr Pap-Am Chem Soc Div Pet Chem,2008
[14] Mykola Seredych;Jakub Lison;Urs Jans .Textural and chemical factors affecting adsorption capacity of activated carbon in highly efficient desulfurization of diesel fuel[J].Carbon,2009(10):2491-2500.
[15] Jing Xiao;Xiaoliang Ma;Chunshan Song .Effects of Aromatics, Diesel Additives, Nitrogen Compounds, and Moisture on Adsorptive Desulfurization of Diesel Fuel over Activated Carbon[J].Industrial & Engineering Chemistry Research,2012(8):3436-3443.
[16] Zhou A N;Ma X L;Song C S .Effect of oxidative modification of carbon surface on the adsorption of sulfur compounds in diesel fuel[J].Appl Catal B:Enviro,2009,87:190-199.
[17] Cigdem Shalaby;Xiaoliang Ma;Anning Zhou;Chunshan Song .Preparation of Organic Sulfur Adsorbent from Coal for Adsorption of Dibenzothiophene-type Compounds in Diesel Fuel[J].Energy & Fuels,2009(3):2620-2627.
[18] Moxin Yu;Zhong Li;Qiaona Ji .Effect of thermal oxidation of activated carbon surface on its adsorption towards dibenzothiophene[J].Chemical engineering journal,2009(2/3):242-247.
[19] Chang Yu;Jie Shan Qiu;Yu Feng Sun;Xian Hui Li;Gang Chen;Zong Bin Zhao .Adsorption removal of thiophene and dibenzothiophene from oils with activated carbon as adsorbent: effect of surface chemistry[J].Journal of porous materials,2008(2):151-157.
[20] Zong X J;Yan L;Xiu P S et al.Adsorption of dibenzothiophene on modified activated carbon for ultra-deep desulfurization of fuel oils[J].Chinese Journal of Catalysis,2003,24:649-650.
[21] Sano Y;Choi K H;Korai Y et al.Selection and further activation of activated carbons for removal of Nitrogen species in gas oil as a pretreatment for its deep hydrodesulfurization[J].Energy and Fuels,2004,18:644-651.
[22] 于畅,李贤辉,邱介山,孙玉峰.活性炭液相吸附去除噻吩硫化物的研究[J].燃料化学学报,2007(01):121-124.
[23] Zhang W;Liu H Y;Xia Q B et al.Enhancement of dibenzothiophnene adsorption on activated carbons by surface modification using low temperature oxygen plasma[J].Chemical Engineering Journal,2012,209:597-600.
[24] Yu M X;Li Z;Xi H X et al.Activation energy of desorption of dibenzothiophene on modified activated carbon by loading metal ions[J].Chemical Engineering Journal,2007,132:233-239.
[25] 余谟鑫,李忠,夏启斌,奚红霞.活性炭表面负载金属离子对其吸附苯并噻吩的影响[J].化工学报,2006(08):1943-1948.
[26] 余谟鑫,李忠,夏启斌,王书文.表面负载不同金属离子的活性炭吸附二苯并噻吩[J].功能材料,2006(11):1816-1818.
[27] Wang YH;Yang RT .Desulfurization of liquid fuels by adsorption on carbon-based sorbents and ultrasound-assisted sorbent regeneration[J].Langmuir: The ACS Journal of Surfaces and Colloids,2007(7):3825-3831.
[28] Enrique Vilarrasa-Garcia;Antonia Infantes-Molina;Ramon Moreno-Tost;Enrique Rodriguez-Castellon;Antonio Jimenez-Lopez;Celio L. Cavalcante Jr.;Diana C. S. Azevedo .Thiophene Adsorption on Microporous Activated Carbons Impregnated with PdCl_2[J].Energy & Fuels,2010(May/Jun.):3436-3442.
[29] Wang YH;Yang FH;Yang RT;Heinzel JM;Nickens AD .Desulfurization of high-sulfur jet fuel by pi-complexation with copper and palladium halide sorbents[J].Industrial & Engineering Chemistry Research,2006(22):7649-7655.
[30] V. Selvavathi;V. Chidambaram;A. Meenakshisundaram .Adsorptive desulfurization of diesel on activated carbon and nickel supported systems[J].Catalysis Today,2009(1/2):99-102.
[31] Hernandez, S.P.;Fino, D.;Russo, N. .High performance sorbents for diesel oil desulfurization[J].Chemical Engineering Science,2010(1):603-609.
[32] C.O. Ania;T.J. Bandosz .Metal-loaded polystyrene-based activated carbons as dibenzothiophene removal media via reactive adsorption[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(12):2404-2412.
[33] Mykola Seredych;Teresa J. Bandosz .Adsorption of dibenzothiophenes on activated carbons with copper and iron deposited on their surfaces[J].Fuel Processing Technology,2010(6):693-701.
[34] Mao L;Wang Y;Hu X .π-π stacking interactions in the peridinin-chlorophyll-protein of amphidinium carterae[J].Journal of Physical Chemistry B,2003,107:3963-3971.
[35] JP2Tsuzuki S;Honda K;Azumi R .Model chemistry calculations of thiophene dimer interactions:origin of π-stacking[J].Journal of the American Chemical Society,2002,124:12200-12209.
[36] Jie Bu;Gabriel Loh;Chuandayani Gunawan Gwie .Desulfurization of diesel fuels by selective adsorption on activated carbons: Competitive adsorption of polycyclic aromatic sulfur heterocycles and polycyclic aromatic hydrocarbons[J].Chemical engineering journal,2011(1):207-217.
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