MgFe2O4耐酸耐碱,但目前还未见将其制成镁合金防腐蚀涂层的报道。采用溶胶.凝胶法在AZ91镁合金表面制备了MgFe:O。薄膜,利用正交试验研究了镀膜层数、溶胶中Mg2+与Fe3+的摩尔比、烧结温度、烧结时间对AZ91镁合金膜试样自腐蚀电流密度的影响,得出最优方案,并研究了优化条件制备的膜试样的组织结构及耐蚀性。结果表明:各因素对AZ91镁合金膜试样自腐蚀电流密度的影响程度由大到小依次是镀膜层数、烧结温度、nMg3+/nFe3+、烧结时间;最优条件是镀膜1层,nMg2+/nFe3+=0.35,烧结温度400℃,烧结时间5h;与AZ91镁合金基体相比,优化条件制备的MgFe20。薄膜的自腐蚀电流密度降低了1个数量级,自腐蚀电位正移了690mV,耐腐蚀性能得到很大提高。
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