以联苯二胺及二甲基联苯二胺为原料,合成了相应的N,N'-二氯联苯醌胺单体,并以二价镍配合物为催化剂与二连噻吩共聚得到了相应的交替共聚物.所得聚合物通过FT-IR,1H-NMR进行了表征.所得聚合物紫外-可见光谱分别在330、437、327、410nm处最大吸收峰出现.所得聚合物在-0.1～0.8V之间进行循环伏安分析,每一个聚合物都观察到两对氧化峰和还原峰分别在(Epa=0.40V/Epc=0.31V和Epa=0.70V/Epc=0.56V)和(Epa=0.33V/Epc=0.28V和Epa=0.63V/Epc=0.50V).
参考文献
| [1] | Li X G;Hua Y M;Huang M R .[J].Chemistry-A European Journal,2005,11:4247. |
| [2] | Arias-Pardilla J;Salavagione HJ;Barbero C;Morallon E;Vazquez JL .Study of the chemical copolymerization of 2-aminoterephthalic acid and aniline. Synthesis and copolymer properties[J].European Polymer Journal,2006(7):1521-1532. |
| [3] | Yang Yifei;Mu Shaolin .[J].Electrochimica Acta,2008,54:506-512. |
| [4] | Ayad MM;Salahuddin NA;Abou-Seif AK;Alghaysh MO .Chemical synthesis and characterization of aniline and o-anthranilic acid copolymer[J].European Polymer Journal,2008(2):426-435. |
| [5] | Chen Chuanxiang;Sun Cheng;Gao Yuhua .[J].Electrochimica Acta,2008,53:3021-3028. |
| [6] | Baibarac M.;Baltog I.;Lefrant S.;Mevellec JY.;Chauvet O. .Polyaniline and carbon nanotubes based composites containing whole units and fragments of nanotubes[J].Chemistry of Materials,2003(21):4149-4156. |
| [7] | 陈润峰;李新贵;赵红 .[J].高分子材料科学与工程,2005,19(03):6-11. |
| [8] | 井新利,赵卫兵,王杨勇.苯胺与二苯胺共聚物的合成与表征[J].功能材料,2003(03):328-330,333. |
| [9] | Yamamoto T;Nurulla I .[J].Japanese Journal of Applied Physics,1999,38:892-894. |
| [10] | Yamamoto T;Nurulla I;Ushiro A .[J].Tetrahed Let,2001,42:8653-8656. |
| [11] | Yamamoto T;Koizumi T .[J].Polymer,2007,48:5449-5472. |
| [12] | 吐尼莎古丽·阿吾提,吐尔逊·阿不都热依木,买苏尔·米吉提,司马义·努尔拉.联苯胺类共轭共聚物的金属配合物催化法合成及性质[J].高分子学报,2005(02):167-171. |
| [13] | Moon D K;Osakada K;Maruyama T et al.[J].Macromolecules,1993,26:6992-6997. |
| [14] | 封伟,韦玮,王辉,吴洪才.聚苯胺的光学吸收及其染料增感作用研究[J].高分子材料科学与工程,2000(05):85-87,91. |
| [15] | Eramo F D';Arévalo A H;Silber J J .[J].Journal of Electroanalytical Chemistry,1995,382:85-95. |
| [16] | Ren Bin;Huang He;Yu Huangzhong et al.[J].Chinese Juornal of Spectroscopy Laboratory,2002,19(01):23-27. |
| [17] | Chung C Y;Wen T C;Gopalan A .[J].Electrochimica Acta,2001,47:423-431. |
| [18] | Sieng W M;Chen W T;Gopalan A .[J].Journal of the Electrochemical Society,2001,148:65-73. |
| [19] | Kim SB.;Yamamoto T.;Harada K. .Preparation of poly(diphenylamine-4,4 '-diyl) and related random copolymers by organometallic polycondensation. Electrical, electrochemical, and optical properties[J].Macromolecules,1998(4):988-993. |
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