通过膨胀率和粉碎后-150 μm粉末产率系统研究了高温法和微波法对蛭石膨胀性能及脆性的影响规律,采用X射线衍射及热重-差示扫描量热法分析蛭石热膨胀过程中物相变化规律,并对影响膨胀蛭石脆性指标的机理进行探讨.结果表明,蛭石在高温膨胀过程中,由于层间水的迅速失去,膨胀率逐渐增大,当蛭石失去结构水时,-150 μm粉末产率迅速增加导致产品脆性性能下降,最终蛭石转变为镁橄榄石,膨胀率和粉末产率急剧下降;微波法对蛭石结构水无较大影响,产品不发脆.
参考文献
[1] | 杜彦召;陈朝阳;范艳伟;王军华.高膨胀率蛭石制备新工艺研究[J].矿产保护与利用,2008(3):13-17. |
[2] | Celia Marcos;Irene Rodriguez.Expansibility of vermiculites irradiated with microwaves[J].Applied clay science,20111/2(1/2):33-37. |
[3] | A. Obut;I. Girgin.Hydrogen peroxide exfoliation of vermiculite and phlogopite[J].Minerals Engineering,20029(9):683-687. |
[4] | Hillier, S.;Marwa, E. M. M.;Rice, C. M..On the mechanism of exfoliation of 'Vermiculite'[J].Clay Minerals: Journal of the Clay Minerals Group of the Mineralogical Society,20134(4):563-582. |
[5] | Celia Marcos;Irene Rodriguez.Exfoliation of vermiculites with chemical treatment using hydrogen peroxide and thermal treatment using microwaves[J].Applied clay science,2014Jan.(Jan.):219-227. |
[6] | M.F. Brigatti;S. Colonna;D. Malferrari;L. Medici;L. Poppi.Mercury adsorption by montmorillonite and vermiculite: a combined XRD, TG-MS, and EXAFS study[J].Applied clay science,20051/4(1/4):1-8. |
[7] | X-ray Diffraction Studies Of The Thermal Behaviour Of Commercial Vermiculites[J].Applied clay science,20093/4(3/4):368-378. |
[8] | 苗朝 .柔性膨胀蛭石节能材料的制备与研究[D].西南科技大学,2010. |
[9] | 胡光锁;李政一;朱永平;张伟刚.高膨胀率高质量蛭石粉体研制--Ⅱ.蛭石热膨胀过程[J].过程工程学报,2006(5):763-767. |
[10] | 杜彦召;陈朝阳;陈运法;张伟岗;范艳伟;张冬梅;刘艳平.尉犁蛭石微波膨胀试验研究[J].非金属矿,2007(5):4-6. |
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