过渡金属掺杂ZnO稀磁半导体的发光特性

材料导报, 2010, 24(19): 27-48.

过渡金属掺杂ZnO稀磁半导体的发光特性

徐明 ^1, , 胡志刚 ^2, , 吴艳南 ^3, , 周海平 ^4, , 徐禄祥 ^5, , 周勋 ^6,

1.四川师范大学物理与电子工程学院固体物理研究所,成都,610068

2.四川师范大学物理与电子工程学院固体物理研究所,成都,610068

3.四川师范大学物理与电子工程学院固体物理研究所,成都,610068

4.四川师范大学物理与电子工程学院固体物理研究所,成都,610068

5.四川师范大学物理与电子工程学院固体物理研究所,成都,610068

6.贵州师范大学物理与电子科学学院,贵阳,550001

基金项目: 贵州省科学技术基金(黔科通J合[2006]2004) 四川省教育厅基金(2006B033;2006C020)

关键词： ZnO , 稀磁半导体 , 过渡金属 , 掺杂 , 发光

Luminescent Properties of Transition-metal-doped ZnO Diluted Magnetic Semiconductors

ZnO是一种宽带隙Ⅱ-Ⅵ族半导体,具有良好的光电耦合特性和稳定性,在光、电、磁功能集成等新型器件方面可获得重要应用.近来的研究表明,过渡金属掺杂的ZnO基半导体有望成为实现高居里温度稀磁半导体的候选材料,是目前研究的热点.总结了近几年人们在Fe、Co、Ni、Cu、Mn等过渡金属掺杂的ZnO基稀磁半导体的发光特性研究结果,讨论了过渡金属掺杂后ZnO中观察到的可见发光机制,分析认为过渡金属掺杂ZnO的可见光发射主要与这些发光过渡金属引入后所产生的缺陷有关,而紫外发光峰的变化则与过渡金属掺入后ZnO晶体质量与禁带宽度的改变相关.

参考文献

[1]	Kwang Joo Kim;Young Ran Park .Large and abrupt optical band gap variation in In-doped ZnO[J].Applied physics letters,2001(4):475-477.
[2]	Tang ZK.;Yu P.;Kawasaki M.;Ohtomo A.;Koinuma H.;Segawa Y.;Wong GKL. .Room-temperature ultraviolet laser emission from self-assembled ZnO microcrystallite thin films[J].Applied physics letters,1998(25):3270-3272.
[3]	Service R F .Will UV lasers beat the blues[J].Science,1997,276(09):895.
[4]	Dietl T;Ohno H;Matsukura F et al.Zener model description of ferromagnetism in zinc-blende magnetic semiconductors[J].Science,2000,287(11):1019.
[5]	Pearton S J;Norton D P;Ip K et al.Recent progresses in processing and properties of ZnO[J].Progress in Materials Science,2005,50(03):293.
[6]	U. Ozgur;Ya. I. Alivov;C. Liu;A. Teke;M. A. Reshchikov;S. Dogan;V. Avrutin;S.-J. Cho;H. Morkoc .A comprehensive review of ZnO materials and devices[J].Journal of Applied Physics,2005(4)
[7]	Liu C;Yun F;Morkoc H .Ferromagnetism of ZnO and GaN: A review[J].Journal of Materials Science. Materials in Electronics,2005(9):555-597.
[8]	Janisch R;Gopal P;Spaldin NA .Transition metal-doped TiO2 and ZnO - present status of the field[J].Journal of Physics. Condensed Matter,2005(27):R657-R689.
[9]	王爱华,张丽伟,张兵临,姚宁.过渡金属掺杂ZnO稀磁半导体铁磁特性研究进展[J].人工晶体学报,2008(01):114-123.
[10]	Farley NRS.;Staddon CR.;Zhao LX.;Edmonds KW.;Gallagher BL.;Gregory DH. .Sol-gel formation of ordered nanostructured doped ZnO films[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2004(7):1087-1092.
[11]	马勇,王万录,廖克俊,吕建伟,孙晓楠.ZnO薄膜的光致发光[J].功能材料,2004(02):139-141,144.
[12]	肖宗湖,张萌.ZnO薄膜结构缺陷与发光性能研究（一）[J].人工晶体学报,2006(06):1322-1327,1331.
[13]	叶志镇,陈汉鸿,刘榕,张昊翔,赵炳辉.直流磁控溅射ZnO薄膜的结构和室温PL谱[J].半导体学报,2001(08):1015-1018.
[14]	Liu M;Kitai A H;Mascher P .Point defects and lumine-scence centers in zinc oxide doped with manganese[J].Journal of Luminescence,1992,54(11):35.
[15]	Jin B J;Im S;Lee S Y .Violet and UV luminescence emitted from ZnO thin films grown on sapphire by pulsed laser deposition[J].Thin Solid Films,2000,366(1-2):107.
[16]	Bae S H;Lee S Y;Kim H Y et al.Effects of post-annealing treatment on the light emission properties of ZnO thin films on Si[J].Optical Materials,2001,17(1-2):327.
[17]	王晶,张希清,腾小瑛,熊德平,林鹏,王丽,黄世华.磁控溅射制备ZnO薄膜的受激发射特性的研究[J].光谱学与光谱分析,2004(07):775-778.
[18]	张德恒,王卿璞,薛忠营.不同衬底上的ZnO薄膜紫外光致发光[J].物理学报,2003(06):1484-1487.
[19]	刘益春,张喜田,张吉英,吕有明,孔祥贵,申德振,范希武.氧化锌可见区发光机制[J].发光学报,2002(06):563-569.
[20]	徐彭寿,孙玉明,施朝淑,徐法强,潘海斌.ZnO及其缺陷的电子结构[J].中国科学A辑,2001(04):358-365.
[21]	Vanheusdenk;Seager C H;Warrmen W L et al.Correlation between photoluminescence and oxygen vacancies in ZnO phosphors[J].Applied Physics Letters,1996,68(03):403.
[22]	Minami T;Nanto H;Takata S .UV emission from sputtered zinc oxide thin films[J].Thin Solid Films,1983,109(04):379.
[23]	修向前,张荣,徐晓峰,俞慧强,陈丽星,施毅,郑有炓.溶胶-凝胶法制备ZnO基稀释磁性半导体薄膜[J].高技术通讯,2003(03):64-66.
[24]	李金华,张吉英,赵东旭,张振中,吕有明,申德振,范希武.Fe掺杂ZnO纳米薄膜的光致发光[J].发光学报,2006(06):976-980.
[25]	Photoluminescence and damage recovery studies in Fe-implanted ZnO single crystals[J].Journal of Applied Physics,2003(11):8995-9000.
[26]	杨霞,徐晓峰,梁二军,龚玉武.ZnO：Fe薄膜制备、光学与电学性质研究[J].光散射学报,2007(01):60-64.
[27]	Z. C. Chen;L. J. Zhuge;X. M. Wu;Y. D. Meng .Initial study on the structure and optical properties of Zn_(1-x)Fe_xO films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2007(13):5462-5465.
[28]	Chen AJ;Wu XM;Sha ZD;Zhuge LJ;Meng YD .Structure and photoluminescence properties of Fe-doped ZnO thin films[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,2006(22):4762-4765.
[29]	王凯,周祚万,刘国梅,李艳霞.Fe掺杂T-ZnO的结构和绿光发光性质研究[J].功能材料,2006(06):867-869.
[30]	Kenji Ueda;Hitoshi Tabata;Tomoji Kawai .Magnetic and electric properties of transition-metal-doped ZnO films[J].Applied physics letters,2001(7):988-990.
[31]	Y.M. Kim;M. Yoon;I.-W. Park;Y.J. Park;Jong H. Lyou .Synthesis and magnetic properties of Zn_(1-x)Mn_xO films prepared by the sol-gel method[J].Solid State Communications,2004(3):175-178.
[32]	Wu HZ.;Qiu DJ.;Cai YJ.;Xu XL.;Chen NB. .Optical studies of ZnO quantum dots grown on Si(001)[J].Journal of Crystal Growth,2002(1/2):50-55.
[33]	Samanta K;Bhattacharya P;Katiyar R S .Optical properties of ZnCoO thin films grown on Al2O3 (0001) substrates[J].Applied Physics Letters,2005,87(10):101903.
[34]	温晓莉,陈长乐,陈钊,张利学,牛利伟,高国棉.Mn、Co掺杂ZnO薄膜结构及发光特性研究[J].功能材料,2007(04):559-561.
[35]	刘学超,施尔畏,宋力昕,张华伟,陈之战.固相反应法制备Co掺杂ZnO的磁性和光学性能研究[J].物理学报,2006(05):2557-2561.
[36]	Hung-Ta Lin;Tsung-Shune Chin;Jhy-Chau Shih;Show-Hau Lin;Tzay-Ming Hong;Rong-Tan Huang;Fu-Rong Chen;Ji-Jung Kai .Enhancement of ferromagnetic properties in Zn_(1-x)Co_(x)O by additional Cu doping[J].Applied physics letters,2004(4):621-623.
[37]	Bylander E G .Surface effects on the low-energy cathodoluminescence of zinc oxide[J].Journal of Applied Physics,1978,49(03):1188.
[38]	王卿璞,张德恒,马洪磊,张兴华,张锡健.射频磁控溅射法制备ZnO薄膜的绿光发射[J].发光学报,2004(03):291-294.
[39]	林碧霞,傅竹西,贾云波,廖桂红.非掺杂ZnO薄膜中紫外与绿色发光中心[J].物理学报,2001(11):2208-2211.
[40]	Koidl P .Optical absorption of Co2+ in ZnO[J].Physical Review B:Condensed Matter,1977,15(05):2493.
[41]	杨景景,方庆清,王保明,王翠平,周军,李雁,刘艳美,吕庆荣.Co掺杂对ZnO薄膜结构和性能的影响[J].物理学报,2007(02):1116-1120.
[42]	Cui J;Gibson U .Thermal modification of magnetism in cobalt-doped ZnO nanowires grown at low temperatures[J].Physical review, B. Condensed matter and materials physics,2006(4):5416-1-5416-8-0.
[43]	曹志峰,张娟,孙元平,李剑平,徐宝龙.Co2+掺杂ZnO纳米线的制备与光学特性的研究[J].功能材料,2008(02):305-306,310.
[44]	Lommens P;Smet P F;Donega C de M et al.Photoluminescence properties of Co2+-doped ZnO nanocrystals[J].Journal of Luminescence,1996,118(02):245.
[45]	Qiu DJ.;Wu HZ.;Feng AM.;Lao YF.;Chen NB.;Xu TN. .Annealing effects on the microstructure and photoluminescence properties of Ni-doped ZnO films[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2004(1/4):263-268.
[46]	刘晓雪,程文娟,马学鸣,石旺舟.Ni掺杂ZnO薄膜的荧光特性[J].光谱学与光谱分析,2006(11):2069-2071.
[47]	Y. B. Zhang;S. Li .Distinct spins of substituent Co in polycrystalline Co- and Cu-codoped ZnO magnetic semiconductors[J].Applied physics letters,2008(4):042511-1-042511-3-0.
[48]	朋兴平,兰伟,谭永胜,佟立国,王印月.Cu掺杂氧化锌薄膜的发光特性研究[J].物理学报,2004(08):2705-2709.
[49]	X.B. Wang;C. Song;K.W. Geng;F. Zeng F. Pan .Photoluminescence and Raman scattering of Cu-doped ZnO films prepared by magnetron sputtering[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(16):6905-6909.
[50]	Liu Z F;Shan F K;Sohn J Y et al.Photoluminescence of ZnO:Ga thin films fabricated by pulsed laser deposition technique[J].Journal of Electroceramics,2004,13:183.
[51]	李爱侠,毕红,刘艳美,吴明在.Co,Cu共掺杂ZnO薄膜的结构及发光特性[J].发光学报,2008(02):289-293.
[52]	Xu M;Zhao H;Ostrikov K et al.Effect of doping with Co and/or Cu on electronic structure and optical properties of ZnO[J].Journal of Applied Physics,2009,105:044307.
[53]	Ranjani Viswanatha;Sameer Sapra;Subhra Sen Gupta;B.Satpati;P.V.Satyam;B.N.Dev;D.D.Sarma .Synthesis and Characterization of Mn-Doped ZnO Nanocrystals[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2004(20):6303-6310.
[54]	Magnetic resonance investigation of Mn~(2+) in ZnO nanocrystals[J].Journal of Applied Physics,2003(3):1965-1968.
[55]	吴小惠;王卿璞 .溅射法生长ZnMnO薄膜的结构和光学性质[J].功能材料,2006,37:306.
[56]	孙柏,邹崇文,刘忠良,徐彭寿,张国斌.衬底温度对PLD方法生长的ZnO薄膜结构和发光特性的影响[J].无机材料学报,2006(04):1005-1010.
[57]	钟红梅,陈效双,王金斌,夏长生,王少伟,李志锋,徐文兰,陆卫.基于离子注入技术的ZnMnO半导体材料的制备及光谱表征[J].物理学报,2006(04):2073-2077.
[58]	Y. Q. Chang;D. B. Wang;X. H. Luo;X. Y. Xu;X. H. Chen;L. Li;C. P. Chen;R. M. Wang;J. Xu;D. P. Yu .Synthesis, optical, and magnetic properties of diluted magnetic semiconductor Zn_(1-x)Mn_(x)O nanowires via vapor phase growth[J].Applied physics letters,2003(19):4020-4022.
[59]	倪赛力,常永勤,多永正,张寅虎,龙毅,强文江,叶荣昌.Mn掺杂ZnO纳米线的拉曼散射和光致发光特性[J].功能材料,2007(08):1380-1382.
[60]	李金华,张吉英,赵东旭,吕有明,申德振,范希武.Mn掺杂浓度对ZnO纳米薄膜的结构和光致发光的影响[J].液晶与显示,2006(06):615-619.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网