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采用X射线衍射、电子探针和电化学测试研究了La2MgNi7.5-xC01.5A1x(x=O.0~0.5)合金的相结构和电化学性能.XRD结果和EPMA观察表明,A1替代改变了合金的物相组成和物相的丰度.LaNi3相消失,αLa2Ni7相丰度的变化表现为先增加(x从O.0~0.1)后减少(x=O.3和O.5),LaNi5相随合金中A1含量x的增加而明显增加.A1替代Ni降低了合金的最大电化学放电容量和活化性能,但明显改善了La2MgNi7.5Co1.5合金的电化学循环稳定性.

参考文献

[1] Kadir K;Sakai T;Uehara L .[J].Journal of Alloys and Compounds,1997,257(1/2):115-121.
[2] K.Kadir;T.Sakai .Structural investigation and hydrogen storage capacity of LaMg_2Ni_9 and (La_(0.65) Ca_(0.35))(Mg_(1.32) Ca_(0.68))Ni_9 of the AB_2C_9 type structure[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):112-117.
[3] K.Kadir;T.Sakai .Structural investigation and hydrogen capacity of Ymg2Ni9 and (Y0.5Ca0.5)(MgCa)Ni9: new phases in the AB2C9 system isostructural with LaMg2Ni9[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(1/2):264-270.
[4] K.Kadir;N.Kuriyama .Structural investigation and hydrogen capacity of CaMg2Ni9: a new phase in the AB2C9 system isostructural with LaMg2Ni9[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(1/2):145-154.
[5] Latroche M;Percheron-Guégan A .[J].Journal of Alloys and Compounds,2003,356/357:461-468.
[6] Pan Hongge;Liu Yongfeng;Gao Mingxia et al.[J].International Journal of Hydrogen Energy,2003,28(01):113-117.
[7] Hongge Pan;Yongfeng Liu;Mingxia Gao;Yunfeng Zhu;Yongquan Lei .The structural and electrochemical properties of La_(0.7)Mg_(0.3)(Ni_(0.85)Co_(0.15))_x (x = 3.0-5.0) hydrogen storage alloys[J].International journal of hydrogen energy,2003(11):1219-1228.
[8] Y. Liu;H. Pan;Y. Yue .Cycling durability and degradation behavior of La-Mg-Ni-Co-type metal hydride electrodes[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2005(1/2):291-299.
[9] 张绪玉,罗永春,王大辉,闫汝煦,章应,康龙.La0.67Mg0.33Ni3.0-xAlx(x=0~0.3)贮氢合金的相结构及电化学性能的研究[J].功能材料,2005(07):1034-1037,1040.
[10] X. B. Zhanga;D. Z. Sunb;W. Y. Yina;Y. J. Chaia;M. S. Zhao .Effect of La/Ce ratio on the structure and electrochemical characteristics of La{sub}(0.7-x)Ce{sub}xMg{sub}0.3Ni{sub}2.8Co{sub}0.5 (x = 0.1-0.5) hydrogen storage alloys[J].Electrochimica Acta,2005(9):1957-1964.
[11] 王大辉,吴彦军,阎汝煦,罗永春,康龙.Al替代Mg对La2MgNi7.5Al1.5贮氢合金相结构和电化学性能的影响[J].稀有金属材料与工程,2008(01):45-49.
[12] Zhang Yanghuan;Dong Xiaoping;Wang Guoqing et al.[J].Journal of Power Sources,2005,144(01):255-261.
[13] 朱春玲,阎汝煦,王大辉,康龙,章应,罗永春.表面包覆镍处理La0.67Mg0.33Ni2.5Co0.5贮氢合金电极的电化学性能[J].稀有金属材料与工程,2006(04):573-576.
[14] Wang Dahui;Luo Yongchun;Yan Ruxu et al.[J].Transactions of Nonferrous Metals Society of China,2007,17:s972-s977.
[15] Hu Weikang .[J].Journal of Alloys and Compounds,1998,279:295-300.
[16] Wu Jianmin;Li Jun;Zhang Wenpeng et al.[J].Jour-nal of Alloys and Compounds,1997,248:180-184.
[17] 罗永春,康龙,张昌青,陈剑红.稀土系贮氢三元合金的生成焓计算[J].甘肃工业大学学报,2000(01):1-5.
[18] Okada M;Kuriiwa T;Tamura T et al.[J].Journal of Alloys and Compounds,1999,293-295:130-134.
[19] Zhang Faliang;Luo Yongchun;Chen Jiangping et al.[J].Journal of Power Sources,2005,150(04):247-254.
[20] 罗永春,章应,阎汝煦,张法亮,康龙,陈剑虹.La2-xMgNi9-5x (x=0~1.0)贮氢合金的晶体结构与电化学性能研究[J].中国稀土学报,2005(01):11-15.
[21] 王大辉,吴彦军,闫汝煦,罗永春,康龙.Al替代Mg对La2MgNi7.5Co1.5贮氢合金电化学循环稳定性的影响[J].稀有金属材料与工程,2008(01):40-44.
[22] Chartouni D;Meli F;Zǔlttel A et al.[J].Journal of Alloys and Compounds,1996,241(1-2):160-116.
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