聚有机砖倍半氧烷作为分子级的有机-无机杂化材料,与一般的硅树脂相比,具有更优异的耐热性、电绝缘性、耐候性以及耐化学药品性等.综述了近期国内外聚有机硅倍半氧烷的合成方法与表征手段.重点介绍了水解法和非水解法各自的优势及特点.同时将一维微纳米材料与有机硅材料两者的特点相结合,探索了聚有机硅倍半氧烷微纳米管及微球的合成.
参考文献
| [1] | Ronald H. Baney;Maki Itoh;Akihito Sakakibara;Toshio Suzuki .Silsesquioxanes[J].Chemical Reviews,1995(5):1409-1430. |
| [2] | Li H.;Liu CQ.;Guo GQ.;Zhou XS.;Zhang JM.;Shen DY.;Zhang ZX.;Xie P. Yu SY.;Zhang RB. .Self-assembling directed synthesis of a novel terephthalamide-bridged ladderlike polysiloxane[J].Journal of Polymer Science, Part A. Polymer Chemistry,2002(18):3161-3170. |
| [3] | Liu C Q;Liu Y;Shen Z R et al.Synthesis and Characterization of Novel Alcohol-Soluble Ladderfike Poly (Silsesquioxane),Containing Side-Chain Hydroxy Groups[J].Macromolecular Chemistry and Physics,2001,202(09):1 576-1 580. |
| [4] | Taoyi Zhang;Kuilin Deng;Pingping Zhang;Ping Xie;Rongben Zhang .Supramolecular Template-Directed Synthesis of Perfect Phenelenediimino-Bridged Ladderlike Polyphenylsiloxanes[J].Chemistry: A European journal,2006(13):3630-3635. |
| [5] | Wallace WE.;Antonucci JM.;Guttman CM. .Polymeric silsesquioxanes: degree-of-intramolecular-condensation measured by mass spectrometry[J].Polymer: The International Journal for the Science and Technology of Polymers,2000(6):2219-2226. |
| [6] | Douglas A.Loy;Brigitta M.Baugher;Colleen R.Baugher;Duane A.Schneider;Kamyar Rahimian .Substituent Effects on the Sol-Gel Chemistry of Organotrialkoxysilanes[J].Chemistry of Materials,2000(12):3624-3632. |
| [7] | Sharp K G.Star AlkoxySilane Molecules,Gels and Appreciably Tough Glaeses[J].Journal of Materials Chemistry,2005(15):3 812-3 820. |
| [8] | plinio Innocenzi;Giovanna Brusatin;Florence Babonneau .Competitive Polymerization between Organic and Inorganic Networks in Hybrid Materials[J].Chemistry of Materials,2000(12):3726-3732. |
| [9] | 幸松民;王一璐.有机硅合成工艺及产品应用[M].北京:化学工业出版社,2001 |
| [10] | Hanjiang Dong;Manho Lee;Ruthanne D.Thomas;Zhengping Zhang;R.F.Reidy;D.W.Mueller .Methyltrimethoxysilane sol-gel polymerization in acidic ethanol solutions studied by ~(29)Si NMR spectroscopy[J].Journal of Sol-Gel Science and Technology,2003(1):5-14. |
| [11] | Libor Matejka;Oxana Dukh;Drahomira Hlavata;Bohumil Meissner;Jiri Brus .Cyclization and Self-Organization in Polymerization of Trialkoxysilanes[J].Macromolecules,2001(20):6904-6914. |
| [12] | Dong H;Reidy F;Brennan J D .Shrinkage and Springhack Behavior of Methylsilsesquioxanes Prepared by an Acid/Base Two -Step Processing Procedure[J].Chemistry of Materials,2005,17(24):6 012-6 017. |
| [13] | Dong HJ;Brennan JD .Controlling the morphology of methylsilsesquioxane monoliths using a two-step processing method[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(2):541-546. |
| [14] | Dong H;Brennan J D .Macroperous Monolithic Methylsilse Squioxanes Prepared by Two-Step Acid/acid Processing Method[J].Chemistry of Materials,2006,18(17):4 176-4 182. |
| [15] | Dong, HJ;Brook, MA;Brennan, JD .A new route to monolithic methylsilsesquioxanes: Gelation behavior of methyltrimethoxysilane and morphology of resulting methylsilsesquioxanes under one-step and two-step processing[J].Chemistry of Materials,2005(11):2807-2816. |
| [16] | 黎白钰;徐坚 .聚甲基硅倍半氧烷制备方法[P].China,03109724.3 |
| [17] | 刘海云;徐坚 .聚有机硅倍半氧烷的制备方法[P].China,200410029146.5 |
| [18] | 戴珍;刘海云;李燕芳 et al.高纯度聚有机硅倍半氧烷的制备方法[P].China,200810074965.X |
| [19] | Lappert M F;Smith J K.Reactions of Sulphoxides with Some Group Ⅲ and Ⅳ Halides[J].Journal of the Chemical Society,1961:3 224-3 230. |
| [20] | Baesindale A R;Gentle T E.Siloxane and Hydrocarbon Octopus Molecules with Silsesquioxane Cores[J].Journal of Materials Chemistry,1993(03):1 319-1 325. |
| [21] | Voronkov MG.;Basenko SV. .FROM EPHEMERS TO MONOMERS, OLIGOMERS AND POLYMERS - NEW METHODS FOR THE GENERATION AND TRANSFORMATION OF SILANONES [Review][J].Journal of Organometallic Chemistry,1995(1/2):325-329. |
| [22] | Lu P;Paulasaari J K;Weber W P .Reaction of Dimethyldichlorosilane,Pbenylmethyldichlorosilane,or Diphenyldichlorosilane with Dimethyl Sulfoxide.Evidence for Silanone and Cyclodisiloxane Intermediates[J].Organometallics,1996,15(21):4 649-4 652. |
| [23] | Le Roux C.;Wenzel S.;Grigoras S.;Brook MA.;Yang H. .Using "anhydrous" hydrolysis to favor formation of hexamethylcyclotrisiloxane from dimethyldichlorosilane[J].Organometallics,1998(4):556-564. |
| [24] | Bassindale R;MacKinnon I A;Maesano M G.The Preparation of Hexasilsesquioxane (T6) Cages by Non Aqueous Hydrolysis of Trichiorosilanes[J].Chemical Communications,2003:1 382-1 383. |
| [25] | ANNA ARKHIREEVA;JOHN N.HAY;JACKIE M.LANE FST;MIGUEL MANZANO;HELEN MASTERS;WILBERFORCE OWARE;STEVE J.SHAW .Synthesis of Organic-Inorganic Hybrid Particles by Sol-Gel Chemistry[J].Journal of Sol-Gel Science and Technology,2004(1/3):31-36. |
| [26] | 马军;徐坚 .聚有机硅倍半氧烷及其制备方法[P].China,00130514.X,2001-02-17. |
| [27] | Park ES;Ro HW;Nguyen CV;Jaffe RL;Yoon DY .Infrared spectroscopy study of microstructures of poly(silsesquioxane)s[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(4):1548-1554. |
| [28] | Wallace W.E.;Antonucci J.M.;Guttman C.M. .Molecular structure of silsesquioxanes determined by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry[J].Journal of the American Society for Mass Spectrometry,1999(3):224-230. |
| [29] | 宋国君,李建江,佘希林.聚合物纳米管研究进展[J].高分子通报,2004(06):31-37. |
| [30] | Wesley P. Hoffman;Hong T. Phan;Phillip G. Wapner .The far-reaching nature of microtube technology[J].Materials research innovations,1998(2):87-96. |
| [31] | Han C C;Lee J T;Yang R W et al.A New and Easy Methed for Making Well-Organized Micrometer-Sized Carbon Tubes and Their Regularly Assembled Structures[J].CHEMISTRY OF MATERIALS,1999,11(07):1806-1813. |
| [32] | Mitsuhashi K;Tagami N;Tanabe K;Ohkubo T;Sakai H;Koishi M;Abe M .Synthesis of microtubes with a surface of "house of cards" structure via needlelike particles and control of their pore size[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(8):3659-3663. |
| [33] | Yang X H;Wang L;Yang S.Facile Route to Fabricate Large-Scale Silver Microtubes[J].Materials Letters,2007(61):2 904-2 907. |
| [34] | Liu H;Xu J;Li Y;Li B;Ma J;Zhang X .Fabrication and characterization of an organic-inorganic gradient surface made by polymethylsilsesquioxane (PMSQ)[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2006(18):1603-1607. |
| [35] | A.N.Shigapov;G.W.Graham;R.W.McCabe;H.K.Plummer .The preparation of high-surface area, thermally-stable, metal-oxide catalysts and supports by a cellulose templating approach[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2001(1/2):287-300. |
| [36] | Shuxia Liu;Junhui He .Facile Fabrication of Porous Titania Microtube Arrays by Replication of Human Hair[J].Journal of the American Ceramic Society,2005(12):3513-3514. |
| [37] | Davis S A;Burkett S L;Mendelson N H.Bacterial Templating of Ordered Macrostructures in Silica and Silica-Sur-factant Mesophases[J].Nature,1997(385):420-423. |
| [38] | Xiao H;Yu W;Shi M J.The Structure and Application of Kapor Fibre[J].Textile Research Journal,2005(26):4-8. |
| [39] | 罗运军;桂红星.有机硅树脂及其应用[M].北京:化学工业出版社,2002 |
| [40] | Kimura Hiroshi .Perfectly Spherical Polymethylsilsesquioxane Power and Production Therof[P].Japan,63077940,1988. |
| [41] | Noda I;Kamoto T;Sasaki Y et al.Topological Morphology of Methylsilsesquioxane Derivatives[J].CHEMISTRY OF MATERIALS,1999,11(12):3693-3701. |
| [42] | Sankaraiah S;Lee JM;Kim JH;Choi SW .Preparation and characterization of surface-functionalized polysilsesquioxane hard spheres in aqueous medium[J].Macromolecules,2008(16):6195-6204. |
| [43] | Kim YB;Kim YA;Yoon KS .Preparation of functionalized polysilsesquioxane and polysilsesquioxane-metal nanoparticle composite spheres[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2006(15):1247-1253. |
| [44] | Arkhireeva, A;Hay, JN;Manzano, M .Preparation of silsesquioxane particles via a nonhydrolytic sol-gel route[J].Chemistry of Materials,2005(4):875-880. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%