采用高频表面机械研磨方法在304不锈钢中制备出纳米晶和纳米孪晶结构.采用腐蚀失重试验和极化曲线测试等方法测试两种纳米结构304不锈钢在室温及80℃条件下5％硫酸溶液中的耐腐蚀性能,并利用透射电镜和扫描电镜分析其腐蚀性能和微观结构的关系.失重试验结果表明在80℃条件下5％硫酸溶液中,纳米孪晶比纳米晶结构的304不锈钢耐腐蚀性能好,以均匀腐蚀为主,点蚀为辅;而纳米晶则发生严重的点蚀.电化学测试结果表明:在室温条件下,纳米孪晶结构304不锈钢呈现高的自腐蚀电位和宽的钝化区间,但在80℃条件下,纳米晶和纳米孪晶结构304不锈钢的耐腐蚀性比粗晶不锈钢差.
参考文献
| [1] | 李楠,李瑛,王胜刚,王福会.轧制纳米块体304不锈钢腐蚀行为的研究Ⅰ.钝化膜耐氯离子侵蚀能力[J].中国腐蚀与防护学报,2007(02):80-83. |
| [2] | K.H. Lo;C.H. Shek;J.K.L. Lai .Recent developments in stainless steels[J].Materials Science & Engineering. R, Reports,2009(4/6):39-104. |
| [3] | X.H. CHEN;J. LU;L. LU .Tensile properties of a nanocrystalline 316L austenitic stainless steel[J].Scripta materialia,2005(10):1039-1044. |
| [4] | 曹胜男,郭志超,王光灿.低维纳米材料的制备方法与金属纳米材料[J].上海有色金属,2007(02):90-94. |
| [5] | 王宇,黄敏,毕宗岳,牛辉,高惠临.X80管线钢焊接接头表面自身纳米化[J].材料科学与工程学报,2009(03):465-468,364. |
| [6] | Wei Ye;Ying Li;Fuhui Wang .The improvement of the corrosion resistance of 309 stainless steel in the transpassive region by nano-crystallization[J].Electrochimica Acta,2009(4):1339-1349. |
| [7] | 林兰芳,戴品强,林绿波.纳米晶Ni-Co-Fe-P合金镀层在3.5wt.％NaCl溶液中的腐蚀特性[J].材料科学与工程学报,2013(02):229-234. |
| [8] | Z.J. Zheng;Y. Gao;Y. Gui;M. Zhu .Corrosion behaviour of nanocrystalline 304 stainless steel prepared by equal channel angular pressing[J].Corrosion Science,2012(Jan.):60-67. |
| [9] | 包乌日图巴雅拉,朱军,邱嘉杰.非晶及纳米晶软磁材料耐腐蚀性能的研究现状[J].上海有色金属,2008(01):32-36. |
| [10] | HAO Yun-wei,DENG Bo,ZHONG Cheng,JIANG Yi-ming,LI Jin.Effect of Surface Mechanical Attrition Treatment on Corrosion Behavior of 316 Stainless Steel[J].钢铁研究学报（英文版）,2009(02):68-72. |
| [11] | A.Q. Lü,Y. Zhang,Y. Li,G. Liu,Q.H. Zang,C.M. Liu.EFFECT OF NANOCRYSTALLINE AND TWIN BOUNDARIES ON CORROSION BEHAVIOR OF 316L STAINLESS STEEL USING SMAT[J].金属学报（英文版）,2006(03):183-189. |
| [12] | Changliang Hu;Shuang Xia;Hui Li;Tingguang Liu;Bangxin Zhou;Wenjue Chen;Ning Wang .Improving the intergranular corrosion resistance of 304 stainless steel by grain boundary network control[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2011(5):1880-1886. |
| [13] | A.Y. Chen;H.H. Ruan;J. Wang .The influence of strain rate on the microstructure transition of 304 stainless steel[J].Acta materialia,2011(9):3697-3709. |
| [14] | 林文松,周细应,王思珺,李轶.镍/碳纳米管复合镀层在NaCl和H2SO4溶液中的腐蚀特性[J].材料科学与工程学报,2005(02):218-220,229. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%