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采用分子设计的方法,合成出一种含芴基Cardo环及芳醚键结构双马来酰亚胺单体(PF-BMI),采用核磁共振法对其结构进行了表征.采用差热分析法及热重分析表征了PF-BMI/二烯丙基双酚A(DABPA)共聚物的固化行为及耐热性能,动态机械分析研究了PF-BMI/DABPA玻璃布复合物的热性能.结果表明,PF-BMI单体具有较好的溶解性能,热固化后的PF-BMI及PF-BMI/DABPA树脂均具有优异的热稳定性和较高的残炭率;PA-BM I/DABPA共聚物与玻璃布复合物的tanδ峰值达到313.8℃.

参考文献

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