目的：制备一种低温一次烧成搪瓷涂料,并研究其性能。方法调整搪瓷配方中耐火与助熔化合物的配比,细化搪瓷粉体粒度,采用低温长烧工艺制备搪瓷涂料。通过 SEM 观察瓷层的微观结合形貌,考察密着性能,最后通过柠檬酸溶液处理测试其耐酸性能。结果最佳烧成工艺参数为：烧成温度780℃,烧结时间8 min。结论涂料密着性能良好,耐酸性能良好,在保证低温烧成的情况下,搪瓷涂料具备其他良好的性能。
Objective To develop a kind of low firing non-engobe enamel and study its performance. Methods The ratio of flux-ible and refractory compound was adjusted, the particle size of enamel powder was refined and the enamel coating was prepared u-sing low-temperature long-time sintering technology. SEM was used to observe the morphology of the enamel coating and plain steel substrate to characterize its adherence. Finally, citric acid solution was used to test the acid resistance. Results The optimal pa-rameters of enamel preparation were as follows: firing time 8 min,firing temperature 780 ℃ . Conclusion This kind of enamel coat-ing has good acid corrosion resistance and adherence between enamel coating and plain steel substrate. In the premise of low sinte-ring temperature, the enamel coating also had other good performance.
参考文献
| [1] | SCRINZI E,ROSSI S . The Aesthetic and Functional Proper-ties of Enamel Coatings on Steel[J].Materials and Design,2010,31 |
| [2] | WANG De-qing . Effect of Crystallization on the Property of Hard Enamel Coating on Steel Substrate[J].Applied Sur-face Science,2009,255 |
| [3] | 韩辉,李军,焦丽娟,李楠.陶瓷-金属复合材料在防弹领域的应用研究[J].材料导报,2007(02):34-37. |
| [4] | 钱蕙春.磨加纳米二氧化硅提高铸铁搪瓷耐酸化学稳定性研究[J].上海应用技术学院学报（自然科学版）,2007(01):45-48. |
| [5] | 王德庆,李翠娥.高硬度耐热搪瓷的制备与性能[J].大连交通大学学报,2009(05):31-35,39. |
| [6] | 钱蕙春.建筑装饰平板搪瓷的发展和应用[J].玻璃与搪瓷,2010(04):40-44. |
| [7] | 陈玉华,刘颖.搪瓷（喷瓷）管道及其连接技术国内外研究现状[J].表面技术,2008(06):74-77. |
| [8] | 黄传兵,杜令忠,刘伟,张伟刚.等离子喷涂CoCrAl-B4C涂层的微观结构与性能[J].表面技术,2012(03):1-4. |
| [9] | 周学杰,张三平,付志勇,陈琳,萧弘烨,潘颖.金属喷涂层在青海盐湖水中的腐蚀初探[J].装备环境工程,2004(04):30-33. |
| [10] | 李朋,李秉忠.热喷涂铝涂层与玻璃结合机理的研究[J].装备环境工程,2009(02):36-39. |
| [11] | 王文焱,卢高,谢敬佩,王爱琴.溶胶-凝胶法在钛表面制备钛/羟基磷灰石生物涂层[J].表面技术,2011(05):21-24. |
| [12] | 温芳,林涛,刘祥庆,郭志猛.SHS合成TiC粉对铁基涂层显微组织和硬度的影响[J].表面技术,2011(04):30-33. |
| [13] | 严春进,杨峻,崔浩然.节能型搪瓷涂层烧成工艺及其性能研究[J].表面技术,2012(01):44-47. |
| [14] | 李景学,钱蕙春,蒋伟忠.低温搪瓷密着结构研究[J].上海应用技术学院学报：自然科学版,2011(02):129-132. |
| [15] | Manual Editorial Board. Daily-use Porcelain Enamel Manual [M]. Beijing:Light Industry Press,1982.,1982. |
| [16] | 手册编委会. 日用搪瓷手册[M]. 北京:轻工业出版社, 1982. ,1982. |
| [17] | 邵规贤,芶文彬. 搪瓷学 [M]. 北京:轻工业出版社, 1983. SHAO Gui-xian,GOU Wen-bin. Enamel[M]. Beijing:Light Industry Press,1983.,1983. |
| [18] | JIANG Wei-zhong,WANG Ying,DAI Qi . Influence of the Su-perfine Crystal of LI2Ni8O10 as Mill Addition on the Enamel Adherence[J].Materials Letters,2004,58 |
| [19] | 胡春和,唐电.添加稀土对瓷釉的影响[J].热处理,2001(02):16-19. |
| [20] | 王海燕,程麟.钢板处理工艺对搪瓷性能的影响[J].南京工业大学学报（自然科学版）,2008(02):90-93. |
| [21] | LEILA S . Microstructure and Adherence of Cobalt Contai-ning and Cobalt Free Enamels to Low Carbon Steel[J].Ma-terials Science and Engineering A,2007,458 |
| [22] | YANG C. The Effects of a Nickel Oxide Precoat on the Gas Bubble Structures and Fish-scaling Resistance in Vitreous Enamels[J]. Materials Science and Engineering A,2004, 366:254-261.,2004. |
- 下载量()
- 访问量()
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%