目的 拓宽碳化硅增强聚酰亚胺(SiC/PI)复合薄膜在耐磨涂层领域的应用.方法 利用流延成膜法制备SiC/PI复合薄膜,在氮气氛围中对复合薄膜进行600～1000℃的碳化处理,并对碳化后的薄膜进行SEM,XRD及FNR等测试,分析碳化过程中组织结构的变化.结果 由于SiC纳米颗粒起到物理交联点的作用,复合薄膜的热稳定性和残碳率得到提高,同时也具有了断裂塑性特征.随着碳化温度升高,复合薄膜六角碳层结构逐步完善.PI在碳化中,芳核自由基聚合成环数更多的分子,且SiC与PI的界面处产生Si-O键.结论 碳化过程中,SiC纳米粒子与PI作用形成微弱的化学键合,改善了碳膜的界面结合情况,使得其耐热性得到提高.
参考文献
| [1] | 宋晓峰.聚酰亚胺的研究与进展[J].纤维复合材料,2007(03):33-37. |
| [2] | 王振廷,秦立富.SiC颗粒表面修饰及形成机理[J].表面技术,2009(04):11-12,29. |
| [3] | 熊信柏,李贺军,黄剑锋,李克智,付业伟.生物医用碳/碳复合材料碳化硅涂层的研究[J].西北工业大学学报,2003(03):356-359. |
| [4] | 姚怀,许波,王永志.温度对碳化硅粉体表面镀镍的影响[J].表面技术,2011(06):71-73. |
| [5] | 徐中,王健,李颖.仿生涂层磨损及其与表面形貌的关联性研究[J].表面技术,2013(04):9-11,114. |
| [6] | YUDIN V E;GOYKHMAN M Y;GUBANOVA G N et al.Carbon/Carbom Composites Based on a Polyimide Matrix with Coal Tar Pitch[J].CARBON,2002,40:1427-1433. |
| [7] | MICHIO Inagaki;SUNAO Harada;TESTSUHITO Sato et al.Carbonization of Polyimide Film "Kapton"[J].CARBON,1989,27(02):253-257. |
| [8] | WU J;YANG S;HU A et al.Preparation,Morphology and Properties of Nano-sized Al2 O3/Polyimide Composite Films[J].European Polymer Journal,2005,41:73-81. |
| [9] | WANG H;ZHONG W;XU P et al.Polyimide/Silica/Titania Nanocomposites via a Novel Non-hydrolytic Sol-gelroute[J].Composites Part A: Applied Science and Manufacturing,2003,36:909-914. |
| [10] | C.Xenopoulos;L.Mascia;S.J.Shaw .Polyimide-silica hybrids derived from an isoimide oligomer precursor[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2002(2):213-218. |
| [11] | Pellegrino Musto;Giuseppe Ragosta;Gennaro Scarinzi;Leno Mascia .Toughness enhancement of polyimides by in situ generation of silica particles[J].Polymer: The International Journal for the Science and Technology of Polymers,2004(12):4265-4274. |
| [12] | 陈跃良,刘旭.聚合物基复合材料老化性能研究进展[J].装备环境工程,2010(04):49-56. |
| [13] | 龚鹏,范真,丁建宁,程广贵,袁宁一,凌智勇.氮化铜薄膜制备中氮气比例对其结构及微观力学性能的影响[J].表面技术,2013(05):15-18,31. |
| [14] | Der-Jang Liaw;Kung-Li Wang;Ying-Chi Huang .Advanced polyimide materials: Syntheses, physical properties and applications[J].Progress in Polymer Science,2012(7):907-974. |
| [15] | Hatori H.;Shiraishi M.;Yoshihara M.;Kimura T.;Yamada Y. .THE MECHANISM OF POLYIMIDE PYROLYSIS IN THE EARLY STAGE[J].Carbon: An International Journal Sponsored by the American Carbon Society,1996(2):201-208. |
| [16] | Nakahashi T.;Inagaki M.;Konno H. .Chemical state of nitrogen atoms in carbon films prepared from nitrogen-containing polymer films[J].Solid state ionics,1998(Special Issue SI):73-77. |
| [17] | Bin YZ;Oishi K;Koganemaru A;Zhu D;Matsuo M .Catalytic effect of nickel under carbonization of polyimide films[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(8):1617-1627. |
| [18] | GRIBANOV A V;SAZANOV YU N;MOKEEV M V .Role of Structural Characteristics of Aromatic Polyimides in Carbonization[J].RUSSIAN JOURNAL OF APPLIED CHEMISTRY,2002,75(04):606-610. |
| [19] | 宣剑国,许振良,殷静,冯建立.聚酰亚胺中空纤维膜的热亚胺化及碳化的研究[J].上海化工,2005(12):14-16. |
| [20] | 亓淑英,迟伟东,沈曾民.聚酰亚胺（PI）膜碳化过程中结构和性能变化研究[J].材料科学与工程学报,2007(01):115-117,101. |
| [21] | 赵根祥;贾世军;钱树安.PI膜转变为炭膜过程中的结构变化[J].炭素技术,1997(05):12-16. |
| [22] | 赵晨,陈跃良,刘旭.湿热条件下飞机聚合物基复合材料界面问题研究进展[J].装备环境工程,2012(05):62-66,117. |
| [23] | Yudin VE.;Balik K.;Glogar P.;Gubanova GN.;Kudriavtsev VV.;Goykhman MY. .Carbonization behaviour of some polyimide resins reinforced with carbon fibers[J].Carbon: An International Journal Sponsored by the American Carbon Society,2000(1):5-12. |
| [24] | 郑凤新.超硬薄膜制备技术与性能表征方法的研究进展[J].表面技术,2012(06):99-103. |
| [25] | 王冬华.高比表面积碳化硅的制备及表征[J].广州化工,2011(04):51-54. |
| [26] | 王铎 .碳化硅/聚酞亚胺基低介电常数复合材料制备与特性研究[D].西安:西安理工大学,2006. |
| [27] | 边丽娟,张灵云.碳化硅掺杂聚酰亚胺纳米复合薄膜的制备与性能研究[J].化工新型材料,2006(11):38-40. |
| [28] | 吕静,党智敏.低热膨胀系数纳米碳化硅/聚酰亚胺复合薄膜的制备与性能[J].复合材料学报,2011(05):41-45. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%