利用基于欧拉-欧拉两相流模型,建立硅烷热分解的均相和非均相反应模型,模拟了二维流态化的多晶硅化学气相沉积过程,以及硅烷、硅烯和硅沉积速率在反应器中的分布规律.模拟结果表明多晶硅的沉积主要发生在流化床中的密相区及气泡的周围,浓度相对较小的硅烯非均相反应对多晶硅沉积的贡献约为硅烷的10%.分析了硅烷入口浓度和反应温度对硅沉积速率及转化率的影响,模拟的硅沉积速率与文献中的实验数据做了比较.
参考文献
[1] | Maria P.Tejero-Ezpeleta;Sigurd Buchholz;Leslaw Mleczko .Optimization of Reaction Conditions in a Fluidized-Bed for Silane Pyrolysis[J].The Canadian Journal of Chemical Engineering,2004(3):520-529. |
[2] | White, CM;Ege, P;Ydstie, BE .Size distribution modeling for fluidized bed solar-grade silicon production[J].Powder Technology,2006(1/2):51-58. |
[3] | Cadoret L;Reuge N;Pannala S;Syamlal M;Coufort C;Caussat B .Silicon CVD on powders in fluidized bed: Experimental and multifluid Eulerian modelling study[J].Surface & Coatings Technology,2007(22/23):8919-8923. |
[4] | Caussat B;Hemati M;Couderc J P .Silicon Deposition from Silane or Disilane in a Fluidized Bed-Part Ⅱ:Theoretical Analysis and Modeling[J].Chemical Engineering Science,1995,50(22):3625-3635. |
[5] | Caussat B;Hemati M;Couderc J P .Silicon Deposition from Silane or Disilane in a Fluidized Bed-Part Ⅰ:Experimental Study[J].Chemical Engineering Science,1995,50(22):3615-3624. |
[6] | N.Reuge;L.Cadoret;B.Caussat .Multifluid Eulerian modelling of a silicon Fluidized Bed Chemical Vapor Deposition process:Analysis of various kinetic models[J].Chemical engineering journal,2009(2/3):506-516. |
[7] | V. Cocheteau;P. Mur;T. Billon .Development of an original model for the synthesis of silicon nanodots by Low Pressure Chemical Vapor Deposition[J].Chemical engineering journal,2008(1/3):600-608. |
[8] | Reuge N;Cadoret L;Coufort-Saudejaud C;Pannala S;Syamlal M;Caussat B .Multifluid Eulerian modeling of dense gas-solids fluidized bed hydrodynamics: Influence of the dissipation parameters[J].Chemical Engineering Science,2008(22):5540-5551. |
[9] | Constantin Vahlas;Brigitte Caussat;Philippe Serp;George N. Angelopoulos .Principles and applications of CVD powder technology[J].Materials Science & Engineering, R. Reports: A Review Journal,2006(1/2):1-72. |
[10] | B.Caussat;M.Hemati;J.P.Couderc .Local modeling of mass transfer with chemical reactionsin a gas-solid fluidized bed.Application to the chemical vapor deposition of silicon from silanes[J].Powder Technology,1999(1):43-55. |
[11] | Iya S K;Flagella R N;DiPaolo F S .Heterogeneous Decomposition of Silane in a Fixed Bed Reactor[J].Journal of the Electrochemical Society,1982,129:1531-1535. |
[12] | Hsu G;Hogle R;Rohatgi N et al.Fines in Fluidized Bed Silane Pyrolysis[J].Journal of the Electrochemical Society,1984,131:660-668. |
[13] | Lai S;Dudukovic M P;Ramachandran P A .Chemical Vapor Deposition and Homogeneous Nucleation in Fluidized Bed Reactors:Silicon from Silane[J].Chemical Engineering Science,1986,41(04):633-641. |
[14] | Furusawa T;Kojima T;Hiroha H .Chemical Vapor Deposition and Homogeneous Nucleation in Monosilane Pyrolysis within Interparticle SpacesApplication of Fines Formation Analysis to Fluidized Bed CVD[J].Chemical Engineering Science,1988,43(08):2037-2042. |
[15] | Ho P;Coltrin M E;Binkley J S et al.Theoretical Study of the Heats of Formation of Si2 HN (N =0-6) Compounds and Trisilane[J].Journal of Physical Chemistry,1986,90(15):3399-3406. |
[16] | Pauline Ho;Michael E Coltrin;William G Breiland .Laser-Induced Fluorescence Measurements and Kinetic Analysis of Si Atom Formation in a Rotating Disk Chemical Vapor Deposition Reactor[J].Journal of Physical Chemistry,1994,98(40):10138-10147. |
[17] | Girshick S.L.;Swihart M.T. .Numerical Modeling of Gas-Phase Nucleation and Particle Growth during Chemical Vapor Deposition of Silicon[J].Journal of the Electrochemical Society,2000(6):2303-2311. |
[18] | Guenther C;OBrien T;Syamlal M.A Numerical Model of Silane Pyrolysis in a Gas-Solids Fluidized Bed[A].New Orleans,SRP,2001:1-12. |
[19] | L Cadoret;N.Reuge;S.Pannala .Silicon Chemical Vapor Deposition on macro and submicron powders in a fluidized bed[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2009(1/2):185-191. |
[20] | H.Wiggers;R.Starke;Paul Roth .Silicon Particle Formation by Pyrolysis of Silane in a Hot Wall Gasphase Reactor[J].Chemical Engineering & Technology: Industrial Chemistry -Plant Equipment -Process Engineering -Biotechnology,2001(3):261-264. |
[21] | Syamlal M;Rogers W;O Brien T J .Mfix Documentation Theory Guide[EB/OL].http://www.mfix.org/documentation/Theory.pdf,1993. |
[22] | Hsu G;Rohatgi N;Houseman J .Silicon Particle Growth in a Fluidized-Bed Reactor[J].AICHE Journal,1987,33(05):784-791. |
[23] | Benyahia S;Syamlal M;OBrien T J .Summary of Mfix Equations 2005-4,From[Z].,2008. |
[24] | Syamlal M;Rogers W;OBrien T J .Mfix Documentation:Theory Guide[Technical Note,DOE/METC-95/1013][R].,1993. |
[25] | Mathiesen V.;Hjertager BH.;Solberg T. .An experimental and computational study of multiphase flow behavior in a circulating fluidized bed[J].International Journal of Multiphase Flow,2000(3):387-419. |
[26] | Lun C K K .Kinetic Theory for Granular Flow of Dense,Slightly Inelastic,Slightly Rough Spheres[J].Journal of Fluid Mechanics,1991,233:539-559. |
[27] | Gidaspow D.Multiphase Flow and Fluidization:Continuum and Kinetic Theory Descriptions[M].Academic Press,Inc,1994 |
[28] | Schaeffer D G .Instability in the Evolution Equations Describing Incompressible Granular Flow[J].Journal of Differential Equations,1987,66(01):19-50. |
[29] | Pauline Ho;A Balakrishna;JM Chacin.Chemical Kinetics for Modelling Silicon Epitaxy from Chlorosilanes[A].Boston,Massachusetts,1998:117-122. |
[30] | Coltrin M E;Kee R J;Miller J A .A Mathematical Model of Silicon Chemical Vapor Deposition[J].Journal of the Electrochemical Society,1986,133:1206-1210. |
[31] | Wen C Y;Chen H;Onozaki M .User's Manual for Computer Simulation and Design of the Moving-Bed Coal Gasifier[R].West Virginia Univ,Morgantown (USA).Dept.of Chemical Engineering,1982. |
[32] | Nan Xie;Francine Battaglia;Rodney O Fox .Simulations of multiphase reactive flows in fluidized beds using in situ adaptive tabulation[J].Combustion theory and modelling,2004(2):195-209. |
[33] | Guenther C;Syamlal M .The Effect of Numerical Diffusion on Isolated Bubbles in a Gas-Solid Fluidized Bed[J].Powder Technology,2001,116:142-154. |
[34] | Pierson H O.Handbook of Chemical Vapor Deposition:Principles,Technology,and Applications[M].New York:Noyes Pubns,1999:51-53. |
[35] | 李建隆;王伟文;陈光辉 等.有机硅单体合成流化床反应器的条形组合内部构件[P].CN:200720176242 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%