利用二次离子质谱仪对高压电解电容器用高纯铝箔的微量元素进行了分析,研究了微量元素含量及分布对铝箔织构及性能的影响.结果表明:铝箔中Fe、Si、Cu和Pb含量较高,Fe、Cu元素含量直接影响铝箔的电性能,而Si和Pb元素含量的变化,对铝箔的织构和电性能无直接影响.铝箔中微量元素的平均含量,是影响铝箔织构组成与最终电性能的主要因素.而Fe、Cu等微量元素在近表面深度方向上浓度梯度方向的改变和显著波动,可导致在腐蚀发孔过程中微量元素的微观作用机制发生改变,不利于隧道孔的稳定生长,也是影响铝箔最终电性能的又一个重要原因.
参考文献
[1] | Takata N;Ikeda K;Yoshida F et al.[J].Materials Transactions,2004,45(05):1687. |
[2] | Kobayashi M;Takayama Y;Kato H .[J].Materials Transactions,2004,45(12):3247. |
[3] | Xiao R G;Yan K P;Yan J X et al.[J].Corrosion Science,2008,50(06):1576. |
[4] | Kajihara K;Tokuda K;Sugizaki Y et al.[J].Japanese Journal of Institute of Light Metals,2001,51(03):182. |
[5] | Engler O;Huh MY .Evolution of the cube texture in high purity aluminum capacitor foils by continuous recrystallization and subsequent grain growth[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,1999(1/2):371-381. |
[6] | Titorov D B;Volkov V A;Lebedev V P et al.[J].Physics of Metals and Metallography,2006,102(01):83. |
[7] | Murakami T .[J].Materials Science Forum,2003,426-432:3697. |
[8] | Song J B;Mao W M;Yang Hong et al.[J].Journal of Materials Science and Technology,2008,24(05):718. |
[9] | Kajihara K;Tokuda K;Sugizaki Y et al.[J].Materials Science Forum,2002,408-412:791. |
[10] | Zhang X M;Meng Y;Zhou Z P et al.[J].Transactions of Nonferrous Metals Society of China,1999,9(01):19. |
[11] | Liu C M;Zhang X M;Chen Z Y et al.[J].Transactions of Nonferrous Metals Society of China,2001,11(02):222. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%