合成了5-[N-(叔丁氧甲酰基)氨基]-1,3,3-三甲基-6'-硝基吲哚啉螺吡喃(BOCSPI)和5-[N-(叔丁氧甲酰基)氨基].1,3,3-三甲基-6'-硝基-8'-甲氧基吲哚啉螺吡喃(BOCSPII)两种光致变色化合物,采用紫外一可见光谱法研究了其在溶液和以不同质量比掺杂在聚甲基丙烯酸甲酯(PMMA)膜中的光致变色性能.研究表明螺吡喃的高掺杂量不利于其开环和闭环态的转化,BOCSPII分子中的甲氧基有利于有色开环体的部花菁的稳定.
参考文献
[1] | Vladimir I.Minkin .Photo-,Thermo-,Solvato-,and Electrochromic Spiroheterocyclic Compounds[J].Chemical Reviews,2004(5):2751-2776. |
[2] | Naoto Tamai;Hiroshi Miyasaka .Ultrafast Dynamics of Photochromic Systems[J].Chemical Reviews,2000(5):1875-1890. |
[3] | Gorner H. .Photochromism of nitrospiropyrans: effects of structure, solvent and temperature[J].Physical chemistry chemical physics: PCCP,2001(3):416-423. |
[4] | James T.C.Wojtyk;Adnaan Wasey;Peter M.Kazmaier;Shmaryahu Hoz;Erwin Buncel .Thermal Reversion Mechanism of N-Functionalized Merocyanines to Spiropyrans:A Solvatochromic,Solvatokinetic,and Semiempirical Study[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2000(39):9046-9055. |
[5] | Lin J S;Chiu H T .Photochromic behavior of spiropyran and fulgide in thin films of blends of PMMA and SBS[J].Journal of Polymer Research,2003,10:105-110. |
[6] | Levitus M;Talhavini M;Negri R M et al.Novel kinetic model in amorphous polymers.spiropyran-merocyanine system revisited[J].Journal of Physical Chemistry B,1997,101:7680-7686. |
[7] | Crano J C;Guglielmeni R.Organic Photochromic and Thermochrmnic Compounds[M].New York:Plenum Press,1999:9-16. |
[8] | Gale D J;Whilshire J F K .Fibre-reactive basic dyes I-polyrnethine dyes containing the N-chloroacetyl group[J].Journal of the Society of Dyers and Colourists,1974,90:97-100. |
[9] | Shvartsman F P;Krongauz V A .Quasi-liquid crystals of thermochromic spiropyran.A material intermediate between supercooled liquids and mesophases[J].Journal of Physical Chemistry,1984,88:6448-6453. |
[10] | Warshawsky A;Kahana N;Buchholtz F et al.Photochromic polysulfones.1 synthesis of polymeric polysulfone cartying pendant spiropyran and spirooxazine groups[J].Industrial and Engineering Chemistry Research,1995,34:2825-2832. |
[11] | Uznanski P. .UV-assisted formation of nanoaggregates from photochromic spiropyrans in nonpolar solvents[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(6):1919-1922. |
[12] | Zhang J Z;Schwartz B J;King J C;Harris C B .Ultrafast studies of photochromic spiropyrans in solution[J].Journal of the American Chemical Society,1992,114:10921-10927. |
[13] | Choi D H;Ban S Y;Kim J H .Stability of photochromism in new bifunctional copolymers containing spiropyran and chaleone moiety in the side chain[J].Bulletin of the Korean Chemical Society,2003,24:441-445. |
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