以高纯金为牺牲阳极,在三苯基磷与浓盐酸的乙腈溶液中,用电化学方法合成了三苯基磷氯金(Au(PPh3) Cl),并经适当的纯化处理获得了Au(PPh3) Cl白色针状晶体.元素分析、红外光谱和X射线衍射分析结果表明,所制备的产物为Au(PPh3) Cl纯相,同时还对Au(PPh3) Cl电化学合成机理及相关实验条件的影响进行了讨论.
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