{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以间苯二甲酰氯、4-哌嗪哌啶、<span style=\"color:red\">3</span>-[(2-氨基乙基)-二甲胺]丙烷-<span style=\"color:red\">1</span>-磺酸作为结构调节分子,分别考察了添加每种分子对<span style=\"color:red\">顺</span>-(<span style=\"color:red\">1,3,5</span>)-<span style=\"color:red\">胺基</span><span style=\"color:red\">环己烷</span>-均苯三甲酰氯纳滤膜的水通量和盐截留率的影响.当添加间苯二甲酰氯时,膜的水通量下降.考察了<span style=\"color:red\">顺</span>-(<span style=\"color:red\">1,3,5</span>)-<span style=\"color:red\">胺基</span><span style=\"color:red\">环己烷</span>-间苯二甲酰氯纳滤膜的性能,该膜水通量为2.7 L/(m2·h·MPa),对盐的截留顺序为Na2SO4 (92.3％)＞MgC12 (76.6％)＞NaCl(54.5％).当添加4-哌嗪哌啶时,膜的水通量增加.当添加<span style=\"color:red\">3</span>-[(2-氨基乙基)-二甲胺]丙烷-<span style=\"color:red\">1</span>-磺酸时,膜的水通量随其浓度增加呈先增大后减小的趋势.当添加少量结构调节分子时,各膜对Na2SO4的截留率都轻微下降;当添加量较多时,截留率下降幅度较大.","authors":[{"authorName":"刘中楠","id":"7b988c67-9a8c-4e98-ac81-f752d783833e","originalAuthorName":"刘中楠"},{"authorName":"刘丹丹","id":"ad0b5de7-91fc-4311-9ee9-4eef65c0be7c","originalAuthorName":"刘丹丹"},{"authorName":"康国栋","id":"c1810721-f267-4fe4-94d0-bde4533a68df","originalAuthorName":"康国栋"},{"authorName":"于海军","id":"bb15803b-9c87-4873-b93b-a1d93ad0d013","originalAuthorName":"于海军"},{"authorName":"金焱","id":"ef647a32-4f5e-4fac-bace-fc1207f41d54","originalAuthorName":"金焱"},{"authorName":"曹义鸣","id":"d9c8e8e5-621e-4d50-ada3-2346d31f463f","originalAuthorName":"曹义鸣"}],"doi":"10.16159/j.cnki.issn1007-8924.2017.01.003","fpage":"16","id":"f90a179d-a5b1-450d-9a9a-8b2f981078cc","issue":"1","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"f15ce368-7efd-4ac3-a96f-ff1b0ba7393e","keyword":"纳滤膜","originalKeyword":"纳滤膜"},{"id":"9e110580-3575-4418-ad5e-c560cc72b97b","keyword":"<span style=\"color:red\">顺</span>-(<span style=\"color:red\">1,3,5</span>)-<span style=\"color:red\">胺基</span><span style=\"color:red\">环己烷</span>","originalKeyword":"顺-(1,3,5)-胺基环己烷"},{"id":"4344aa9a-c0cb-46c5-8172-662c55def630","keyword":"结构调节分子","originalKeyword":"结构调节分子"}],"language":"zh","publisherId":"mkxyjs201701003","title":"结构调节分子对<span style=\"color:red\">顺</span>-(<span style=\"color:red\">1,3,5</span>)-<span style=\"color:red\">胺基</span><span style=\"color:red\">环己烷</span>-均苯三甲酰氯复合纳滤膜性能的影响","volume":"37","year":"2017"},{"abstractinfo":"以苯甲醛、异丁醛、三氯化磷为原料合成了新型的<span style=\"color:red\">1,3</span>,2-二氧磷杂环类化合物2-苯羟甲基-<span style=\"color:red\">5</span>,5-二甲基-4-苯基-2-氧代-<span style=\"color:red\">1,3</span>,2-二氧磷杂<span style=\"color:red\">环己烷</span>,总收率为40.8%,并对其进行了NMR研究和结构表征.","authors":[{"authorName":"张想竹","id":"f700c17e-0687-4c35-b0bc-91ae21e93941","originalAuthorName":"张想竹"},{"authorName":"吴明书","id":"d627abf9-3812-4ee1-aa78-a5f979f6402e","originalAuthorName":"吴明书"},{"authorName":"孙宝盛","id":"95ac3fbe-d42e-43fc-b0c5-1f2b4b37fc85","originalAuthorName":"孙宝盛"}],"doi":"10.3969/j.issn.1000-0518.2007.01.026","fpage":"114","id":"3bd2befa-14cf-4975-8eed-c0c710978743","issue":"1","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"e6ada888-07e6-4b3d-9cc3-111eb5af81b6","keyword":"二氧磷杂<span style=\"color:red\">环己烷</span>","originalKeyword":"二氧磷杂环己烷"},{"id":"0c8b809a-bfec-46bd-b3b7-7b1ea326dd7e","keyword":"合成","originalKeyword":"合成"},{"id":"06d5fe63-a486-48ec-9b6e-c4f4e741a6fc","keyword":"表征","originalKeyword":"表征"}],"language":"zh","publisherId":"yyhx200701026","title":"2-苯羟甲基-<span style=\"color:red\">5</span>,5-二甲基-4-苯基-2-氧代-<span style=\"color:red\">1,3</span>,2-二氧磷杂<span style=\"color:red\">环己烷</span>的合成及表征","volume":"24","year":"2007"},{"abstractinfo":"在TiFe合金中添加少量的IIA族轻金属元素Mg,并且使Ti侧过化学计量,组成Ti1.2+x%(质量分数,下同)Mg(x=<span style=\"color:red\">1,3,5</span>)试验合金,研究了该系列合金的储氢特性.结果表明,Ti1.2Fe+<span style=\"color:red\">3</span>%Mg和Ti1.2Fe+<span style=\"color:red\">5</span>%Mg合金在室温下,经2次吸放氢操作即能完全活化,前者的储氢量为213ml/g,且具有较小的压力滞后和平台斜率,适合作为氢燃料电池氢源储氢材料.X-射线分析发现,所有试验合金的主相均为TiFe相,而合金显微组织显示,Mg以弥散颗粒分布于合金基体.并讨论了Mg的添加和Ti过量对合金活化性能和储氢容量的影响机制.","authors":[{"authorName":"徐海鸥","id":"db59f821-3bfa-4a25-b530-d695dd2aae40","originalAuthorName":"徐海鸥"},{"authorName":"陈长聘","id":"a1858d2f-be03-487c-9193-a5acbee6f7ab","originalAuthorName":"陈长聘"},{"authorName":"王澂","id":"a9da03dc-122f-4c35-8711-eef963afcdb5","originalAuthorName":"王澂"},{"authorName":"蔡官明","id":"5a18eb3a-3bfc-4f0c-a7da-99afe278fdcd","originalAuthorName":"蔡官明"},{"authorName":"陈立新","id":"9672de73-ecf4-4bf7-b757-f383a760fab3","originalAuthorName":"陈立新"}],"doi":"","fpage":"220","id":"cd61ae4b-99a9-43a8-8e68-668b786fcce0","issue":"3","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"5f1aadbb-4c02-41f4-b567-9276a5d45af3","keyword":"钛铁合金","originalKeyword":"钛铁合金"},{"id":"2788df8b-593a-49c6-8969-da757905b1b1","keyword":"镁","originalKeyword":"镁"},{"id":"d66f9e75-fee2-4521-a24c-392ccb8b22d3","keyword":"储氢性能","originalKeyword":"储氢性能"}],"language":"zh","publisherId":"xyjsclygc200303017","title":"Ti1.2Fe+x%Mg(x=<span style=\"color:red\">1,3,5</span>)合金的贮氢特性","volume":"32","year":"2003"},{"abstractinfo":"考察了钛硅分子筛(TS-<span style=\"color:red\">1</span>)以及硅烷化钛硅分子筛(TS-<span style=\"color:red\">1</span>-S)上环烷酸钴(Co-nap)催化<span style=\"color:red\">环己烷</span>氧化反应性能.结果表明,TS-<span style=\"color:red\">1</span>和TS-<span style=\"color:red\">1</span>-S对该反应均具有显著的促进作用,<span style=\"color:red\">环己烷</span>转化率由无TS-<span style=\"color:red\">1</span>时的3.6%分别提高至6.4%和7.9%,产物选择性保持在80%左右,反应时间由300 min可缩短为130min.进一步的研究表明,随着TS-<span style=\"color:red\">1</span>的加入,Co-nap在其表面发生了吸附,使得均相反应变成了\"类多相催化反应\".这是反应性能显著提高的主要原因.","authors":[{"authorName":"王德强","id":"59239dbd-00dc-4831-831e-209fe223859b","originalAuthorName":"王德强"},{"authorName":"张一波","id":"2916653f-dff9-427f-941d-0e5d75fdb543","originalAuthorName":"张一波"},{"authorName":"肖德海","id":"3682062d-d154-4f06-9707-1cda4810f928","originalAuthorName":"肖德海"},{"authorName":"杨向光","id":"c3cb91d0-689b-403f-8f09-f803e024745f","originalAuthorName":"杨向光"}],"doi":"10.1016/S1872-2067(10)60193-3","fpage":"723","id":"3f995cf4-ba97-407e-bc01-e43db3656e20","issue":"5","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"2e640e2f-0576-4178-a46c-426373a02a5d","keyword":"钛硅分子筛","originalKeyword":"钛硅分子筛"},{"id":"9b4c1a83-11c6-4401-9901-88e5cbe65ca7","keyword":"<span style=\"color:red\">环己烷</span>","originalKeyword":"环己烷"},{"id":"b443b28b-cc98-40b1-b8ac-9c917815fa14","keyword":"均相氧化","originalKeyword":"均相氧化"},{"id":"c6fa7231-8e59-4bc5-a686-947c0e40550d","keyword":"吸附","originalKeyword":"吸附"},{"id":"bc4b0796-528c-4968-b229-d67bfd260de6","keyword":"硅烷化","originalKeyword":"硅烷化"}],"language":"zh","publisherId":"cuihuaxb201105004","title":"硅烷化TS-<span style=\"color:red\">1</span>对<span style=\"color:red\">环己烷</span>均相氧化反应的促进作用","volume":"32","year":"2011"},{"abstractinfo":"研究了反式-<span style=\"color:red\">1</span>,4-二芳基<span style=\"color:red\">环己烷</span>类、反式-环己基联苯类、反式,反式-双环己基苯类等三环骨架化合物中环己基排序对混合液晶配方阈值电压的影响,同时考察了阈值电压随温度的变化.实验结果表明,反式-<span style=\"color:red\">1</span>,4-二芳基<span style=\"color:red\">环己烷</span>类化合物与带有相同端基的反式-环己基联苯类和反式,反式-双环己基苯类化合物相比,能有效降低混合液晶配方的阈值电压;在-20～0℃的温度区间内,阈值电压随温度变化的幅度较小,能起到改善混合液晶配方低温性能的作用.","authors":[{"authorName":"杜渭松","id":"f433b54b-ce7f-4c16-b075-4e63e3cc9cb0","originalAuthorName":"杜渭松"},{"authorName":"安忠维","id":"cc4daaec-09b5-4da4-8649-4b2790b5958b","originalAuthorName":"安忠维"},{"authorName":"冯凯","id":"3017f1fd-0964-4fb1-a48d-fc4505ca846a","originalAuthorName":"冯凯"}],"doi":"10.3969/j.issn.1007-2780.2003.02.003","fpage":"89","id":"bfef0c25-a632-4320-81ed-8eb5b19e662f","issue":"2","journal":{"abbrevTitle":"YJYXS","coverImgSrc":"journal/img/cover/YJYXS.jpg","id":"72","issnPpub":"1007-2780","publisherId":"YJYXS","title":"液晶与显示   "},"keywords":[{"id":"bb536487-1084-46b7-a067-01600a1aa272","keyword":"液晶","originalKeyword":"液晶"},{"id":"6890dd41-0c56-42dc-92c1-9dc216f9d524","keyword":"阈值电压","originalKeyword":"阈值电压"},{"id":"aaf40228-1f7d-480e-8871-e1afab0b0296","keyword":"<span style=\"color:red\">环己烷</span>","originalKeyword":"环己烷"},{"id":"1c9603b3-bc03-4ea3-8377-db8caf2ed8fa","keyword":"配方","originalKeyword":"配方"},{"id":"21fee2a6-254d-4108-a8f8-54712ff73fc2","keyword":"温度","originalKeyword":"温度"}],"language":"zh","publisherId":"yjyxs200302003","title":"反式-<span style=\"color:red\">1</span>,4-二芳基<span style=\"color:red\">环己烷</span>类液晶的性能研究","volume":"18","year":"2003"},{"abstractinfo":"研究了时效处理对热挤压Mg-xZn(x =<span style=\"color:red\">1,3,5</span>)-Y合金显微组织和力学性能的影响.实验结果表明:挤压态Mg-xZn(x=<span style=\"color:red\">1,3,5</span>)-Y合金显微组织由α-Mg,Mg<span style=\"color:red\">3</span>Zn6Y和Mg<span style=\"color:red\">3Zn3</span>Y2相组成.挤压后合金发生了动态再结晶,随着Zn含量的增加,合金中的Mg<span style=\"color:red\">3</span>Zn6Y相依次增加.经时效处理后,颗粒状的Mg<span style=\"color:red\">3</span>Zn6Y相沉淀析出,Mg<span style=\"color:red\">3Zn3</span>Y2相也逐渐弥散析出.其中Mg-<span style=\"color:red\">5</span>Zn-Y合金经过温度为200℃,18h的时效处理后,具有良好的综合力学性能,其抗拉强度,屈服强度和伸长率分别为375 MPa,258MPa,23.5％.该合金拥有良好的力学性能主要是由于晶粒细化和Mg<span style=\"color:red\">3</span> Zn6Y相的沉淀强化.","authors":[{"authorName":"邝亚飞","id":"88dab359-c52c-4391-8f33-75b0f6dd2b00","originalAuthorName":"邝亚飞"},{"authorName":"王泽辉","id":"56badcac-833e-4478-a54e-a45a55d7800d","originalAuthorName":"王泽辉"},{"authorName":"房大庆","id":"716da18c-927a-499e-9de1-2c3cb04d6570","originalAuthorName":"房大庆"},{"authorName":"柴跃生","id":"4cb8c3e6-08e9-4f95-a298-9fdc776cb136","originalAuthorName":"柴跃生"},{"authorName":"武华杰","id":"fdbbe48f-7bb9-4f58-b6a6-bacaca8f35e0","originalAuthorName":"武华杰"}],"doi":"10.11785/S1000-4343.20160513","fpage":"600","id":"8317c70f-010f-4db1-948c-29b24328d33a","issue":"5","journal":{"abbrevTitle":"ZGXTXB","coverImgSrc":"journal/img/cover/ZGXTXB.jpg","id":"86","issnPpub":"1000-4343","publisherId":"ZGXTXB","title":"中国稀土学报"},"keywords":[{"id":"bb8a7963-bb37-43ec-bffc-a37591728e51","keyword":"热挤压Mg-xZn-Y合金","originalKeyword":"热挤压Mg-xZn-Y合金"},{"id":"3412c2b1-789c-4fe3-b4a9-720766db6b27","keyword":"显微组织","originalKeyword":"显微组织"},{"id":"ea1325f8-4fc1-4866-b036-f64f2b95b356","keyword":"时效处理","originalKeyword":"时效处理"},{"id":"2961534d-b373-4df8-99cb-350cedbac1aa","keyword":"力学性能","originalKeyword":"力学性能"}],"language":"zh","publisherId":"zgxtxb201605013","title":"时效处理对热挤压Mg-xZn(x=<span style=\"color:red\">1,3,5</span>)-Y合金组织与力学性能的影响","volume":"34","year":"2016"},{"abstractinfo":"的稳定性.本文以传统均相Co盐催化剂的多相化为出发点，制备了Co掺杂SAPO-<span style=\"color:red\">5</span>与分子筛催化剂(Co-SAPO-<span style=\"color:red\">5</span>)，考察了Co掺杂量对催化剂结构、表面性质以及氧气选择性氧化<span style=\"color:red\">环己烷</span>反应性能的影响.结果表明，一部分Co进入分子筛骨架，同时有少量Co以氧化钴形式高度分散在SAPO-<span style=\"color:red\">5</span>表面. Co掺杂对SAOP-<span style=\"color:red\">5</span>催化剂比表面积没有显著影响，但可使其孔体积减小.相反， Co掺杂可以提高SAOP-<span style=\"color:red\">5</span>分子筛表面B酸性位数量和总酸量.活性测试结果表明，<span style=\"color:red\">环己烷</span>转化率随着Co-SAPO-<span style=\"color:red\">5</span>催化剂中Co含量的增加而增加，但KA油选择性在转化率高于6.3%时急剧下降.还考察了反应温度、反应时间、初始氧气压力和催化剂用量对Co-SAPO-<span style=\"color:red\">5</span>分子筛催化剂性能的影响，得到了最优反应条件.以Co-SAPO-<span style=\"color:red\">5</span>-0.2(Co/Si摩尔比为0.2)分子筛为催化剂时， KA油总收率最高可达7.8%.另外， Co-SAPO-<span style=\"color:red\">5</span>催化剂在<span style=\"color:red\">环己烷</span>氧化反应中显示出很好的稳定性， Co-SAPO-<span style=\"color:red\">5</span>-0.2催化剂套用6次后活性几乎没有变化.","authors":[{"authorName":"校准","id":"f6d51189-01d4-4454-8f68-f348eeada205","originalAuthorName":"校准"},{"authorName":"詹望成","id":"dd1b19a9-b3f5-4b61-9b19-103e569c344b","originalAuthorName":"詹望成"},{"authorName":"郭耘","id":"3e5c021a-df7d-4812-89e1-bc0f4753ba8a","originalAuthorName":"郭耘"},{"authorName":"郭杨龙","id":"e117ec7b-da6b-4bc7-b1ba-3e383519ec63","originalAuthorName":"郭杨龙"},{"authorName":"龚学庆","id":"6945a3ba-dd98-419c-bcd9-e9f8f33edbec","originalAuthorName":"龚学庆"},{"authorName":"卢冠忠","id":"a2f74b1f-746b-4dc4-8061-4078874f504b","originalAuthorName":"卢冠忠"}],"doi":"10.1016/S1872-2067(15)61014-2","fpage":"273","id":"525840a1-fa76-4ddc-b53f-925351c16bf8","issue":"2","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"0bcc9d79-e49c-4899-9e3a-f7bd71944df6","keyword":"SAPO-<span style=\"color:red\">5</span>分子筛","originalKeyword":"SAPO-5分子筛"},{"id":"4d8551ec-2586-42f6-a0ef-78092cc90349","keyword":"钴","originalKeyword":"钴"},{"id":"7feecd3b-9b2a-4b05-af7b-af3e2b54b1ef","keyword":"<span style=\"color:red\">环己烷</span>","originalKeyword":"环己烷"},{"id":"4a8b5622-0a6d-43ff-b94c-26bdd17bb9ca","keyword":"选择氧化","originalKeyword":"选择氧化"},{"id":"2e18442d-4e31-4464-82e7-0dcdf420a820","keyword":"氧气","originalKeyword":"氧气"}],"language":"zh","publisherId":"cuihuaxb201602009","title":"Co掺杂SAPO-<span style=\"color:red\">5</span>分子筛制备及其催化氧气氧化<span style=\"color:red\">环己烷</span>反应性能","volume":"37","year":"2016"},{"abstractinfo":"由于水蒸气处理HZSM-<span style=\"color:red\">5</span>生成的骨架外铝在分子筛中体现Lewis酸性,分子筛中骨架外铝物种的可移动性导致Lewis酸与分子筛本身的Br(o)nsted酸在空间上具有临近性.当甲基<span style=\"color:red\">环己烷</span>分子在HZSM-<span style=\"color:red\">5</span>的笼中转化时,Lewis酸与Br(o)nsted酸的协同作用加快了甲基<span style=\"color:red\">环己烷</span>分子的转化速率,且骨架外铝物种浓度越高,这种协同效应越明显.而产物的选择性只与催化剂的孔道结构有关,与水蒸气处理所导致的酸性质的变化无关.","authors":[{"authorName":"宋晨海","id":"fe6812b3-63ea-422c-8ba2-504459a6c079","originalAuthorName":"宋晨海"},{"authorName":"王蒙","id":"251dad08-1ceb-4ec2-96d4-4cbbf0d409df","originalAuthorName":"王蒙"},{"authorName":"赵理","id":"56f26527-3291-4843-8a80-0f35a1edb0af","originalAuthorName":"赵理"},{"authorName":"薛念华","id":"643465c0-f7ce-4f28-92a4-0fddc948b377","originalAuthorName":"薛念华"},{"authorName":"彭路明","id":"6b41991f-2903-4cda-91ef-1fb322c87770","originalAuthorName":"彭路明"},{"authorName":"郭学锋","id":"8f29d5c4-7ba9-4342-ae18-819e47501320","originalAuthorName":"郭学锋"},{"authorName":"丁维平","id":"8b12ffbe-2d50-4bce-9e20-ac2712601e5f","originalAuthorName":"丁维平"},{"authorName":"杨为民","id":"75db53ca-ca31-48e7-a5cf-91e09473beb5","originalAuthorName":"杨为民"},{"authorName":"谢在库","id":"c0c4015a-ee79-44a9-a44b-359a3509b926","originalAuthorName":"谢在库"}],"doi":"10.1016/S1872-2067(12)60721-9","fpage":"2153","id":"b23f54ad-f018-43c8-80d5-5fb119290a3c","issue":"11","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"1979f4c1-b4bb-4113-9268-ed40314fb2f7","keyword":"甲基<span style=\"color:red\">环己烷</span>","originalKeyword":"甲基环己烷"},{"id":"f550c379-4d96-48d7-b021-c84593b34473","keyword":"HZSM-<span style=\"color:red\">5</span>","originalKeyword":"HZSM-5"},{"id":"c39e28c4-d23c-48aa-85bb-24e9988b6526","keyword":"水蒸气处理","originalKeyword":"水蒸气处理"},{"id":"5f5a8a5f-1afd-4dac-b27e-489f1987261e","keyword":"协同效应","originalKeyword":"协同效应"},{"id":"bd6d21b2-730b-4b80-9cc8-c5a71c03ffa6","keyword":"Lewis酸","originalKeyword":"Lewis酸"},{"id":"ec235a21-b0a0-4797-8344-c41190e89810","keyword":"Br(o)nsted酸","originalKeyword":"Br(o)nsted酸"}],"language":"zh","publisherId":"cuihuaxb201311026","title":"HZSM-<span style=\"color:red\">5</span>沸石中Lewis酸与Br(o)nsted酸协同作用下的甲基<span style=\"color:red\">环己烷</span>开环反应","volume":"34","year":"2013"},{"abstractinfo":"采用正交设计试验法对乙酸锰催化<span style=\"color:red\">环己烷</span>液相亚硝化一步合成己内酰胺的新反应进行了研究.考察了反应温度、反应时间、催化剂用量和反应物配比等因素对<span style=\"color:red\">环己烷</span>转化率和己内酰胺选择性的影响.结果表明,最佳的合成条件为:在81℃反应36 h,催化剂乙酸锰用量为<span style=\"color:red\">环己烷</span>质量的2.5%,亚硝基硫酸与发烟硫酸的质量比为<span style=\"color:red\">1</span>:<span style=\"color:red\">3</span>.在此优化的条件下,<span style=\"color:red\">环己烷</span>液相亚硝化反应的转化率为8.12%,目标产物己内酰胺的选择性达10.54%.","authors":[{"authorName":"吴伯华","id":"711f5542-ca05-49d0-84eb-75a7101fecdb","originalAuthorName":"吴伯华"},{"authorName":"毛丽秋","id":"5fc1cc69-ec5b-46aa-bf68-4f0ac20abbc1","originalAuthorName":"毛丽秋"},{"authorName":"尹笃林","id":"5b8c3391-313e-4a2c-bf46-c7a308c5db82","originalAuthorName":"尹笃林"},{"authorName":"游奎一","id":"970fbc8b-8916-43f7-9d4e-ed6be4ce1a4a","originalAuthorName":"游奎一"},{"authorName":"刘平乐","id":"9e3b5293-f594-4f19-9af1-9d34f35a9990","originalAuthorName":"刘平乐"},{"authorName":"罗和安","id":"9688e2f3-7df9-4119-8042-d38147fd279c","originalAuthorName":"罗和安"}],"doi":"10.3969/j.issn.1000-0518.2008.04.028","fpage":"502","id":"2d26b758-affb-408d-85ee-fcdf5ddd93e7","issue":"4","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"7a44307b-ba0d-4b67-b28b-1cb5663b72d7","keyword":"正交设计","originalKeyword":"正交设计"},{"id":"96b6de5d-48f6-49f1-b26c-06af790c5833","keyword":"<span style=\"color:red\">环己烷</span>","originalKeyword":"环己烷"},{"id":"d4f4eeac-9fd0-4b80-91cf-40f7e392d1b3","keyword":"亚硝化反应","originalKeyword":"亚硝化反应"},{"id":"b8f7f2d4-b2eb-4b72-b099-fcf46bfd1c53","keyword":"己内酰胺","originalKeyword":"己内酰胺"}],"language":"zh","publisherId":"yyhx200804028","title":"<span style=\"color:red\">环己烷</span>液相亚硝化一步合成己内酰胺","volume":"25","year":"2008"},{"abstractinfo":"合成了<span style=\"color:red\">1</span>,4-<span style=\"color:red\">环己烷</span>二甲醇(CHDM)共聚改性的聚对苯二甲酸乙二酯(PET),用示差扫描量热(DSC)和傅立叶变换红外(FT-IR)方法研究了该体系的等温结晶动力学和结晶度,结果表明,共聚物组成和结晶温度均会影响材料的结晶行为,这将有利于控制和改善PET的加工性.","authors":[{"authorName":"应燕","id":"bb1555e2-9da6-4ffc-8d26-1ed8684b3cfb","originalAuthorName":"应燕"},{"authorName":"王铁军","id":"72331c6c-4b60-4139-8b07-1c4c5a127f0e","originalAuthorName":"王铁军"},{"authorName":"杨昌正","id":"aacaa8a1-3f4b-4a64-883f-e130f6a78242","originalAuthorName":"杨昌正"}],"doi":"","fpage":"120","id":"6c158ee3-74b6-4cfe-8350-cedeb821c958","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"7d7c6665-63f7-4fe9-80e5-0b255c92fadb","keyword":"共聚改性","originalKeyword":"共聚改性"},{"id":"e6ece24b-d646-4c7b-a4be-566bfec0fc2e","keyword":"等温结晶动力学","originalKeyword":"等温结晶动力学"},{"id":"cb24fc22-cfc5-4246-b4df-856fe0326e37","keyword":"结晶度","originalKeyword":"结晶度"}],"language":"zh","publisherId":"gfzclkxygc200001036","title":"<span style=\"color:red\">1</span>,4-<span style=\"color:red\">环己烷</span>二甲醇改性聚对苯二甲酸乙二酯结晶行为的研究","volume":"16","year":"2000"}],"totalpage":9504,"totalrecord":95037}