为改善亚乙基降冰片烯(ENB)自修复微胶囊在环氧树脂(Epoxy)中的分散性,采用KH560偶联剂对ENB微胶囊表面进行处理,探讨KH560改性ENB微胶囊(KH560-ENB)在Epoxy材料中的分散性及KH560-ENB环氧树脂材料(KH560-ENB/Epoxy)的拉伸性能。结果表明:对未改性的ENB微胶囊树脂复合材料(ENB/Epoxy),当ENB微胶囊与Epoxy质量比小于或等于5%时,ENB/Epoxy的拉伸断裂强度、拉伸模量以及断裂伸长率均随ENB微胶囊与Epoxy质量比的增加而降低,但经不同温度预固化后,ENB/Epoxy复合材料拉伸指标初始下降速率均不同;KH560-ENB微胶囊在Epoxy中累积分布线性拟合相关系数为0.9945,接近于1,说明KH560-ENB微胶囊在Epoxy中分散性好,且KH560-ENB/Epoxy复合材料的拉伸断裂强度提高19.1%,拉伸模量提高6.6%;对KH560-ENB/Epoxy复合材料的SEM断面观察结果表明,KH560-ENB微胶囊与Epoxy界面粘接良好。
In order to improve the dispersion of ethylidene - 2 - norbornene (ENB) based self - healing microcapsules in the epoxy, KH560 coupling agent was chosen to modify the surface of ENB microeapsules. The dispersion of KH560 - ENB microcapsules and their influence on tensile property of KH560 - ENB/Epoxy composites were studied. The results show that, the tensile fracture strength, tensile modulus and elongation at break of ENB/Epoxy composites, decrease when the mass ratio of ENB microcapsules to epoxy increases to no more than 5~. The falling slopes of those three tensile properties vary with pre-curing temperature for ENB/Epoxy composites. The linear coefficient of cumulative distribution of KH560 - ENB microcapsule in epoxy is 0. 9945, nearly to 1, showing better dispersion. Furthermore, tensile fracture strength and tensile modulus of KH560 - ENB/Epoxy composites increase by 19.1% and 6.6%, respectively. According to SEM observations of KH560 - ENB/Epoxy cross section, the interface between KH560 - ENB microcapsules and epoxy is well bonded.
参考文献
[1] | White S R, Sottos N R, Geubelle P H, et al. Autonomic healing of polymer composites [J]. Nature, 2001, 409: 794-797. |
[2] | Brown E N, White S R, Sottos N R. Microcapsule induced toughening in a self healing polymer composite [J]. Materials Science, 2004, 39: 1703-1710. |
[3] | Yin T, Zhou L, Rong M Z, et al. Self- healing woven glass fabric/epoxy composites with the healant consisting of micro- encapsulated epoxy and latent curing agent [J]. Smart Mater Struct, 2008, 17:1-8. |
[4] | Yuan I., Liang G Z, Xie J Q, et al. Synthesis and characterization of microencapsulated dicy- clopentadiene with melamine-formaldehyde resins [J]. Colloid Polym Sci, 2007, 285: 781-791. |
[5] | Liu X, Sheng X, Lee J K, et al. Synthesis and characterization of melamine formaldehyde microeapsules containing ENB-hased self-healing agents [J]. Macromol Mater Eng, 2009, 294: 389-395. |
[6] | Blaiszik B J, Scottos N R, White S R. Nanocapsules for self- healing materials [J].Composites Science and Technology, 2008, 68: 978-986. |
[7] | 季小勇,李惠,欧进萍.炭黑分散状态对炭黑/环氧树脂导电复合材料电阻率和力电性能的影响[J].复合材料学报,2009,26(5):39-46. |
[8] | Li H Y, Wang R G, Hu H L, et al. Surface modification of self healing poly (urea - formaldehyde) microcapsules using silane-coupling agent [J].Applied Surface Science, 2008, 225: 1894-1900. |
[9] | Suetsugu Y. State of dispersion mechanical properties correlation in small particle filled polymer composites [J]. Intern Polymer Processing, 1990, 5(3) : 184-190. |
[10] | Morishita M. Measuring of the dispersion and analysis of distribution patterns [J]. Memoirs of the Faculty of Science Kyushu University: Series E--Biology, 1959, 2: 215-235. |
[11] | 陈芳,赵学增,聂鹏,等.基于分形的纳米复合材料分散相分散均匀性描述[J].塑料工业,2004,32(1):50-53. |
[12] | 聂鹏,王新鑫,高霁,等.纳米复合材料分散相分散均匀性的分形表征[J].北京航空航天大学学报,2009,33(7):852-855. |
[13] | Li T T, Wang R, Liu X. Synthesis of self - healing microcapsules via different heating profiles [J]. Advanced Materials Research, 2011, 148/149: 1486-1490. |
[14] | Liu X. Self-healing for polymer matrix composites: Healing agents and micro encapsulation [D]. Korea: Graduate School of Kumoh National Institute of Technology, 2008. |
[15] | 上海化工学院玻璃教研室.合成树脂[M].北京:中国建筑工业出版社,1979. |
[16] | 沈玺,高雅男,徐政.硅烷偶联剂的研究与应用[J].上海生物医学杂志,2006,26(1):14-17. |
[17] | Wu S H. Phase structure and adhesion in polymer blends: A criterion for rubber toughening [J]. Polymer, 1985, 26(12) : 1855-1863. |
[18] | Sudduth R D. Analysis of the maximum tensile strength of a composite with spherical particulates [J]. Compos Mater, 2006, 40(4): 301-331. |
[19] | Agarwal B D, Broutman L J, Analysis and performance of fvber composite [M]. New York: John Wiley and Sons, 1990: 59-65 |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%