STRUCTURAL DETERMINATION OF TITANIUM-OXIDE NANOPARTICLES BY X-RAY ABSORPTION SPECTROSCOPY

金属学报(英文版), 2002, 15(1): 53-57.

^1, , ^2, , ^3, , ^4, , ^5, , ^6, , ^7, , ^8, , ^9, , ^10, , ^11, , ^12, , ^13,

1.Beijing Synchrotron Radiation Facility,Institute of High Energy Physics,The Chinese Academy of Sciences,Beijing 100039,China;Laboratori Nazionali di Frascati, Istituto Nazionali di Fisica Nucleare, Via Enrico Fermi 40,P.O. Box 13,I-00044 Frascati,Italy

2.Beijing Synchrotron Radiation Facility, Institute of High Energy Physics,The Chinese Academy of Sciences, Beijing 100039,China

3.Beijing Synchrotron Radiation Facility, Institute of High Energy Physics,The Chinese Academy of Sciences, Beijing 100039,China

4.Beijing Synchrotron Radiation Facility, Institute of High Energy Physics,The Chinese Academy of Sciences, Beijing 100039,China

5.Beijing Synchrotron Radiation Facility, Institute of High Energy Physics,The Chinese Academy of Sciences, Beijing 100039,China

6.Beijing Synchrotron Radiation Facility, Institute of High Energy Physics,The Chinese Academy of Sciences, Beijing 100039,China

7.Beijing Synchrotron Radiation Facility, Institute of High Energy Physics,The Chinese Academy of Sciences, Beijing 100039,China

8.Beijing Synchrotron Radiation Facility, Institute of High Energy Physics,The Chinese Academy of Sciences, Beijing 100039,China

9.Beijing Synchrotron Radiation Facility, Institute of High Energy Physics,The Chinese Academy of Sciences, Beijing 100039,China

10.Beijing Synchrotron Radiation Facility, Institute of High Energy Physics,The Chinese Academy of Sciences, Beijing 100039,China

11.Shanghai Institute of Ceramics,The Chinese Academy of Sciences,Shanghai,200050,China

12.Shanghai Institute of Ceramics,The Chinese Academy of Sciences,Shanghai,200050,China

13.Shanghai Institute of Ceramics,The Chinese Academy of Sciences,Shanghai,200050,China

基金项目: 国家自然科学基金(10074063) 中国科学院资助项目(KJ952-S1-418)

STRUCTURAL DETERMINATION OF TITANIUM-OXIDE NANOPARTICLES BY X-RAY ABSORPTION SPECTROSCOPY

Keywords： X-ray absorption

As a potential application of titanium-oxide nanoparticles, it is extremely importantto investigate a detailed picture of the surface and interior structural properties ofnanocrystalline materials, such as rutile and anatase with diameters 7.0 and 4.5nm,respectively. X-ray absorption spectroscopy has been used to identify the local Ti envi-ronment and related electronic structure. We combine the experimental results at theTi edge in both bulk and nano-crystals to determine the lattice distortion in terms ofdifferently characteristic preedge features and the variation in the multiple-scatteringregion of X-ray absorption near-edge structure (XANES) spectra. The relationshipbetween the transition peaks and the surface-to volume ratio is also discussed.

参考文献

[1]	X Peng;J Wickham;A P Alivisatos .[J].Journal of the American Chemical Society,1998(120):5343.
[2]	J M Mchale;A Auroux;A J Perrotta;A Narrotsky .[J].Science,1997,277:788.
[3]	N A Hill;K B Whaley .[J].Journal of Chemical Physics,1994(100):2831.
[4]	M R Hoffmann;S T Martin;W Y Choi;D W Bahnemann .[J].Chemical Reviews,1995(95):69.
[5]	A L Linsebigler;G Q Lu;J T Yates .[J].Chemical Reviews,1995(95):735.
[6]	L X Chen;T Rajh;Z Y Wang;M Thurnauer .[J].Journal of Physical Chemistry,1997,B101:10688.
[7]	K J Klabunde .[J].Journal of Physical Chemistry,1996(100):12142.
[8]	C B Murray;D J Norris;M G Bawendi .[J].Journal of the American Chemical Society,1993(115):8706.
[9]	N Herron;J C Calabresse;W E Farneth .[J].科学(上海),1993,259:1426.
[10]	A Bianconi.[A].Prins and D Koningsberger Wiley,New York,1988
[11]	V Luca;S Djajanti;R F Howe .[J].Journal of Physical Chemistry B,1998(102):10650.
[12]	M F Ruiz Lopez;Munoz Paez .[J].Journal of Physics:Condensed Matter,1991,3(03):8981.
[13]	B Poumellec;P J Durham;G Y Guo .[J].Journal of Physics:Condensed Matter,1991,3(03):8195.
[14]	R Brydson;H Sauer;W Engel J;M Thomas E Zeitler N Kosugi H Kuroda .[J].Journal of Physics:Condensed Matter,1989,1(01):797.
[15]	Z Y Wu;G Ouvrard;P Gressier;C R Natoli .[J].Physical Review B,1997,55:10382.
[16]	Y Joly;D Cabaret;H Renevier;C R Natoli .[J].Physical Review Letters,1999,82:2398.
[17]	J M Mchale;A Auroux A .[J].Journal of Perrotta and A Narrotsky,Science,1995,277(102):4642.
[18]	S H Tolbert;A P Alivisatos .[J].Journal of Chemical Physics,1995,102:4642.

上一张下一张

计量

下载量()
访问量()

作者相关

在本站搜索
在百度学术搜索
在万方数据库搜索
在CNKI搜索

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

STRUCTURAL DETERMINATION OF TITANIUM-OXIDE NANOPARTICLES BY X-RAY ABSORPTION SPECTROSCOPY

参考文献