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本工作采用超高真空气相渗透技术,在300-420℃温度范围内,测定了氢在DD8,Rene'N4两种单晶高温合金中的扩散系数、渗透率和溶解度常数,分析了缺陷对扩散系数的影响及氢溶解放热的原因.结果表明,在实验温度范围内,氢在两种单晶高温合金中的扩散系数,渗透率和溶解度常数均遵循Arrhenius关系,空洞不是造成氢溶解放热的原因.

The diffusivity, permeability and solubility of hydrogen in DD8 and Rene'N4 superalloys were measured in the temperature range of 30t-420℃ by using ultrahigh vacuum gas permeation technique. The effect of defects on diffusivity and the reason of exothermic reaction of H-solubilization were analyzed. The results show that, in the testing temperature range, the diffusivity, permeability and solubility of hydrogen in DD8 and Rene'N4 superalloys are all in agreement with Arrhenius relationship, and the presence of voids is not the reason of exothermic reaction of H-solubilization.

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[12] WalstonWS,BernsteinIM,ThompsonAW.MetallTrans,1992
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