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采用氧化物法陶瓷工艺,在缺铁配方的基础上,制备不同Bi2O3掺量的Li0.45Ni0.2Ti0.1Fe2.25O4(δ=0.06)铁氧体样品。结果表明,添加Bi2O3没有在锂铁氧体中形成杂相,烧结后陶瓷样品物相组成单一,结晶状况良好;适量的Bi2O3能有效改善材料微观形貌,促进锂铁氧体的烧结致密化,有助于提高材料的饱和磁化强度47cM。和剩磁比R,降低矫顽力Hc。Bi2O3掺量为1.5%(质量分数)的样品具有较好的综合性能,表观密度d为4.72g/cm^3,饱和磁化强度4πM。为2.3T,剩磁比R为0.853,矫顽力Hc为2.3×10^2A/m。

Ferrites of Li0.45 Ni0.2 Ti0.1 Fe2.25-δO4, doped with different Bi2O3 contents on the basis of iron deficiency content 8 at 0.06, were fabricated by oxide ceramic processing. Result shows that Li-ferrite doped with Bi2O3 exhibits a single phase with pure spinal structure and are crystallized well. Appropriate content of Bi2 Oa helped to improve mierostructure which contributed to increasing saturation magnetizations and remanenee ratios and decreasing coercivety. Ferrite with the doping content at 1.5wt% shows well combination property with apparent densities d at 4.72g/ema , saturation magnetizations 4πMs at 0. 23T, remanence ratios R at 0. 853 and coercivety Hc at 2.3× 10^2A/m.

参考文献

[1] Zhou Zhigang.Ferrite magnetic material[M].北京:科学出版社,1991:194.
[2] Gupta N;Kashyap SC;Dube DC .Microwave behavior of substituted lithium ferrite composites in X-band[J].Journal of Magnetism and Magnetic Materials,2005(0):307-314.
[3] Ridgley D H;Lelloff H;Childress J D .Effects of lithium and oxygen losses on magnetic and crystalographid prop- erties of spinel lithium ferrite[J].Journal of the Ameri- can Ceramic Society,1970,53:304-311.
[4] 余忠,陈代中,兰中文,蒋晓娜,刘保元.Bi2O3对烧结LiZn铁氧体性能的影响[J].无机材料学报,2007(06):1173-1177.
[5] Qiao Liang;Xu Bin;Xi Qiaoqin et al.Effects of trace of BizO3 addition on the morphology of strontium ferrite particles[J].Ceramics International,2010,36:1423-1427.
[6] Su Hua;Tang Xiaoli;Zhang Huaiwu et al.Influences of Bi2Oa additive on the mierostructure,permeability and power loss characteristics of Ni-Zn ferrites[J].Journal of Magnetism and Magnetic Materials,2009,321:3183-3186.
[7] 荆玉兰,贾利军,张怀武,黄卫.复合添加对锂铁氧体烧结特性和电磁性能的影响[J].磁性材料及器件,2005(05):44-46.
[8] 曹晓非,孙康宁,冷亮.Bi2O3和Bi(NO3)3掺杂对锂锌铁氧体微观结构和微波吸收性能的影响[J].功能材料,2009(03):384-386.
[9] 杨洪杰,唐可,徐光亮,余洪滔,刘桂香.Ni-Ti复合取代锂铁氧体的显微结构及磁性能[J].硅酸盐学报,2011(12):1963-1967.
[10] Verma, V;Pandey, V;Shukla, VN;Annapoorni, S;Kotnala, RK .Remarkable influence on the dielectric and magnetic properties of lithium ferrite by Ti and Zn substitution[J].Solid State Communications,2009(39/40):1726-1730.
[11] Verma, V;Gairola, SP;Pandey, V;Tawale, JS;Su, H;Kotanala, RK .High permeability and low power loss of Ti and Zn substitution lithium ferrite in high frequency range[J].Journal of Magnetism and Magnetic Materials,2009(22):3808-3812.
[12] A. Kianvash;R. Arghavanian;S. Zakerifar .The effect of TiO_2 addition on the microstructure and magnetic properties of Bi-CVG material[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2008(1/2):432-435.
[13] Arjihunwadkar P R;Patil R R;Kulkarni D K .Effect of sintering temperature on the structural,electrical and magnetic properties of Li0.5 All.0 Fel.5 04 ferrite prepared by combustion method[J].Journal of Alloys and Com- pounds,2008,463:403-407.
[14] Li Biaorong.Principle of electronic ceramics Technology[M].Wuhan:Huazhong Institute of Technology Press,1986:110-123.
[15] Liu Peiyuan .Study on electromagnetic properties of LiZn ferrite[D].Chengdu:University of Electronic Sci- ence and Technology of China,2009.
[16] Pointon A J;Saull R C .Solid state reactions in lithium ferrite[J].Journal of the American Ceramic Society,1969,52:157-160.
[17] Li Shipu.Special ceramic technology[M].Wuhan:Wu- han University of Technology Press,1990:300-308.
[18] Wan Defu;Ma Xinglong.Magnetic physics[M].Bei- jing:Electronic Industry Press,1998:372-378.
[19] Slama, J.;Gruskova, A.;Soka, M.;Usakova, M.;Jancarik, V. .Analysis of Magnetic Properties of Substituted Li Ferrites[J].IEEE Transactions on Magnetics,2010(2):455-458.
[20] Saafan, SA;Assar, ST;Moharram, BM;El Nimr, MK .Comparison study of some structural and magnetic properties of nano-structured and bulk Li-Ni-Zn ferrite samples[J].Journal of Magnetism and Magnetic Materials,2010(6):628-632.
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