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The orientation relationships among TiB (B27), B2, and Ti(3)Al phases have been investigated by transmission electron microscopy. By using the composite selected-area electron diffraction technique, the orientation relationship between TiB (B27) and B2 was determined to be [100](TiB)parallel to[00](B2), (001)(TiB)parallel to(010)(B2); and that between TiB (B27) and Ti(3)Al was [010](TiB)parallel to[1120](Ti3Al), (001)(TiB)parallel to(0001)(Ti3Al). These orientation relationships have been predicted precisely by the method of coincidence of reciprocal lattice points.

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