对比分析了目前国内外关于高岭石插层复合物的热行为,发现高岭石复三方孔对其插层复合物层间距具有重要影响.与纯高岭石相比,插层复合物脱羟基温度降低,可能与插层作用降低了晶层之间连结力有关,这对于高岭石的剥片具有重要意义.有关高岭石插层复合物热分解机制的理论知识仍然有待进一步挖掘.
参考文献
[1] | 吴小缓,王文利.我国高岭土市场现状及发展趋势[J].非金属矿,2005(04):1-3,11. |
[2] | 刘钦甫;张鹏飞.华北晚古生代煤系高岭岩物质组成和成矿机理研究[M].北京:海洋出版社,1996 |
[3] | Wada K .Lattice expansion of kaolin minerals by treatment with potassium acetate[J].American Mineralogist,1961,46:78. |
[4] | Wada K .Intercalation of water in kaolin minerals[J].American Mineralogist,1965,50:924. |
[5] | Wada K .Oriented penetration of ionic compounds between the silicate layers of halloysite[J].American Mineralogist,1959,44:153. |
[6] | Ledoux R L;White J L .Infrared studies of hydrogen bonding interaction between kaolinite surface and intercalated potassium acetate,formamide and urea[J].Journal of Colloid and Interface Science,1966,21:127. |
[7] | Wiewiora A;Brindley G W.Potassium acetate intercalation in kaolinites and its removal:Effect of material characteristics[A].Jerusalem,1969 |
[8] | Lagaly G;Barren R M;Goulding K .Clay-organic interactions[and discussion][J].Philos Trans R Soc A:Math Phys Eng Sci,1984,311:315. |
[9] | Weiss A;Thielepape W;Orth H.Intercalation into kaolinite minerals[A].Jerusalem,1966 |
[10] | Foldvari M .Kaolinite-genetic and thermo analytical parameters[J].Journal of Thermal Analysis and Calorimetry,1997,48:107. |
[11] | Smith D L;Zuckerman J J;MiIford M H .Mechanism for intercalation of kaolinite by alkali acetates[J].SCIENCE,1966,153:741. |
[12] | Horte C H;Becker C;Kranz G et al.Thermal decompositions of kaolinite intercalation compounds[J].Journal of Thermal Analysis and Calorimetry,1988,33:401. |
[13] | Kristof J;Mink J;Horvdth E et al.Intercalation study of clay minerals by Fourier transform infrared spectrometry[J].VIBRATIONAL SPECTROSCOPY,1993,5:61. |
[14] | Gabor M;Toth M;Kristof J et al.Thermal behavior and decomposition of intercalated kaolinite[J].Clays and clay minerals,1995,43:223. |
[15] | Kristof J.;Felinger A.;Mink J.;Frost RL. .FTIR SPECTROSCOPIC STUDY OF INTERCALATED KAOLINITE[J].Journal of Molecular Structure,1997(0):119-122. |
[16] | 刘钦甫,丁述理.煤系高岭石-醋酸钾复合体的热行为[J].矿物学报,1997(03):276-279. |
[17] | Frost RL.;Paroz GN.;Kloprogge JT.;Kristof J. .Modification of the kaolinite hydroxyl surfaces through intercalation with potassium acetate under pressure[J].Journal of Colloid and Interface Science,1998(2):478-486. |
[18] | Frost RL.;Paroz GN.;Tran TH.;Kloprogge JT.;Kristof J. .The role of water in the intercalation of kaolinite with potassium acetate[J].Journal of Colloid and Interface Science,1998(2):227-236. |
[19] | Ruiz Cruz M D;Duro F L F .New data on the kaolinite-potassium acetate complex[J].Clay Minerals,1999,34:565. |
[20] | 夏华,王方正,李学强.高岭石-醋酸钾插层复合物的制备与表征[J].哈尔滨工业大学学报,2006(01):126-129. |
[21] | Cheng, H.;Yang, J.;Frost, R.L.;Liu, Q.;Zhang, Z. .Thermal analysis and Infrared emission spectroscopic study of kaolinite-potassium acetate intercalate complex[J].Journal of thermal analysis and calorimetry,2011(2):507-513. |
[22] | Kristof J;Frost R L;Kloprogge J T et al.Thermal behavior of kaolinite intercalated with formamide,dimethylsulphoxide and hydrazine[J].Journal of Thermal Analysis and Calorimetry,1999,56:885. |
[23] | Frost RL.;Mako E.;Kloprogge JT.;Kristof J. .Modification of the hydroxyl surface in potassium-acetate-intercalated kaolinite between 25 and 300 degrees C[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(19):7421-7428. |
[24] | Makó, ?.;Rutkai, G.;Kristóf, T. .Simulation-assisted evidence for the existence of two stable kaolinite/potassium acetate intercalate complexes[J].Journal of Colloid and Interface Science,2010(1):442-445. |
[25] | White C E;Provis J L;Gordon L E et al.Effect of temperature on the local structure of kaolinite intercalated with potassium acetate[J].CHEMISTRY OF MATERIALS,2010,23:188. |
[26] | Churchman G J;Whitton J S;Claridge G G C et al.Intercalation method using formamide for differentiating halloysite from kaolinite[J].Clays and clay minerals,1984,32:241. |
[27] | Theng B K G;Churchman G J;Whitton J S et al.Comparison of intercalation methods for differentiating halloysite from kaolinite[J].Clays and clay minerals,1984,32:249. |
[28] | Frost RL.;Horvath E.;Kloprogge JT.;Kristof J. .Raman microscopy of formamide-intercalated kaolinites treated by controlled-rate thermal analysis technology[J].Journal of Raman Spectroscopy,2001(10):873-880. |
[29] | Kristof J et al.Thermo analytical investigation of formamide intercalated kaolinites under quasi-isothermal conditions[J].Journal of Thermal Analysis and Calorimetry,2001,63:279. |
[30] | Frost R L;Kristof J;Horváth E et al.The modification of hydroxyl surfaces of formamide-intercalated kaolinites synthesized by controlled rate thermal analysis[J].Journal of Colloid and Interface Science,2001,239:126. |
[31] | 王林江,吴大清,袁鹏,陈志伟,陈忠.高岭石/甲酰胺插层的1H 魔角旋转核磁共振谱[J].科学通报,2001(22):1910-1914. |
[32] | Horvath E;Kristof J;Frost RL;Jakab E;Mako T;Vagvolgyi V .Identification of superactive centers in thermally treated formamide-intercalated kaolinite[J].Journal of Colloid and Interface Science,2005(1):132-138. |
[33] | 王林江,吴大清.甲酰胺在高岭石层间的定向研究[J].矿物岩石,2003(04):25-27. |
[34] | Clifford T J;Garrison Sposito;David F B et al.Vibrational spectroscopic study of the interlamellar kaolinite-dimethylsulfoxide complex[J].Journal of Physical Chemistry,1984,88:5959. |
[35] | Frost R L;Kristof J;Paroz G N et al.Molecular structure of dimethylsulfoxide intercalated kaolinites[J].Journal of Physical Chemistry,1998,B102:8519. |
[36] | 李伟东;黄建国;许承晃 .高岭石-二甲基亚砜夹层复合物的形成机理[J].华侨大学学报(自然科学版),1994,15(01):48. |
[37] | Frost R L;Kristof J;Horváth E et al.Deintercalation of dimethyl-sulphoxide intercalated kaolinites-a DTA/TGA and Raman spectroscopic study[J].Thermochimica Acta,1999,327:155. |
[38] | Frost R L;Kristof J;Horváth E et al.Kaolinite hydroxyls in dimethyl sulphoxide-intercalated kaolinites at 77K-A Raman spectroscopic study[J].Clay Minerals,2000,35:443. |
[39] | Franco F;Cruz M D R .High-temperature X-ray diffraction,differential thermal analysis and thermogravimetry of the kaolinite dimethylsulfoxide intercalation complex[J].Clays and clay minerals,2002,50:47. |
[40] | Franco F;Cruz M D R .Thermal behavior of dickite dimethylsulfoxide intercalation complex[J].Journal of Thermal Analysis and Calorimetry,2003,73:151. |
[41] | Gardolinski J E;Filho H P M;Wypych F .Thermal behavior of hydrated kaolirite[J].Quimica Nova,2003,26:30. |
[42] | 方沁华;汪文川 .蒙脱石和高岭石的分子动力学模拟研究[J].北京化工大学学报,2005,41:233. |
[43] | 叶血清;夏华;黄海波 .高岭石/二甲亚砜插层复合物的热分析[J].碳酸盐学报,2006,34:1416. |
[44] | 李志杰;郭方方;林枞 等.工业微波在制备高岭石/二甲基亚砜插层复合物中的应用[J].材料导报,2007,21(11):41. |
[45] | Lapides I;Yariv S .Thermo-X-ray-diffraction analysis of dimethylsulfoxide-kaolinite intercalation complexes[J].Journal of Thermal Analysis and Calorimetry,2009,97:19. |
[46] | Zhang, Y.;Liu, Q.;Wu, Z.;Zheng, Q.;Cheng, H. .Thermal behavior analysis of kaolinite-dimethylsulfoxide intercalation complex[J].Journal of thermal analysis and calorimetry,2012(3):1167-1172. |
[47] | Horváth, E.;Kristóf, J.;Frost, R.L. .Vibrational spectroscopy of intercalated kaolinites. part I.[J].Applied Spectroscopy Reviews: An International Journal of Principles, Methods, and Applications,2010(1/3):130-147. |
[48] | Wada K;Yamada H .Hydrazine intercalation-intercalation for differentiation of kaolin minerals from chlorites[J].American Mineralogist,1968,53:334. |
[49] | Calvert C S .Simplified,complete Cscl-hydrazine-dimethyl-sulfoxide intercalation of kaolinite[J].Clays and clay minerals,1984,32:125. |
[50] | Johnston C T;Stone D A .Influence of hydrazine on the vibrational modes of kaolinite[J].Clays and clay minerals,1990,38:121. |
[51] | Cruz M D R;Franco F .Thermal behavior of the kaolinitehydrazine intercalation complex[J].Clays and clay minerals,2000,48:63. |
[52] | Frost RL.;Paroz GN.;Kloprogge JT.;Kristof J. .Role of water in the intercalation of kaolinite with hydrazine[J].Journal of Colloid and Interface Science,1998(1):216-225. |
[53] | Frost R L;Kloprogge J T;Kristof J et al.Deintercalation of hydrazine-intercalated low-defect kaolinite[J].Clays and clay minerals,1999,47:732. |
[54] | Cruz M D R;Franco E .Thermal decomposition of a dickitehydrazine intercalation complex[J].Clays and clay minerals,2000,48:586. |
[55] | Frost R L;Kristof J;Kloprogge J T et al.Deintercalation of hydrazine-intercalated kaolinite in dry and moist air[J].Journal of Colloid and Interface Science,2002,246:164. |
[56] | Kristof J.;Frost RL.;Martens WN.;Horvath E. .Separation of adsorbed and intercalated hydrazine in hydrazine-hydrate intercalated kaolinite by controlled-rate thermal analysis[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(4):1244-1249. |
[57] | Deng Y;Dixon J B;White G N .Molecular configurations and orientations of hydrazine between structural layers of kaolinite[J].Journal of Colloid and Interface Science,2003,257:208. |
[58] | Tsunematsu K;Tateyama H .Delamination of urea-kaolinite complex by using intercalation procedures[J].Journal of the American Ceramic Society,1999,82:1589. |
[59] | Gardolinski J E et al.Exfoliation and hydration of kaolinite after intercalation with urea[J].Quimica Nova,2001,24:761. |
[60] | Yan C J;Chen J Y;Zhang C Z .Kaolinite-urea intercalation composites prepared using a rapid method[J].Journal of American Ceramic Society Bulletin,2005,84:11. |
[61] | Letaief S;Elbokl TA;Detellier C .Reactivity of ionic liquids with kaolinite: Melt intersalation of ethyl pyridinium chloride in an urea-kaolinite pre-intercalate[J].Journal of Colloid and Interface Science,2006(1):254-258. |
[62] | Budziak Fukamachi C R;Wypych F;Mangrich A S .Use of Fe3+ ion probe to study the stability of urea-intercalated kaolinite by electron paramagnetic resonance[J].Journal of Colloid and Interface Science,2007,313:537. |
[63] | Valá(s)ková M;Rieder M;Matejka V et al.Exfoliation/delimination of kaolinite by low-temperature washing of kaolinite-urea intercalates[J].Applied Clay Seience,2007,35:108. |
[64] | Rutkai, G.;Makó, E.;Kristóf, T. .Simulation and experimental study of intercalation of urea in kaolinite[J].Journal of Colloid and Interface Science,2009(1):65-69. |
[65] | Nicolini, K.P.;Fukamachi, C.R.B.;Wypych, F.;Mangrich, A.S. .Dehydrated halloysite intercalated mechanochemically with urea: Thermal behavior and structural aspects[J].Journal of Colloid and Interface Science,2009(2):474-479. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%