采用柠檬酸络合溶胶-凝胶法制备玻璃纤维滤膜基纳米钛酸锶钡(BBST),用X射线衍射(XRD)、扫描电镜(SEM)和傅里叶变换红外光谱(FTIR)进行表征.并系统地研究玻璃纤维滤膜基钛酸锶钡对水中Cd~(2+)吸附行为.结果表明,纳米钛酸锶钡通过Si-O-Ti和B-O-Ti键与玻璃纤维滤膜结合,成为新型多孔块体吸附剂.当介质的pH值为4～8时,该吸附剂对水中的Cd~(2+)具有很强的吸附能力,吸附容量为9.8 mg·g~(-1);其吸附行为符合Freundlich吸附等温模型和HO准二级动力学方程式,吸附过程焓变(△H)为17.241 kJ·mol~(-1),各温度下的自由能变(△G)均小于零,熵变(△S)均为正值,该吸附过程是自发的吸热物理过程.
Strontium-barium titanate based on glass fiber filter (BBST) was prepared by the citrate acid complex sol-gel method and characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and fourier transform infrared spectrophotometer (FT-IR). The adsorption behavior of BBST for cadmium ion in distilled water was investigated. The results show that the strontium-barium titanate could bond with glass fiber filter through Si-O-Ti and B-O-Ti bonding to produce a new sort of porous block adsorbent. The cadmium ion could be quantitatively retained in the medium with pH value range of 4-8, and the capacity of adsorption was 9.8 mg·g~(-1). The adsorption behavior followed Freundlich adsorption isotherm model and HO pseudo-second-order kinetic equation. The enthalpy changes (△H) of the adsorption process was 17.241 kJ·mol~(-1). At various temperatures, Gibbs free energy changes (△G) were negative, and entropy changes (△S) were positive. These showed that the adsorption of cadmium ion by BBST was endothermic and spontaneous physical process.
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