首次用固载化AlCl3催化剂催化桥式四氢双环戊二烯异构化反应合成金刚烷. 结果表明,以γ-Al2O3为载体的固载化AlCl3催化剂在较低的反应温度(140 ℃)下具有较高的催化活性和生成金刚烷的选择性,桥式四氢双环戊二烯的转化率达到100%, 金刚烷的选择性为17.7%;而以SiO2作为载体制备的催化剂,几乎没有金刚烷生成.
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