聚丙烯酸类共聚物/SiO2硅织物有机-无机杂化材料的合成与表征

材料导报, 2006, 20(4): 139-141.

聚丙烯酸类共聚物/SiO2硅织物有机-无机杂化材料的合成与表征

朱复红 ^1, , 曹永林 ^2, , 蒋艳 ^3, , 邱凤仙 ^4,

1.江苏大学化学化工学院,镇江,212013

2.江苏大学化学化工学院,镇江,212013

3.江苏大学化学化工学院,镇江,212013

4.江苏大学化学化工学院,镇江,212013

基金项目: 江苏大学校科研和教改项目(1291400001) 江苏省高校自然科学基金(05KJB150016)

关键词：溶胶-凝胶法 , 聚丙烯酸酯 , SiO2硅织物 , 杂化材料

Preparation and Identification of Polyacrylate Copolymer/SiO2 Silica Fabric Organic-Inorganic Hybrid Material

以γ缩水甘油氧丙基三甲氧基硅烷为偶联剂,通过溶胶-凝胶法制备了聚丙烯酸类共聚乳液/SiO2硅织物的有机-无机杂化材料,利用FT-IR、SEM、DSC及TG等手段对其进行了结构表征.SEM照片显示有机组分与无机组分间分布较均匀,并出现了相互贯穿;DSC表明Tg为206℃;对比法测得的比表面为81.61m2/g.实验结果证实该硅织物杂化材料中存在-Si-O-C-共价键,热稳定性较好.

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聚丙烯酸类共聚物/SiO2硅织物有机-无机杂化材料的合成与表征

Preparation and Identification of Polyacrylate Copolymer/SiO2 Silica Fabric Organic-Inorganic Hybrid Material

参考文献