采用两步法合成了一系列组分不同的水溶性苯乙烯/丙烯酸酯改性醇酸树脂.采用FT-IR、1H-NMR和GPC分别对树脂的结构、组成及相对分子质量进行了表征.测定了由合成树脂制备的清漆的性能,包括漆膜干燥时间、铅笔硬度、附着力、耐水和耐碱性能.结果表明:改性醇酸树脂具有良好的物理机械性能.
参考文献
| [1] | Weissenborn PK.;Motiejauskaite A. .Emulsification, drying and film formation of alkyd emulsions[J].Progress in Organic Coatings: An International Review Journal,2000(1/4):253-266. |
| [2] | NABUURS T;BAIJARDS R;GERMAN A .Alkyd-acrylic hybrid systems for use as binders in waterborne paints[J].Progress in organic Coatings,1996,27(01):163-172. |
| [3] | M J Deriss;O J Karlsson .Suspension structures and film morphologies of high-solids acrylic-alkyd hybrid binders[J].Surface Coatings International, Part B. Coatings Transactions: The Science and Technology of Paints, Inks and Related Coatings and their Raw Materials,2005(4):251-256. |
| [4] | Wang Changchun;Lin Geng;Pae Joon-Hwan;Jones Frank N. .Novel Synthesis of Carboxy-Functional Soybean Acrylic-Alkyd Resins for Water-Reducible Coatings[J].JCT,2000(904):55-61. |
| [5] | Akbarinezhad, E;Ebrahimi, M;Kassiriha, SM;Khorasani, M .Synthesis and evaluation of water-reducible acrylic-alkyd resins with high hydrolytic stability[J].Progress in Organic Coatings: An International Review Journal,2009(2):217-221. |
| [6] | Saravari O;Phapant P;Pimpan V .Synthesis of water-reducible acrylic-alkyd resins based on modified palm oil[J].Journal of Applied Polymer Science,2005(4):1170-1175. |
| [7] | HARRIS R R;POLLACK W J .Acrylate-modified alkyd resin[P].USA,4133786,1979-01-09. |
| [8] | Uschanov P;Heiskanen N;Mononen P;Maunu SL;Koskimies S .Synthesis and characterization of tall oil fatty acids-based alkyd resins and alkyd-acrylate copolymers[J].Progress in Organic Coatings: An International Review Journal,2008(1):92-99. |
| [9] | 刘国杰.醇酸-丙烯酸水性涂料杂化改性研究进展[J].现代涂料与涂装,2010(01):28-31. |
| [10] | 克拉克;赫尔墨;朔尔夫 .丙烯酸类改性的水性醇酸树脂或氨基甲酸酯改性醇酸树脂分散体[P].CN,1365368A,2002-08-21. |
| [11] | 弋天宝,梁亮,齐曾清,贺亮洪,曾凡初.水溶性苯乙烯改性醇酸树脂的合成工艺研究[J].涂料工业,2011(07):28-32. |
| [12] | Ikhuoria EU;Aigbodion AI;Okieimen FE .Preparation and characterisation of water-reducible alkyds with fumarized rubber seed oil[J].Progress in Organic Coatings: An International Review Journal,2005(3):238-240. |
| [13] | DELIGNY P;OLDRING P K T;TUCK N.Alkyds & Polyesters[M].New York:Wiley,2000 |
| [14] | IKHUORIA E U;OKIEIMEN F E;OBAZEE E O et al.Synthesis and characterization of styrenated rubber seed oil alkyd[J].AFRICAN JOURNAL OF BIOTECHNOLOGY,2011(10):1913-1918. |
| [15] | 周波.豆油脚脂肪酸制备松香改性醇酸树脂的配方研究[J].涂料工业,2007(06):58-60. |
| [16] | De Silva, S.H.U.I.;Amarasinghe, A.D.U.S.;Premachandra, B.A.J.K.;Prashantha, M.A.B. .Effect of karawila (Momordica charantia) seed oil on synthesizing the alkyd resins based on soya bean (Glycine max) oil[J].Progress in Organic Coatings: An International Review Journal,2012(1):228-232. |
| [17] | Radi?evi?, R.;Jovi?i?, M.;Budinski-Simendi?, J. .Preparation and curing of alkyd based on ricinoleic acid/melamine coatings[J].Progress in Organic Coatings: An International Review Journal,2011(3):256-264. |
| [18] | 刘登良.涂料工艺[M].北京:化学工艺出版社,2009 |
| [19] | Dziczkowski, J.;Soucek, M.D. .Factors influencing the stability and film properties of acrylic/alkyd water-reducible hybrid systems using a response surface technique[J].Progress in Organic Coatings: An International Review Journal,2012(4):330-343. |
| [20] | Stenberg, C;Svensson, M;Johansson, M .A study of the drying of linseed oils with different fatty acid patterns using RTIR-spectroscopy and chemiluminescence (CL).[J].Industrial crops and products,2005(2):263-272. |
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