为了对云南某厂废水中的铂族金属Pt(Ⅳ)、Pd(Ⅱ)进行吸附回收ⅷ将大肠杆菌E.coli做为吸附剂ⅷ探讨其在较适工艺条件下的吸附率ⅷ并结合Pt(Ⅳ)、Pd(Ⅱ)的纯溶液吸附来探索E.coli对废水中铂族金属的吸附特性。Pt(Ⅳ)、Pd(Ⅱ)纯溶液吸附实验表明ⅷE.coli对两者吸附能力相当ⅷ吸附率分别为96.66%、97.68%?而在工业废水中ⅷE.coli对Pt(Ⅳ)的吸附率仅为19.5%ⅷPd(Ⅱ)的吸附率仍有97.20%。用SPSS软件对工业废水吸附结果进行显著性分析ⅷ综合吸附量、吸附率ⅷ可认为废水中存在的大量贱金属对 Pd(Ⅱ)的吸附没有产生影响ⅷE.coli 对 Pd(Ⅱ)表现除了较高的恒择吸附性?双相Pt(Ⅳ)-Pd(Ⅱ)溶液吸附实验也表现出了相似的结果。可见在Pt(Ⅳ)-Pd(Ⅱ)共存的溶液中ⅷE.coli对Pd(Ⅱ)具有较高恒择吸附性。
To recover the platinum group metal Pt(IV) and Pd(II) in the waste water of a factory in Yunnan Province, the E.coliwas used as adsorbent to investigate the adsorption rate under better conditions and adsorption of pure Pt(IV), Pd(II) solution were used to explore the adsorption characteristics ofE.coli on the platinum group metals in wastewater. Pure Pt(IV) and Pd(II) solution adsorption experiments showed that two adsorption capacity of E.coli is equal, and the adsorption rate was 96.66% and 97.68% respectively; in industrial wastewater, the adsorption rate ofE.coli on Pt(IV) was 19.5%, and the adsorption rate of Pd(II) was still 97.20%. Analysis results of the adsorption results of industrial wastewater using SPSS software showed the adsorption of Pd(II) was not affected by the presence of a large number of base metals in wastewater, and theE.colishows Pd(II)-selective sorption behavior; the similar results were also demonstrated by Pt(IV)-Pd(II) solution adsorption experiments. In the solution of Pt (IV)-Pd (II), the E.coli has a high Pd(II)-selective adsorption property.
参考文献
[1] | 刘艳伟,杨滨,李艳.铂族金属在现代工业中的应用[J].南方金属,2009(02):1-3,19. |
[2] | 韩守礼,吴喜龙,王欢,王咏梅,贺小塘.从汽车尾气废催化剂中回收铂族金属研究进展[J].矿冶,2010(02):80-83. |
[3] | 孙广林;孙殿.炼油催化剂[M].北京:中国石化出版社,2012 |
[4] | 侯芙生.中国炼油技术[M].北京:中国石化出版社,2011 |
[5] | 付光强,范兴祥,董海刚,吴跃东,刘杨,闫君禺,行卫东,左川.贵金属二次资源回收技术现状及展望[J].贵金属,2013(03):75-81. |
[6] | 张苺 |
[7] | Mack C;Wilhelmi B;Duncan JR;Burgess JE .Biosorption of precious metals[J].Biotechnology Advances: An International Review Journal,2007(3):264-271. |
[8] | Das N .Recovery of precious metals through biosorption-a review[J].HYDROMETALLURGY,2010,103(1):180-189. |
[9] | 张秀丽,刘月英.贵、重金属的生物吸附[J].应用与环境生物学报,2002(06):668-671. |
[10] | Ramakul P;Yanachawakul Y;Leepipatpiboon N.Biosorption of palladium,(Ⅱ)and platinum,(Ⅳ)from aqueous solution using tannin from Indian almond,(Terminalia catappa L.)leaf biomass:Kinetic and equilibrium studies[J].CHEMICAL ENGINEERING JOURNAL,2012(193):102-111. |
[11] | Park J;Won S W;Mao J et al.Recovery of Pd(Ⅱ)from hydrochloric solution using polyallylamine hydrochloride-modified Escherichia coli biomass[J].Journal of Hazardous Materials,2010,181(1):794-800. |
[12] | Song M H;Won S W;Yun Y S.Decarboxylated polyethylenimine-modified bacterial biosorbent for Ru biosorption from Ru-bearing acetic acid wastewater[J].CHEMICAL ENGINEERING JOURNAL,2013(230):303-307. |
[13] | 徐家振,金哲男.重贵金属冶金中的微生物技术[J].有色矿冶,2002(01):31-34. |
[14] | Xiong, Y;Adhikari, CR;Kawakita, H;Ohto, K;Inoue, K;Harada, H .Selective recovery of precious metals by persimmon waste chemically modified with dimethylamine[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2009(18):4083-4089. |
[15] | Kim S;Song M H;Wei W.Selective biosorption behavior of Escherichia coli biomass toward Pd,(Ⅱ)in Pt,(Ⅳ)-Pd,(Ⅱ)binary solution[J].Journal of Hazardous Materials,2015(283):657-662. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%