目前国际上已商业化使用或提出的潜在的环保工质,大多数为氢氟烃(HFC)混合物,利用状态方程描述混合工质热力性质时,交互作用系数是重要参数之一.本文应用Peng-Robinson状态方程对多种HFC二元混合物的气液相平衡(vapor-liquid equilibrium,VLE)实验数据进行了回归,得到了相应混合物的交互作用系数.提出了交互作用系数新关联式,结果表明所得到的交互作用系数能很好的应用于描述HFC混合物气液相平衡性质,计算精度可以满足工程应用的需要.
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