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通过失重法、电化学和表面分析技术探讨了1013×105P a和80℃条件下吸收了CO2的4种有代表性的烷醇胺(MEA、DEA、AMP、MDEA)水溶液(3 mol/L )对碳钢的腐蚀性特点,从不同角度讨论了它们的CO2吸收机理和腐蚀性大小.实验表明, 不同的烷醇胺溶液吸收CO2的机理不同,生成的腐蚀产物膜及溶液组成也不同,所以腐蚀 性大小也有差异.在本实验条件下,腐蚀性大小顺序为:MEA>AMP>DEA>MDEA.

The corrosion behavior of carbon steel in CO2-abs orbed 3.0 mol/L MEA、DEA、AMP and MDEA solutions under 1.013×105Pa CO2 at 8 0℃ was investigated by static weight loss test,electrochemical method and surfa ce analytical technology.Their CO2 absorption mechanisms and corrosive charact eristic were discussed from several points of view.Different structure alkanolam ines have different CO2 absorption mechanisms,their corrosion product film and solution constituents were different,so their corrosivity was different.The cor rosivity of CO2 saturated amines tested in this work decreased in the order: M EA>AMP>DEA>MDEA.

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