含有稀土元素的合金材料具有很好的催化析氢活性,可用作析氢电极材料.分析对比了稀土La、Ce与铁组元素形成的非晶态合金的成分、组织结构及电化学性能.与晶态合金及不含有稀土的非晶态合金镀层相比发现,稀土作用的合金的组织更均匀、细致,且电化学活性较高.因此将稀土元素加入合金结构用以改变形成合金的晶体结构、提高合金的化学活性,是今后研究的重点.
参考文献
| [1] | Lokhande C D;Jadhav M S;Pawar S H .Electrodeposition of lanthanum from aqueous baths[J].Metal Finishing,1988,86(11):53. |
| [2] | E. Coetsee;J.J. Terblans;H.C. Swart .Degradation of Y_2SiO_5:Ce phosphor powders[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2007(1):37-42. |
| [3] | Wojciech Zajac;Konrad Swierczek;Janina Molenda .Thermochemical compatibility between selected (La,Sr) (Co,Fe,Ni)O_3 cathodes and rare earth doped ceria electrolytes[J].Journal of Power Sources,2007(2):675-680. |
| [4] | 郑敏章,刘晓梅,朱成军,徐丹,孙敬姝,苏文辉.复合阴极材料La1-xSrxCuO3-δ-SDC的制备及电学性能[J].高等学校化学学报,2006(11):2030-2033. |
| [5] | Mih6kov?E;Nikl M;Mare(s) J A et al.Luminescence and scintillmion properties of YAG:Ce single crystal and optical ceramics[J].Journal of Luminescence,2007,126(01):77. |
| [6] | Y.J. Chai;K. Sakaki;K. Asano .Crystal structure and hydrogen storage properties of La-Mg-Ni-Co alloy with superstructure[J].Scripta materialia,2007(6):545-548. |
| [7] | 刘淑兰;覃奇贤;成旦红 等.电沉积Ni-La合金上的阴极析氢行为[J].应用化学,1995,12(05):115. |
| [8] | 吴俊;黄清安;陈永言 等.水溶液中Ni-La-P合金的电沉积行为[J].应用化学,1999,16(06):65. |
| [9] | 安茂忠,马丽萍,孙德智,杨哲龙.乙醇溶液电沉积La-Ni合金工艺研究[J].功能材料,2001(02):164-166. |
| [10] | 金学平,吴俊,黄清安,莫少波,杨业智.含稀土的镍基合金的析氢电催化行为[J].中国稀土学报,2001(03):243-246. |
| [11] | Zinkevich M;Solak N;NiBche H et al.Stability and thermodynamic functions of lanthanum nickelates[J].Journal of Alloys and Compounds,2007,438(1-2):92. |
| [12] | Ozaki T;Kanemoto M;Kakeya T et al.Stacking structures and electrode performances of rare earth-Mg-Nibased alloys for advanced nickel-metal hydride battery[J].Journal of Alloys and Compounds,2007,446-447:620. |
| [13] | Han Qing;Li Xin;Chela Jianshe et al.Study of amorphous Ni-S(La)alloy used as HER cathode in alkaline medium[J].Journal of Alloys and Compounds,2005,400:265. |
| [14] | Itoh K;Shoumura T;Mori K et al.Structure of amorphous LaNi5D3.3 studied by neutron and X-ray diffraction[J].J Non-Cryste Solids,2007,353(18-21):1975. |
| [15] | Shi Siqi;Ouyang Chuying;Lei Minsheng .Crystal structure and electrochemical characteristics of non-AB5 type La-Ni system alloys[J].Journal of Power Sources,2007,164(02):911. |
| [16] | Ye F.;Lu K. .Crystallization kinetics of Al-La-Ni amorphous alloy[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2000(1/3):228-235. |
| [17] | 杨昌英,李昕,周俊婷,潘家荣.电沉积Ni-La-P非晶态合金电极电解还原葡萄糖[J].稀土,2003(03):34-36. |
| [18] | Chu Hailiang;Zhang Yao;Sun Lixian et al.Structure and electrochemical properties of composite electrodes synthesized by mechanical milling Ni-free TiMn2-based alloy with La-based alloys[J].Journal of Alloys and Compounds,2007,446-447:614. |
| [19] | Takako Yoshino;Hideki Masuda .Characterization of nano-structured thin films of electrodeposited Ce-Co mixed oxides for EC devices[J].Solid-State Ionicis,2003,165:123. |
| [20] | 袁定胜,刘应亮,刘冠昆,童叶翔.在二甲亚砜中脉冲电沉积La-Co-Fe合金膜的研究[J].中山大学学报（自然科学版）,2005(01):126-128. |
| [21] | Kaczorowski D;Gulay L D .Magnetic and electrical trausport properties of novel RE4Ni3Pb4(RE=La,Ce,Pr)compounds[J].J Alloys Comp,2007,436(1-2):9. |
| [22] | GAO Cheng-hui.Formation mechanism of amorphous Ni-Fe-P alloys by electrodeposition[J].中国有色金属学会会刊（英文版）,2005(03):504-509. |
| [23] | 高诚辉,赵源.Wear mechanism of electrodeposited amorphous Ni-Fe-P alloys[J].中国有色金属学会会刊(英文版),2004(02):255-259. |
| [24] | Chenghui GAO,Dajian CHEN,Baiyang ZHOU.Nitriding of Hard Fe Electrodeposition and Its Effects on Wear Resistance[J].材料科学技术学报(英文版),2001(02):271-274. |
| [25] | Song Y W;Shan D Y;Han E H .Corrosion behaviors of electroless plating Ni-P coatitings deposited on magnesium alloys in artificial sweat solution[J].Electrochimica Acta,2007,53(04):2009. |
| [26] | Wu Fanbean;Su Yuming;Tsai Yanzo et al.Fabrication and characterization of the Ni-PAl-W multicomponent coatings[J].Surface and Coatings Technology,2007,202(4-7):762. |
| [27] | Yuan XT;Sun DB;Yu HY;Meng HM;Fan ZS;Wang XD .Preparation of amorphous-nanocrystalline composite structured Ni-P electrodeposits[J].Surface & Coatings Technology,2007(2):294-300. |
| [28] | 汪继红,费锡明,李伟.稀土铈对镍-钴-磷合金电极的析氢催化性能的影响[J].材料保护,2004(01):9-10. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%