以碳纳米管醇分散剂TNADIS(粉末状聚合物分散剂)作为分散剂,同时应用超声振荡和高速剪切相互配合的工艺制成多壁碳纳米管(MWCNT)乙醇导电液.通过拉曼光谱,TEM和SEM表征MWCNTs的微观形态,通过离心,静置以及丁达尔效应的检测分析MWCNTs导电液的分散情况和稳定性.结果显示,添加0.05wt％分散剂时碳纳米管分散效果最佳,未石墨化MWCNTs的分散效果优于石墨化后的MWCNTs,且静置五个月后导电液依然保持良好的稳定性.应用此导电液通过旋涂工艺制得的涂覆均匀的MWCNTs透明导电薄膜,旋涂3min的透明导电薄膜方块电阻为0.34 kΩ/sq.
参考文献
| [1] | 毕松;苏勋家;侯根良;牛云波;谷国强;肖舟.碳纳米管增韧氧化铝纳米复合陶瓷的研究现状[J].陶瓷学报,2010(4):670-676. |
| [2] | K. Shinke;K. Ando;T. Koyama;T. Takai;S. Nakaji;T. Ogino.Properties of various carbon nanomaterial surfaces in bilirubin adsorption[J].Colloids and Surfaces, B. Biointerfaces,20101(1):18-21. |
| [3] | Kaushik Ghosh;Mukul Kumar;Takahiro Maruyama.Micro-structural, electron-spectroscopic and field-emission studies of carbon nitride nanotubes grown from cage-like and linear carbon sources[J].Carbon: An International Journal Sponsored by the American Carbon Society,20096(6):1565-1575. |
| [4] | Kaushik Ghosh;Mukul Kumar;Takahiro Maruyama.Tailoring the field emission property of nitrogen-doped carbon nanotubes by controlling the graphitic/pyridinic substitution[J].Carbon: An International Journal Sponsored by the American Carbon Society,20101(1):191-200. |
| [5] | Huafeng Wang;Zhenhua Li;Kaushik Ghosh.Synthesis of double-walled carbon nanotube films and their field emission properties[J].Carbon: An International Journal Sponsored by the American Carbon Society,201010(10):2882-2889. |
| [6] | Ando, K;Shinke, K;Yamada, S;Koyama, T;Takai, T;Nakaji, S;Ogino, T.Fabrication of carbon nanotube sheets and their bilirubin adsorption capacity[J].Colloids and Surfaces. B, Biointerfaces,20092(2):255-259. |
| [7] | Mukul Kumar;Yoshinori Ando.Camphor - a botanical precursor producing garden of carbon nanotubes[J].Diamond and Related Materials,20033/7(3/7):998-1002. |
| [8] | Shimizu T;Abe H;Ando A;Tokumoto H.Electric transport measurement of a multi-walled carbon nanotube in scanning transmission electron microscope[J].Physica, E. Low-dimensional systems & nanostructures,20041/2(1/2):37-41. |
| [9] | M. Taniguchi;H. Nagao;M. Hiramatsu.Preparation of dense carbon nanotube film using microwave plasma-enhanced chemical vapor deposition[J].Diamond and Related Materials,20053/7(3/7):855-858. |
| [10] | M.Endo;K.Takeuchi;T.hiraoka.Stacking nature of graphene layers in carbon nanotubes and nanofibres[J].The journal of physics and chemistry of solids,199711(11):1707-1712. |
| [11] | Endo M.;Karaki T.;Kasai T.;Matthews MJ.;Brown SDM. Dresselhaus MS.;Tamaki T.;Nishimura Y.;Kim C..Structural characterization of milled mesophase pitch-based carbon fibers[J].Carbon: An International Journal Sponsored by the American Carbon Society,199811(11):1633-1641. |
| [12] | M. Endo;Y.A. Kim;T. Hayashi;T. Yanagisawa;H. Muramatsu;M. Ezaka;H. Terrones;M. Terrones;M.S. Dresselhaus.Microstructural changes induced in "stacked cup" carbon nanofibers by heat treatment[J].Carbon: An International Journal Sponsored by the American Carbon Society,200310(10):1941-1947. |
| [13] | Wakiwaka H;Kodani M;Endo M;Takahashi Y.Non-contact measurement of CNT compounding ratio in composite material by eddy current method[J].Sensors and Actuators, A. Physical,20061-2(1-2):235-238. |
| [14] | Park SJ.;Cho MS.;Lim ST.;Cho HJ.;Jhon MS..Synthesis and dispersion characteristics of multi-walled carbon nanotube composites with poly(methyl methacrylate) prepared by in-situ bulk polymerization[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,200318(18):1070-1073. |
| [15] | 谢君樑;陈希元;黄进;刘子睿;李宏.稳定石墨烯胶体分散液的制备与表征[J].功能材料,2014(12):12108-12112. |
| [16] | Peng-Cheng Ma;Naveed A. Siddiqui;Gad Marom;Jang-Kyo Kim.Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review[J].Composites, Part A. Applied science and manufacturing,201010(10):1345-1367. |
| [17] | Magali Gauthier;David Reyter;Driss Mazouzi;Philippe Moreau;Dominique Guyomard;Bernard Lestriez;Lionel Roue.From Si wafers to cheap and efficient Si electrodes for Li-ion batteries[J].Journal of Power Sources,2014Jun.15(Jun.15):32-36. |
| [18] | Wen-Yin Ko;Jun-Wei Su;Chian-Hua Guo;Shu-Juan Fu;Chuen-Yuan Hsu;Kuan-Jiuh Lin.Highly conductive, transparent flexible films based on open rings of multi-walled carbon nanotubes[J].Thin Solid Films,201122(22):7717-7722. |
| [19] | Highly conductive and transparent carbon nanotube composite thin films deposited on polyethylene terephthalate solution dipping[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,201010(10):2822. |
| [20] | Jung R;Kim HS;Kim Y;Kwon SM;Lee HS;In HJ.Electrically conductive transparent papers using multiwalled carbon nanotubes[J].Journal of Polymer Science, Part B. Polymer Physics,200812(12):1235-1242. |
| [21] | Sang-Hyun Jo;Yeon-Kyeong Lee;Jong-Won Yang.Carbon nanotube-based flexible transparent electrode films hybridized with self-assembling PEDOT[J].Synthetic Metals,201213/14(13/14):1279-1284. |
| [22] | Yu Wang;Chong-an Di;Yunqi Liu;Hisashi Kajiura;Shanghui Ye;Lingchao Cao;Dacheng Wei;Hongliang Zhang;Yongming Li;Kazuhiro Noda.Optimizing Single-walled Carbon Nanotube Films For Applications In Electroluminescent Devices[J].Advanced Materials,200823(23):4442-4449. |
| [23] | Yuan-Li Huang;Hsi-WenTien;Chen-Chi M. Ma;Chih-ChunTeng;Yi-Hsiuan Yu;Shin-Yi Yang;Ming-Hsiung Wei;Sheng-Yen Wu.Effect of cross-linkable polymer on the morphology and properties of transparent multi-walled carbon nanotube conductive films[J].Applied Surface Science,20111(1):136-142. |
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