使用低密度聚乙烯、聚甲基丙烯酸甲酯和疏水性SiO2为原料,通过简单的共混涂膜方法在玻璃基底上制得了具有超疏水性能的聚乙烯/疏水性SiO2和聚甲基丙烯酸甲酯/疏水性SiO2复合涂层;用接触角测量仪、扫描电子显微镜、X-射线光电子能谱仪等分析手段对涂层的润湿性能、微观结构以及表面化学成分等进行了表征.结果表明,所制备的两种聚合物/疏水性SiO2复合涂层的静态水接触角都超过150°,滚动角低至3.0°.聚合物和疏水性SiO2共混涂膜后形成了类似于荷叶的微纳米二元结构,是其表面具有优异超疏水性能的主要原因.
Using low density polyethylene (PE),polymethyl methacrylate (PMMA) and hydrophobic SiO2 as the raw materials,PE/hydrophobic SiO2 and PMMA/hydrophobic SiO2 composite coatings with superhydrophobicity were fabricated on the glass substrate by a simple one-step casting method.Several analysis equipments,such as contact angle meter,scanning electron microscope and X-ray photoelectron spectroscopy instrument,were used to characterize and analyse the wettability,morphology,and surface chemical properties of the as-prepared coatings,respectively.The results show that the static water contact angles of the two coatings are higher than 150° and the sliding angles are lower than 3.0°.It is also found that the micro-nano-binary structure,similar to lotus leaves,is essential for achieving an excellent superhydrophobic surface.
参考文献
[1] | K.Liu,X.Yao,L.Jiang,Recent developments in bio-inspired special wettability,Chem.Soc.Rev.,39,3240(2010) |
[2] | X.M.Li,D.Reinhoudt,M.Crego-Calama,What do we need for a superhydrophobic surface? A review on the recent progress in the preparation of superhydrophobic surfaces,Chem.Soc.Rev.,36,1350(2007) |
[3] | T.L.Sun,L.Feng,X.F.Gao,L.Jiang,Bioinspired surfaces with special wettability,Acc.Chem.Res.,38,644(2005) |
[4] | F.Xia,L.Jiang,Bio-inspired,smart,multiscale interfacial materials,Adv.Mater.,20,2842(2008) |
[5] | X.Zhang,Y.G.Guo,P.Y.Zhang,Z.J.Zhang,Z.S.Wu,Superhydrophobic and Superoleophilic Nanoparticle Film:Synthesis and Reversible Wettability Switching Behavior,ACS Applied Materials & Interfaces,4,1742(2012) |
[6] | X.Zhang,Y.G.Guo,P.Y.Zhang,Z.S.Wu,Z.J.Zhang,Superhydrophobic CuO@Cu2S nanoplate vertical arrays on copper surfaces,Mater.Lett.,64,1200(2010) |
[7] | C.Neinhuis,W.Barthlott,Characterization and distribution of water-repellent,self-cleaning plant surfaces,Ann.Bot.,79,667(1997) |
[8] | L.Feng,S.H.Li,Y.S.Li,H.J.Li,L.J.Zhang,J.Zhai,Y.L.Song,B.Q.Liu,L.Jiang,D.B.Zhu,Super-hydrophobic surfaces:From natural to artificial,Adv.Mater.,14,1857(2002) |
[9] | M.H.Sun,C.X.Luo,L.P.Xu,H.Ji,O.Y.Qi,D.P.Yu,Y.Chen,Artificial lotus leaf by nanocasting,Langmuir,21,8978(2005) |
[10] | T.Ishizaki,M.Sakamoto,Facile formation of biomimetic colortuned superhydrophobic magnesium alloy with corrosion resistance,Langmuir,27,2375(2011) |
[11] | A.V.Rao,S.D.Bhagat,H.Hirashima,G.M.Pajonk,Synthesis of flexible silica aerogels using methyltrimethoxysilane (MTMS) precursor,J Colloid Interf.Sci.,300,279(2006) |
[12] | HU Xiaojuan,LIU Lan,LUO Yuanfang,JIA Demin,CHENG Liang,HU Shengzhe,Preparation of superhydrophobic PMHS-SiO2 coatings by sol-gel method,Chinese Journal of Materials Research,24(3),266(2010)(胡小娟,刘岚,罗远芳,贾德民,程梁,胡盛哲,溶胶-凝胶法制备超疏水PMHS-SiO2涂膜,材料研究学报,24(3),266(2010)) |
[13] | T.Darmanin,E.T.de Givenchy,S.Amigoni,F.Guittard,Hydrocarbon versus fluorocarbon in the electrodeposition of superhydrophobic polymer films,Langmuir,26,17596(2010) |
[14] | H.Y.Erbil,A.L.Demirel,Y.Avci,O.Mert,Transformation of a simple plastic into a superhydrophobic surface,Science,299,1377(2003) |
[15] | JI Jingou,Preparation of super-Hydrophobic and self-cleaning coating of nano-composite fluoropolyacrylate,Chinese Journal of Materials Research,25(4),422(2011)(季金苟,纳米复合氟改性丙烯酸树脂超疏水自清洁涂层的制备,材料研究学报,25(4),422(2011)) |
[16] | LIAN Feng,TAN Jiazheng ZHANG Huichen,Preparation and properties of super-hydrophobic surface on warship Steel,Chinese Journal of Materials Research,27(1),13(2013)(连峰,谭家政,张会臣,船体用钢板基底超疏水表面的制备和性能,材料研究学报,27(1),13(2013)) |
[17] | A.B.D.Cassie,S.Baxter,Wettability of porous surfaces,Trans.Faraday Soc.,40,546(1944) |
[18] | John F.Moulder,William F.Stickle,Peter E.Sobol,Kenneth D.Bomb,Handbook of X-ray Photoelectron Spectroscopy:A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data,(USA,Perkin-Elmer Corporation Physical Electronics Division,1992) |
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