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研究了不同分子量的上浆剂对碳纤维表观状态及其界面性能的影响,并采用了AFM,SEM等表面分析技术研究了上浆后碳纤维表面形貌.AFM,SEM证实了S-1表面没有小颗粒存在,沟槽较均匀,而S-2表面的沟槽较深,S-3表面的沟槽较浅,且表面都有小的颗粒.XPS证实了S-1表面含有O元素含量最高,表面极性官能团较多.上浆剂分子量对制备的复合材料的界面性能和耐湿热老化性能有较大的影响,分子量适中的上浆剂HIT-7上浆处理后的碳纤维及其复合材料的性能最优.

The effects of three different molecular weight of sizing agent on the performances of carbon fiber and carbon fiber composites were studied.It was found that a number of grooves uniformly dispersed on the S-1 surface.The depth of grooves on the S-1 surface was smaller than that on the S-2,but bigger than that on the S-3.Small particles on the S-2 and S-3 surface were confirmed by AFM,SEM.XPS also confirmed that S-1 surface contained more O element than others.The results indicated that the high and low molecular weight of sizing agent decreased the interfacial shear strengths and ageing properties of carbon fiber composites,while the moderate molecular weight sizing agent(HIT-7) showed better interfacial adhesion and ageing property.

参考文献

[1] 贺福,赵建国,王润娥.炭纤维开发与炭纤维原丝质量[J].新型碳材料,1998(01):64-74.
[2] JYONGSIK JANG;HOJUNG YANG .The effect of surface treatment on the performance improvement of carbon fiber/polybenzoxazine composites[J].Journal of Materials Science,2000(9):2297-2303.
[3] Park SJ.;Lee JR.;Choi S.;Kim MH. .Effect of fiber-polymer interactions on fracture toughness behavior of carbon fiber-reinforced epoxy matrix composites[J].Journal of Colloid and Interface Science,2000(2):287-291.
[4] 潘慧铭,黄素娟.表面、界面的作用与粘接机理(三)[J].粘接,2003(04):37-42.
[5] 程俊梅,于广水,赵树高,张萍.动态热力学分析法评估短纤维/橡胶复合材料界面粘合效果[J].橡胶工业,2006(03):139-142.
[6] 隋刚,杨小平,梁吉,朱跃峰.碳纳米管/天然橡胶复合材料的制备及性能[J].复合材料学报,2005(05):72-77.
[7] 张敏,朱波,王启芬,于美杰,曹伟伟.单向碳纤维复合材料微观形貌与性能相关性研究[J].纤维复合材料,2007(02):21-24.
[8] Huang HC;Ye DQ;Huang BC .Nitrogen plasma modification of viscose-based activated carbon fibers[J].Surface & Coatings Technology,2007(24):9533-9540.
[9] Juliane Mentz;Marcus Mueller;Hans Peter Buchkremer;Detlev Stoever .Carbon-fibre-reinforced carbon composite filled with SiC particles forming a porous matrix[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2006(1/2):64-69.
[10] I.D. Harry;B. Saha;I.W. Cumming .Surface properties of electrochemically oxidised viscose rayon based carbon fibres[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(4):766-774.
[11] Ferry Winter;G.Leendert Bezemer;Cor Van Der Spek;D.Meeldijk .TEM and XPS studies to reveal the presence of cobalt and palladium particles in the inner core of carbon nanofibers[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(2):327-332.
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