研究讨论了纳米或颜料级锐钛矿型及金红石型TiO2在聚丙烯酸酯复合涂层中的抗光降解作用.通过FTIR、失重分析以及氢过氧化物分析表征人工加速耐老化检测中复合涂层光降解变化过程.采用非挥发性物质中C = O键在1733cm-1的透过率变化描述复合涂层光降解速率.实验结果表明:锐钛矿型TiO2由于具有光催化性会加速聚丙烯酸酯复合涂层的光降解过程,使复合涂层失重加快,光氧化产物含量增大;而金红石型TiO2对聚丙烯酸酯复合涂层有良好的抗光降解作用,阻止丙烯酸酯聚合物光降解的进行.颜料级TiO2与纳米级TiO2相比呈现出不同的抗光降解作用.
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