Coarsening behavior of γ' precipitates in the dendritic regions of a Ni 3 Al base alloy containing chromium,molybdenum,zirconium and boron was investigated.Annealing treatment was performed up to 50 h at 900,1000 and 1100℃.The alloy was produced by vacuum-arc remelting technique.Results show that coarsening of the γ' precipitates in this complex alloy containing high volume fractions of γ' phase follows Lifshitz-Slyozov-Wagner(LSW) theory.Coarsening activation energy of the γ' precipitates was evaluated to be about 253.5 kJ.mol-1 which shows that the growth phenomenon is controlled by volume diffusion of aluminum.With an innovative approach,diffusion coefficient of the solute element(s) and the interfacial energy between γ' precipitates and γ'(matrix) were estimated at 900,1000 and 1100℃.Accordingly,the interfacial energies at 900,1000 and 1100℃ are 4.49±1.48,2.08±0.69 and 0.98±0.32 mJ.m-2,respectively.Also the diffusivities of solute element(s) at these temperatures are 3.41±1.08,30±9.5 and 145.15±45.85(10-15 m-2.s-1),respectively.
参考文献
[1] | A. LASALMONIE .Intermetallics: Why is itso difficult to introduce them in gas turbine engines?[J].Intermetallics,2006(10/11):1123-1129. |
[2] | H.B. Motejadded;M. Soltanieh;S. Rastegari .An investigation about the effect of annealing conditions on microstructure in a Ni_3Al base alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):881-885. |
[3] | Y. Ma;A.J. Ardell .Coarsening of gamma (Ni-Al solid solution) precipitates In a gamma' (Ni_3A1) matrix; a striking contrast in behavior from normal gamma/gamma' alloys[J].Scripta materialia,2005(12):1335-1340. |
[4] | X. LI;N. SAUNDERS;A. P. MIODOWNIK .The Coarsening Kinetics of gamma' Particles in Nickel-Based Alloys[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2002(11):3367-3373. |
[5] | A.M. Ges;O. Fornaro;H.A. Palacio .Coarsening behaviour of a Ni-base superalloy under different heat treatment conditions[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2007(1-2):96-100. |
[6] | D. M. Kim;A. J. Ardell .Coarsening of Ni_3Ge in binary Ni-Ge alloys: microstructures and volume fraction dependence of kinetics[J].Acta materialia,2003(14):4073-4082. |
[7] | J. Z. Zhu;T. Wang;A. J. Ardell .Three-dimensional phase-field simulations of coarsening kinetics of gamma' particles in binary Ni-Al alloys[J].Acta materialia,2004(9):2837-2845. |
[8] | T. Maebashi;M. Doi .Coarsening behaviours of coherent γ′ and γ precipitates in elastically constrained Ni-Al-Ti alloys[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2004(1/2):72-79. |
[9] | M. Aghaie-Khafri;M. Hajjavady .The effect of thermal exposure on the properties of a Ni-base superalloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2008(1/2):388-393. |
[10] | J. Tiley;G.B. Viswanathan;R. Srinivasan .Coarsening kinetics of gamma' precipitates in the commercial nickel base Superalloy Rene 88 DT[J].Acta materialia,2009(8):2538-2549. |
[11] | Y. Yamabe-Mitarai;Y. Ro .Ir-base refractory superalloys for ultra-high temperatures[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,1998(2):537-550. |
[12] | G. Kaptay .On the Temperature Gradient Induced Interfacial Gradient Force, Acting on Precipitated Liquid Droplets in Monotectic Liquid Alloys[J].Materials Science Forum,2006(0):269-274. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%